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Abstract:

The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordination spheres of the types S4Cl and S4Br, respectively. The central Cd atom is linked to four S atoms and two bidentate dithiocarbamate ligands and to the halide atom. The resulting Cd-atom coordination geometry is halfway between trigonal bipyrimidal and square pyramidal. Principal dimensions include: Cd-S 2.573 (1)-2.682 (1) in (1) and 2.571 (3)-2.736 (2) Å in (2); Cd-Cl and Cd-Br 2.462 (1) and 2.626 (1) Å, respectively.

Registro:

Documento: Artículo
Título:The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
Autor:Baggio, R.; Garland, M.T.; Perec, M.
Filiación:Div. Física del Sólido, Departamento de Física, Comn. Nac. de Ener. Atómica, Av. del Libertador 8250, 1429 Buenos Aires, Argentina
Departamento de Física, Fac. de Cie. Fis. y Matemat., Universidad de Chile, Casilla 487-3, Santiago de Chile, Chile
Depto. Quim. Inorg., Analitica y Q., Fac. de Ciencias Exactas y Naturales, Pabellón II, 1428 Buenos Aires, Argentina
CONICET
Palabras clave:Bromine compounds; Cadmium compounds; Chlorine compounds; Crystal atomic structure; Molecular structure; Spectroscopic analysis; Cadmium halide bis(diethyldithiocarbamate) complexes; Isomorphous compounds; Mononuclear complexes; Organometallics
Año:1996
Volumen:52
Número:4
Página de inicio:823
Página de fin:826
DOI: http://dx.doi.org/10.1107/S0108270195013941
Título revista:Acta Crystallographica Section C: Crystal Structure Communications
Título revista abreviado:Acta Crystallogr Sect C Cryst Struct Commun
ISSN:01082701
CODEN:ACSCE
PDF:https://bibliotecadigital.exactas.uba.ar/download/paper/paper_01082701_v52_n4_p823_Baggio.pdf
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v52_n4_p823_Baggio

Referencias:

  • Addison, A.W., Rao, T.N., Reedijk, J., Van Rijn, J., Verschoor, G.C.J., (1984) J. Chem. Soc. Dalton Trans., pp. 1349-1356
  • Baggio, R.F., Frigerio, A., Halac, E.B., Vega, D., Perec, M., (1992) J. Chem. Soc. Dalton Trans., pp. 549-554
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  • Reddy, H.K., Zhang, C., Schlemper, E.O., Schrauzer, G.N., (1992) Inorg. Chem., 31, pp. 1673-1677
  • Sheldrick, G.M., (1991) SHELXTUPC. Version 4.2, , Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA
  • Sheldrick, G.M., (1993) SHELXL93. Program for the Refinement of Crystal Structures, , University of Göttingen, Germany
  • Siemens, (1991) P3/P4-PC Diffractameter Program. Version 4.27, , Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA

Citas:

---------- APA ----------
Baggio, R., Garland, M.T. & Perec, M. (1996) . The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]. Acta Crystallographica Section C: Crystal Structure Communications, 52(4), 823-826.
http://dx.doi.org/10.1107/S0108270195013941
---------- CHICAGO ----------
Baggio, R., Garland, M.T., Perec, M. "The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]" . Acta Crystallographica Section C: Crystal Structure Communications 52, no. 4 (1996) : 823-826.
http://dx.doi.org/10.1107/S0108270195013941
---------- MLA ----------
Baggio, R., Garland, M.T., Perec, M. "The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]" . Acta Crystallographica Section C: Crystal Structure Communications, vol. 52, no. 4, 1996, pp. 823-826.
http://dx.doi.org/10.1107/S0108270195013941
---------- VANCOUVER ----------
Baggio, R., Garland, M.T., Perec, M. The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]. Acta Crystallogr Sect C Cryst Struct Commun. 1996;52(4):823-826.
http://dx.doi.org/10.1107/S0108270195013941