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Fernández-Prini, R.; Alvarez, J.L.; Harvey, A.H. "Aqueous solubility of volatile nonelectrolytes" (2004) Aqueous Systems at Elevated Temperatures and Pressures: Physical Chemistry in Water, Steam and Hydrothermal Solutions:73-98
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Abstract:

The solubilities of gases in water and their distribution between coexisting liquid and steam are of great interest for hydrothermal processes because gaseous solutes are usually present. For many geochemical and industrial processes in aqueous media, it is important to have a suitable formulation to describe the solubilities of gases over a wide range of temperatures and pressures. This chapter focuses on aqueous Henry's constants kH at high temperatures, as well as on the alternative description by means of the distribution equilibrium constant KD. These two quantities are easily determined from the experimental solubilities of gaseous solutes when the solvent is far from its critical point. The thermodynamic states along the liquid-vapor coexistence curve are particularly relevant to describe the solubility of slightly soluble gases in water. Hydrothermal systems often operate at total pressures above 5 MPa, while for many practical cases the partial pressure of the solute gas may be smaller than 0.1 MPa. Thus, the clear difference between the two fluid phases at ambient conditions is blurred to some extent in hydrothermal processes, and more so as the temperature approaches Tc1. A thorough thermodynamic analysis produces values of Henry's constant and of KD that depend only on temperature. The use of these quantities to answer questions about the concentration of gases in water or in steam at high temperature is simpler. The two experimental methods used to determine kH for volatile solutes are analytic and synthetic method. © Elsevier Ltd All rights reserved.

Registro:

Documento: Parte de libro
Título:Aqueous solubility of volatile nonelectrolytes
Autor:Fernández-Prini, R.; Alvarez, J.L.; Harvey, A.H.
Filiación:Unidad Actividad Química, Comisión Nacional de Energia Atómica, Av. Libertador 8250, Buenos Aires, 1429, Argentina
INQUIMAE, Ftd. Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón II, Buenos Aires, 1428, Argentina
Universidad Tecnológica Nacional, Facultad Regional Buenos Aires, Medrano 951, Buenos Aires, 1179, Argentina
Physical and Chemical Properties Division, National Institute of Standards and Technology, 325 Broadway, Boulder, CO 80305, United States
Palabras clave:Binary mixtures; Diffusion in gases; Equilibrium constants; Solubility; Thermoanalysis; Ambient conditions; Experimental methods; Hydrothermal process; Hydrothermal system; Industrial processs; Liquid-vapor coexistence curve; Thermo dynamic analysis; Thermodynamic state; Temperature
Año:2004
Página de inicio:73
Página de fin:98
DOI: http://dx.doi.org/10.1016/B978-012544461-3/50004-1
Título revista:Aqueous Systems at Elevated Temperatures and Pressures: Physical Chemistry in Water, Steam and Hydrothermal Solutions
Título revista abreviado:Aqueous Syst. at Elev. Temp. and Pressures: Phys. Chem. in Water, Steam and Hydrothermal Solut.
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_97800804_v_n_p73_FernandezPrini

Referencias:

