Abstract:
A new polymeric phase of zinc(II) oxydiacetate, catena-poly[[[diaquazinc(II)]-μ-oxydiacetato] hydrate], {[Zn(C4H4-O5)(H2O)2] ·H2O}n, isomorphous with the Co homologue [Hatfield, Helms, Rohrs, Singh, Wasson & Weller (1987). Proc. Indian Acad. Sci. Chem. Sci. 98, 23-31], is reported. It presents a chain-like structure, generated by ZnO6 cores which are bridged by carboxylate groups in an anti-anti conformation along the unique crystallographic b axis. The chains are held together through hydrogen-bonding interactions with the three water molecules.
Registro:
Documento: |
Artículo
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Título: | A new polymeric phase of zinc(II) oxydiacetate |
Autor: | Baggio, R.; Garland, M.T.; Perec, M. |
Filiación: | Departamento de Física, Comn. Natl. de Ener. Atómica, Buenos Aires, Argentina Departamento de Física, Fac. Cie. Fis./Matemat., Universidad de Chile, Casilla 487-3, Santiago de Chile, Chile Dept. de Quím. Inorg., INQUIMAE, Fac. de Ciencias Exactas y Naturales, Buenos Aires, Argentina
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Palabras clave: | Carboxylic acids; Crystal structure; Crystallography; Hydrogen bonds; Molecular structure; Polymers; Zinc compounds; Polymeric phases; Organometallics; Catena |
Año: | 2003
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Volumen: | 59
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Número: | 1
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Página de inicio: | m30
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Página de fin: | m32
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DOI: |
http://dx.doi.org/10.1107/S0108270102021959 |
Título revista: | Acta Crystallographica Section C: Crystal Structure Communications
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Título revista abreviado: | Acta Crystallogr Sect C Cryst Struct Commun
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ISSN: | 01082701
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CODEN: | ACSCE
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PDF: | https://bibliotecadigital.exactas.uba.ar/download/paper/paper_01082701_v59_n1_pm30_Baggio.pdf |
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v59_n1_pm30_Baggio |
Referencias:
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- Baggio, R., Garland, M.T., Perec, M., (1996) J. Chem. Soc. Dalton Trans., pp. 2747-2753
- Boman, C.-E., (1974) Acta Chem. Scand. Ser. A, 28, pp. 119-121
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- Grirrane, A., Pastor, A., Ienco, A., Mealli, C., Galindo, A., (2002) J. Chem. Soc. Dalton Trans., pp. 3771-3777
- Hatfleld, W.E., Helms, J.H., Rohrs, B.R., Singh, P., Wasson, J.R., Weller, R.R., (1987) Proc. Indian Acad. Sci. Chem. Sci., 98, pp. 23-31
- Prince, R.H., (1987) Comprehensive Coordination Chemistry, 5, pp. 925-1022. , edited by G. Wilkinson. Oxford: Pergamon
Citas:
---------- APA ----------
Baggio, R., Garland, M.T. & Perec, M.
(2003)
. A new polymeric phase of zinc(II) oxydiacetate. Acta Crystallographica Section C: Crystal Structure Communications, 59(1), m30-m32.
http://dx.doi.org/10.1107/S0108270102021959---------- CHICAGO ----------
Baggio, R., Garland, M.T., Perec, M.
"A new polymeric phase of zinc(II) oxydiacetate"
. Acta Crystallographica Section C: Crystal Structure Communications 59, no. 1
(2003) : m30-m32.
http://dx.doi.org/10.1107/S0108270102021959---------- MLA ----------
Baggio, R., Garland, M.T., Perec, M.
"A new polymeric phase of zinc(II) oxydiacetate"
. Acta Crystallographica Section C: Crystal Structure Communications, vol. 59, no. 1, 2003, pp. m30-m32.
http://dx.doi.org/10.1107/S0108270102021959---------- VANCOUVER ----------
Baggio, R., Garland, M.T., Perec, M. A new polymeric phase of zinc(II) oxydiacetate. Acta Crystallogr Sect C Cryst Struct Commun. 2003;59(1):m30-m32.
http://dx.doi.org/10.1107/S0108270102021959