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McDonald, M.P.; Morozov, Y.; Hodak, J.H.; Kuno, M. "Spectroscopy and microscopy of graphene oxide and reduced graphene oxide" (2015) Graphene Oxide: Reduction Recipes, Spectroscopy, and Applications:29-60
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Abstract:

Graphene oxide (GO) is an important material that provides a scalable approach for obtaining chemically derived graphene. Its optical and electrical properties are largely determined by the presence of oxygen-containing functionalities, which decorate its basal plane. This chemical derivatization results in useful properties such as the existence of a band gap as well as emission spanning both the visible and near infrared. Notably, GO’s optical and electrical properties can be altered through reduction, which proceeds through the removal of these oxygen-containing functional groups. However, widely variable behavior has been observed regarding the evolution of GO’s optical response during reduction. These discrepancies arise from the different reduction methods being used and, in part, from the fact that nearly all prior measurements have been ensemble studies. Consequently, detailed mechanistic studies of GO reduction are needed which can transcend the limitations of ensemble averaging. In this chapter, we show the spectroscopic evolution of GO’s optical properties during photoreduction at the single’sheet level. Laser–induced reduction, in particular, offers a unique and potentially controllable method for producing reduced GO (rGO), a material with properties similar to those of graphene. However, given the complexity of GO’s photoreduction mechanism, microscopic monitoring of the process is essential to understanding and ultimately exploiting this approach. © Springer International Publishing Switzerland 2015.

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Documento: Parte de libro
Título:Spectroscopy and microscopy of graphene oxide and reduced graphene oxide
Autor:McDonald, M.P.; Morozov, Y.; Hodak, J.H.; Kuno, M.
Filiación:Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556, United States
Department of Physics, Taras Shevchenko National University of Kiev, Kiev, Ukraine
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556, United States
INQUIMAE-Departamento de Química Inorgánica, Analítica y Química Físca, Facultad de Ciencias Exactas y Naturales, University of Buenos Aires, Buenos Aires, Argentina
Palabras clave:Absorption; Absorption coefficient; Emission; Fluorescence intermittency; Graphene oxide; Photobrightening; Photolysis; Reduced graphene oxide; Reduction; Absorption; Neutron emission; Optical properties; Photolysis; Reduction; Absorption co-efficient; Fluorescence intermittency; Graphene oxides; Photobrightening; Reduced graphene oxides; Graphene
Año:2015
Página de inicio:29
Página de fin:60
DOI: http://dx.doi.org/10.1007/978-3-319-15500-5_2
Título revista:Graphene Oxide: Reduction Recipes, Spectroscopy, and Applications
Título revista abreviado:Graphene Oxide: Reduct. Recipes, Spectroscopy, and Applications
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97833191_v_n_p29_McDonald

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Citas:

---------- APA ----------
McDonald, M.P., Morozov, Y., Hodak, J.H. & Kuno, M. (2015) . Spectroscopy and microscopy of graphene oxide and reduced graphene oxide. Graphene Oxide: Reduction Recipes, Spectroscopy, and Applications, 29-60.
http://dx.doi.org/10.1007/978-3-319-15500-5_2
---------- CHICAGO ----------
McDonald, M.P., Morozov, Y., Hodak, J.H., Kuno, M. "Spectroscopy and microscopy of graphene oxide and reduced graphene oxide" . Graphene Oxide: Reduction Recipes, Spectroscopy, and Applications (2015) : 29-60.
http://dx.doi.org/10.1007/978-3-319-15500-5_2
---------- MLA ----------
McDonald, M.P., Morozov, Y., Hodak, J.H., Kuno, M. "Spectroscopy and microscopy of graphene oxide and reduced graphene oxide" . Graphene Oxide: Reduction Recipes, Spectroscopy, and Applications, 2015, pp. 29-60.
http://dx.doi.org/10.1007/978-3-319-15500-5_2
---------- VANCOUVER ----------
McDonald, M.P., Morozov, Y., Hodak, J.H., Kuno, M. Spectroscopy and microscopy of graphene oxide and reduced graphene oxide. Graphene Oxide: Reduct. Recipes, Spectroscopy, and Applications. 2015:29-60.
http://dx.doi.org/10.1007/978-3-319-15500-5_2