  • Aasberg-Petersen, K., Stenby, E., Fredenslund, A., (1991) Ind. Eng. Chem. Res., 30, pp. 2180-2185
  • Alvarez, J.L., Fernández-Prini, R., (1991) Fluid Phase Equilib., 66, pp. 309-326
  • Alvarez, J.L., Corti, H.R., Fernández-Prini, R., Japas, M.L., (1994) Geochim. Cosmochim. Acta, 58, pp. 2789-2798
  • Alvarez, J.L., Fernández-Prini, R., Japas, M.L., (2000) Ind. Eng. Chem. Res., 39, pp. 3625-3630
  • Battino, R., (1989) Rev. Anal. Chem., 9, pp. 131-149
  • Benson, B.B., Krause, D., Peterson, M.A., (1979) J. Solution Chem., 8, pp. 655-690
  • Bieling, B., Kurz, F., Rumpf, B., Maurer, G., (1995) Ind. Eng. Chem. Res., 34, pp. 1449-1460
  • Chang, R.F., Levelt Sengers, J.M.H., (1986) J. Phys. Chem., 90, pp. 5921-5927
  • Clever, H.L., (1983) J. Chem. Eng. Data, 28, pp. 340-343
  • Crovetto, R., Fernández-Prini, R., Japas, M.L., (1984) Ber. Bunsenges. Phys. Chem., 88, pp. 484-488
  • Edwards, T.J., Maurer, G., Newman, J., Prausnitz, J.M., (1978) AIChE J., 24, pp. 966-976
  • Fernández-Prini, R., Crovetto, R., (1985) AIChE J., 31, pp. 513-516
  • Fernández-Prini, R., Crovetto, R., (1989) J. Phys. Chem. Ref. Data, 18, pp. 1231-1243
  • Fernández-Prini, R., Japas, M.L., (1994) Chem. Soc. Rev., 23, pp. 155-163
  • Fernández-Prini, R., Corti, H.R., Japas, M.L., (1992) High-Temperature Aqueous Solutions: Thermodynamic Properties, , chapter 2, CRC Press, Cambridge
  • Fernández-Prini, R., Alvarez, J.L., Harvey, A.H., (2003) J. Phys. Chem. Ref. Data, 32, pp. 903-916
  • Harvey, A.H., (1996) AIChE J., 42, pp. 1491-1494
  • Harvey, A.H., Levelt Sengers, J.M.H., (1990) AIChE J., 36, pp. 539-546
  • Harvey, A.H., Prausnitz, J.M., (1989) AIChE J., 35, pp. 635-644
  • Harvey, A.H., Crovetto, R., Levelt Sengers, J.M.H., (1990) AIChE J., 36, pp. 1901-1904
  • Japas, M.L., Levelt Sengers, J.M.H., (1989) AIChE J., 35, pp. 705-713
  • Jin, G., Donohue, M.D., (1988) Ind. Eng. Chem. Res., 27, pp. 1073-1084
  • Kosinski, J.J., Anderko, A., (2001) Fluid Phase Equilib., 183, pp. 75-86
  • Kulkujan, J., Alvarez, J.L., Fernández-Prini, R., (1999) J. Chem. Thermodyn., 31, pp. 1511-1522
  • Lee, J.I., Mather, A.E., (1977) Ber. Bunsenges. Phys. Chem., 81, pp. 1020-1023
  • Li, J., Topphoff, M., Fischer, K., Gmehling, J., (2001) Ind. Eng. Chem. Res., 40, pp. 3703-3710
  • Lindsay, W.T., Physical Chemistry of Aqueous Systems: Meeting the Needs of Industry (1995) Proceedings of the 12th International Conference on the Properties of Water and Steam, pp. 669-676. , Begell House, Boca Raton, FL, H.J. White, J.V. Sengers, D.B. Neumann, J.C. Bellows (Eds.)
  • Long, F.A., McDevit, W.F., (1952) Chem. Rev., 51, pp. 119-169
  • Masterton, W.L., Bolocofsky, D., Lee, T.P., (1971) J. Phys. Chem., 75, pp. 2809-2815
  • Morris, D.R., Yang, L., Giraudeau, F., Sun, X., Steward, F.R., (2001) Phys. Chem. Chem. Phys., 3, pp. 1043-1046
  • Morrison, T.J., Billett, F., (1952) J. Chem. Soc. (London), pp. 3819-3822
  • O'Connell, J.P., Phase Equilibria and Fluid Properties in the Chemical Industries (1977) ACS Symposium Series 60, pp. 490-497. , T.S. Storvick, S.I. Sandler (Eds.)
  • Pawlikowski, E.M., Prausnitz, J.M., (1983) Ind. Eng. Chem. Fundam., 22, pp. 86-90
  • Peng, D.Y., Robinson, D.B., (1976) Ind. Eng. Chem. Fundam., 15, pp. 59-64
  • Peng, D.Y., Robinson, D.B., Thermodynamics of Aqueous Systems with Industrial Applications (1980) ACS Symposium Series 133, pp. 393-414. , S.A. Newman (Ed.)
  • Plyasunov, A.V., O'Connell, J.P., Wood, R.H., (2000) Geochim. Cosmochim. Acta, 64, pp. 495-512
  • Potter, R.W., Clynne, M.A., (1978) J. Solution Chem., 7, pp. 837-844
  • Pray, H.A., Schweikert, C.E., Minnich, B.M., (1952) Ind. Eng. Chem., 44, pp. 1146-1151
  • Rafal, M., Berthold, J.W., Scrivner, N.C., Grice, S.L., (1995) Models for Thermodynamic and Phase Equilibria Calculations, pp. 601-670. , Marcel Dekker, New York, S.I. Sandler (Ed.)
  • Rettich, T.R., Battino, R., Wilhelm, E., (2000) J. Chem. Thermodyn., 32, pp. 1145-1156
  • Sedlbauer, J., O'Connell, J.P., Wood, R.H., (2000) Chem. Geol., 163, pp. 43-63
  • Takenouchi, S., Kennedy, G.C., (1964) Am. J. Sci., 262, pp. 1055-1074
  • Vanderbeken, I., Ye, S., Bouyssiere, B., Carrier, H., Xans, P., (1999) High Temp. High Pressure, 31, pp. 653-663
  • Wagner, W., Pruss, A., (1993) J. Phys. Chem. Ref. Data, 22, pp. 783-787
  • Weisenberger, S., Schumpe, A., (1996) AIChE J., 42, pp. 298-300
  • Wiebe, R., Gaddy, V.L., (1939) J. Am. Chem. Soc., 61, pp. 315-319
  • Wiebe, R., Gaddy, V.L., (1940) J. Am. Chem. Soc., 62, pp. 815-817
  • Wiebe, R., Gaddy, V.L., Heins, C., (1933) J. Am. Chem. Soc., 55, pp. 947-953
  • Wilson, G.M., Eng, W.W.Y., GPSWAT: GPA Sour Water Equilibria Correlation and Computer Program (1990) GPA Research Report RR-118, , Gas Processors Association, New York
  • Wu, J., Prausnitz, J.M., (1998) Ind. Eng. Chem. Res., 37, pp. 1634-1643
  • Zhao, E., Lu, B.C.-Y., (1998) Ind. Eng. Chem. Res., 37, pp. 1619-1624
  • Zuo, Y.-X., Guo, T.-M., (1991) Chem. Eng. Sci., 46, pp. 3251-3258

