Parte de libro

Cosenza, V.A.; Navarro, D.A.; Stortz, C.A. "Chemical modification of carrageenans and application of the modified products" (2016) Carrageenans: Sources and Extraction Methods, Molecular Structure, Bioactive Properties and Health Effects:189-227
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Abstract:

Carrageenans are sulfated galactans notably conspicuous in red seaweeds. Their abundance in renewable sources combined with their already proven biological activities and rheological properties has drawn their attention at both industrial and lab levels. Their complex though basically repeating structure has made carrageenans an interesting target for chemical modifications. In this way, newly functionalized polysaccharides can be obtained with enhanced and/or altered properties, either biological or rheological, but still maintaining fundamental properties such as biocompatibility and biodegradability. This chapter will focus on the different chemical modifications performed up to date on carrageenans and how these modifications have affected the polysaccharide properties. The simplest and best-known modification is the so-called alkaline treatment, only possible in carrageenans carrying -D-galactose 6-sulfate units, as they convert into 3,6-anhydrogalactose in the polysaccharide, thus increasing their gelling properties. The increase or decrease of the negative charge (i.e., oversulfation, desulfation, oxidation of C-6, etc.) comprises another common group of reactions carried out on these polysaccharides that can affect both the physicochemical and biochemical properties. Other reactions such as cationizations, depolymerizations and increases of the hydrophobicity have also been performed on these polysaccharides and have provided large variations of the original properties. Furthermore, the carrageenans have been used as backbones for crosslinking reactions as well as grafting to other polymeric molecules. These new biomaterials are of interest in the biomedical area, as they can be used for drug delivery and tissue engineering, among other uses. © 2016 by Nova Science Publishers, Inc. All rights reserved.

Registro:

Documento: Parte de libro
Título:Chemical modification of carrageenans and application of the modified products
Autor:Cosenza, V.A.; Navarro, D.A.; Stortz, C.A.
Filiación:Departamento de Química Orgánica - CIHIDECAR, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Buenos Aires, 1428, Argentina
Palabras clave:Alkaline treatment; Carrageenans; Chemical modifications; Grafting; Sulfation
Año:2016
Página de inicio:189
Página de fin:227
Título revista:Carrageenans: Sources and Extraction Methods, Molecular Structure, Bioactive Properties and Health Effects
Título revista abreviado:Carrageenans: Sources and Extraction Methods, Molecular Structure, Bioactive Properties and Health Effects
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97816348_v_n_p189_Cosenza

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Citas:

---------- APA ----------
Cosenza, V.A., Navarro, D.A. & Stortz, C.A. (2016) . Chemical modification of carrageenans and application of the modified products. Carrageenans: Sources and Extraction Methods, Molecular Structure, Bioactive Properties and Health Effects, 189-227.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97816348_v_n_p189_Cosenza [ ]
---------- CHICAGO ----------
Cosenza, V.A., Navarro, D.A., Stortz, C.A. "Chemical modification of carrageenans and application of the modified products" . Carrageenans: Sources and Extraction Methods, Molecular Structure, Bioactive Properties and Health Effects (2016) : 189-227.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97816348_v_n_p189_Cosenza [ ]
---------- MLA ----------
Cosenza, V.A., Navarro, D.A., Stortz, C.A. "Chemical modification of carrageenans and application of the modified products" . Carrageenans: Sources and Extraction Methods, Molecular Structure, Bioactive Properties and Health Effects, 2016, pp. 189-227.
Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97816348_v_n_p189_Cosenza [ ]
---------- VANCOUVER ----------
Cosenza, V.A., Navarro, D.A., Stortz, C.A. Chemical modification of carrageenans and application of the modified products. Carrageenans: Sources and Extraction Methods, Molecular Structure, Bioactive Properties and Health Effects. 2016:189-227.
Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97816348_v_n_p189_Cosenza [ ]