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Abstract:

Ordered nanostructured oxides are materials in which nano-objects are arranged in an array with a defined periodicity. Among them, ordered mesoporous oxides (OMPO), such as TiO2, SiO2, and ZrO2 are considered for a wide range of technological applications due to their low-cost reproducible synthesis and chemical stability. These OMPO films exhibit calibrated size pores (2-50nm) and a large surface area that can be tuned using sol-gel synthetic pathways combined with self-assembly of amphiphilic molecules. Functional optical properties of OMPO films can be tailored reacting to changes in the environment, such as relative humidity or vapors in a selective way. Multilayers of OMPO with different composition grown by sol-gel behave as photonic crystals where the photonic band gap can be fitted by tuning the pore's size and shape. In addition to these composite structures, those derived from embedding metal or semiconductor nanoparticles within OMPO films produce new plasmonic and luminescent materials enhancing the possibility of new applications. In this chapter we present some basic concepts on the optical properties of OMPO in relation with sol-gel synthesis process, and we discuss the potential applications for the design of optical sensors. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA.

Registro:

Documento: Parte de libro
Título:Structures and Properties of Ordered Nanostructured Oxides and Composite Materials
Autor:Martínez Ricci, M.L.; Bilmes, S.A.
Filiación:Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales INQUIMAE, Departamento de Química Inorgánica, Analítica y Química Física, Pabellón 2, Intendente Güiraldes 2160, Ciudad Universitaria, Buenos Aires, C1428EHA, Argentina
Palabras clave:Composite materials; Mesostructured thin films; Optical properties; Ordered mesoporous oxides; Ordered nanostructured oxides; Photonic crystals; Sol-gel method; Chemical stability; Composite materials; Energy gap; Film preparation; Mesoporous materials; Metal nanoparticles; Nanocomposite films; Optical properties; Photonic band gap; Photonic crystals; Plasmonics; Self assembly; Silica; Sol-gel process; Sol-gels; Thin films; Titanium dioxide; Zirconia; Amphiphilic molecules; Mesostructured; Nanostructured oxides; Ordered mesoporous; Semiconductor nanoparticles; Sol-gel synthesis process; Structures and properties; Technological applications; Optical films
Año:2015
Volumen:2-3
Página de inicio:1031
Página de fin:1054
DOI: http://dx.doi.org/10.1002/9783527670819.ch33
Título revista:The Sol-Gel Handbook
Título revista abreviado:The Sol-Gel Handb.
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97835276_v2-3_n_p1031_MartinezRicci

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Citas:

---------- APA ----------
Martínez Ricci, M.L. & Bilmes, S.A. (2015) . Structures and Properties of Ordered Nanostructured Oxides and Composite Materials. The Sol-Gel Handbook, 2-3, 1031-1054.
http://dx.doi.org/10.1002/9783527670819.ch33
---------- CHICAGO ----------
Martínez Ricci, M.L., Bilmes, S.A. "Structures and Properties of Ordered Nanostructured Oxides and Composite Materials" . The Sol-Gel Handbook 2-3 (2015) : 1031-1054.
http://dx.doi.org/10.1002/9783527670819.ch33
---------- MLA ----------
Martínez Ricci, M.L., Bilmes, S.A. "Structures and Properties of Ordered Nanostructured Oxides and Composite Materials" . The Sol-Gel Handbook, vol. 2-3, 2015, pp. 1031-1054.
http://dx.doi.org/10.1002/9783527670819.ch33
---------- VANCOUVER ----------
Martínez Ricci, M.L., Bilmes, S.A. Structures and Properties of Ordered Nanostructured Oxides and Composite Materials. The Sol-Gel Handb. 2015;2-3:1031-1054.
http://dx.doi.org/10.1002/9783527670819.ch33