Citas:

---------- APA ----------
Fernández-Prini, R., Alvarez, J.L. & Harvey, A.H. (2004) . Aqueous solubility of volatile nonelectrolytes. Aqueous Systems at Elevated Temperatures and Pressures: Physical Chemistry in Water, Steam and Hydrothermal Solutions, 73-98.
http://dx.doi.org/10.1016/B978-012544461-3/50004-1
---------- CHICAGO ----------
Fernández-Prini, R., Alvarez, J.L., Harvey, A.H. "Aqueous solubility of volatile nonelectrolytes" . Aqueous Systems at Elevated Temperatures and Pressures: Physical Chemistry in Water, Steam and Hydrothermal Solutions (2004) : 73-98.
http://dx.doi.org/10.1016/B978-012544461-3/50004-1
---------- MLA ----------
Fernández-Prini, R., Alvarez, J.L., Harvey, A.H. "Aqueous solubility of volatile nonelectrolytes" . Aqueous Systems at Elevated Temperatures and Pressures: Physical Chemistry in Water, Steam and Hydrothermal Solutions, 2004, pp. 73-98.
http://dx.doi.org/10.1016/B978-012544461-3/50004-1
---------- VANCOUVER ----------
Fernández-Prini, R., Alvarez, J.L., Harvey, A.H. Aqueous solubility of volatile nonelectrolytes. Aqueous Syst. at Elev. Temp. and Pressures: Phys. Chem. in Water, Steam and Hydrothermal Solut. 2004:73-98.
http://dx.doi.org/10.1016/B978-012544461-3/50004-1