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Abstract:

In this work we demonstrate the feasibility to couple adsorption with Fenton and photo-Fenton process to separate and mineralize crystal violet (CV) dissolved in water. Montmorillonite (MMT) and iron modified montmorillonite (MMT-Fe) were studied as adsorbents and heterogeneous catalysts for Fenton and photo-Fenton like oxidation of cationic dye CV. The clays were characterized by XRD, SEM, EDX, BET surface area and electrophoretic mobility. MMT-Fe presents iron in the interlayer space and oxohydroxide particles on its surface. Both clays present a high CV adsorption capacity that can be modeled by a two-site Langmuir equation. MMT-Fe oxidizes faster and have a higher mineralization rate of adsorbed CV than MMT with Fe(II) or Fe(III) added externally. The oxidation of the adsorbed dye release organics to the solution which are further mineralized in solution. The Fenton oxidation can be modeled by a double exponential decay and photo-Fenton oxidation by a pseudo-first order kinetic model. Photo-Fenton oxidation leads to higher mineralization rates than Fenton. © 2014 Elsevier Ltd. All rights reserved.

Registro:

Documento: Artículo
Título:Adsorption of crystal violet on montmorillonite (or iron modified montmorillonite) followed by degradation through Fenton or photo-Fenton type reactions
Autor:Guz, L.; Curutchet, G.; Torres Sánchez, R.M.; Candal, R.
Filiación:Instituto de Ingenieria e Investigación Ambiental, UNSAM, Av. 25 de Mayo y Francia, General San Martín, Provincia de Buenos Aires, 1650, Argentina
Centro de Tecnología de Recursos Minerales y Cerámica-CONICET, Camino Centenario y 506, M.B. Gonnet, Provincia de Buenos Aires, 1897, Argentina
Instituto de Química Física de Materiales Ambiente y Energía-CONICET, Ciudad Universitaria, Pabellón 2, Piso 3, Ciudad Autónoma de Buenos Aires, 1428, Argentina
Palabras clave:Adsorption; Crystal violet; Fenton; Montmorillonite; Photo-Fenton; Adsorption; Dyes; Electrophoretic mobility; Iron; Mineralogy; Oxidation; Adsorption capacities; Crystal violet; Fenton; Heterogeneous catalyst; Modified montmorillonite; Photo-Fenton; Photo-fenton oxidations; Pseudo-first order kinetic model; Clay minerals
Año:2014
Volumen:2
Número:4
Página de inicio:2344
Página de fin:2351
DOI: http://dx.doi.org/10.1016/j.jece.2014.02.007
Título revista:Journal of Environmental Chemical Engineering
Título revista abreviado:J. Environ. Chem. Eng.
ISSN:22133437
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_22133437_v2_n4_p2344_Guz

Referencias:

  • Forgacs, E., Cserháti, T., Oros, G., Removal of synthetic dyes from wastewaters: A review (2004) Environment International, 30, pp. 953-971
  • Dos Santos, A.B., Cervantes, F.J., Van Lier, J.B., Review paper on current technologies for decolourisation of textile wastewaters: Perspectives for anaerobic biotechnology (2007) Bioresource Technology, 98, pp. 2369-2385
  • Gupta, V.K., Suhas, Application of low-cost adsorbents for dye removal - A review (2009) Journal of Environmental Management, 90, pp. 2313-2342
  • Rauf, M.A., Salman Ashraf, S., Survey of recent trends in biochemically assisted degradation of dyes (2012) Chemical Engineering Journal, 209, pp. 520-530
  • Paszczynski, A., Pasti, M.B., Goszczynski, S., Crawford, D.L., Crawford, R.L., New approach to improve degradation of recalcitrant azo dyes by Streptomyces spp. and Phanerochaete chrysosporium (1991) Enzyme and Microbial Technology, 13, pp. 378-384
  • Camarero, S., Ibarra, D., Martínez, M.J., Martínez Á., T., (2005) Lignin-Derived Compounds As Efficient Laccase Mediators for Decolorization of Different Types of Recalcitrant Dyes, pp. 1775-1784
  • De Aragão Umbuzeiro, G., Freeman, H.S., Warren, S.H., De Oliveira, D.P., Terao, Y., Watanabe, T., Claxton, L.D., The contribution of azo dyes to the mutagenic activity of the Cristais River (2005) Chemosphere, 60, pp. 55-64
  • Carneiro, P.A., Umbuzeiro, G.A., Oliveira, D.P., Zanoni, M.V.B., Assessment of water contamination caused by a mutagenic textile effluent/dyehouse effluent bearing disperse dyes (2010) Journal of Hazardous Materials, 174, pp. 694-699
  • Chequer, F.M.D., Lizier, T.M., De Felício, R., Zanoni, M.V.B., Debonsi, H.M., Lopes, N.P., Marcos, R., De Oliveira, D.P., Analyses of the genotoxic and mutagenic potential of the products formed after the biotransformation of the azo dye Disperse Red 1 (2011) Toxicology in Vitro, 25, pp. 2054-2063
  • Zubair Alam, M., Ahmad, S., Malik, A., Ahmad, M., Mutagenicity and genotoxicity of tannery effluents used for irrigation at Kanpur, India (2010) Ecotoxicology and Environmental Safety, 73, pp. 1620-1628
  • Beydilli, M.I., Pavlostathis, S.G., Tincher, W.C., Decolorization and toxicity screening of selected reactive azo dyes under methanogenic conditions (1998) Water Science and Technology, 38, pp. 225-232
  • Wang, C., Yediler, A., Lienert, D., Wang, Z., Kettrup, A., Toxicity evaluation of reactive dyestuffs, auxiliaries and selected effluents in textile finishing industry to luminescent bacteria Vibrio fischeri (2002) Chemosphere, 46, pp. 339-344
  • Golka, K., Kopps, S., Myslak, Z.W., Carcinogenicity of azo colorants: Influence of solubility and bioavailability (2004) Toxicology Letters, 151, pp. 203-210
  • Jones, J.J., Falkinham, J.O., (2003) Decolorization of Malachite Green and Crystal Violet by Waterborne Pathogenic Mycobacteria, pp. 2323-2326
  • Alderman, D.J., Malachite green: A review (1985) Journal of Fish Diseases, 8, pp. 289-298
  • Andersen, W.C., Turnipseed, S.B., Karbiwnyk, C.M., Lee, R.H., Clark, S.B., Rowe, W.D., Madson, M.R., Miller, K.E., Multiresidue method for the triphenylmethane dyes in fish: Malachite green, crystal (gentian) violet, and brilliant green (2009) Analytica Chimica Acta, 637, pp. 279-289
  • Crini, G., Non-conventional low-cost adsorbents for dye removal: A review (2006) Bioresource Technology, 97, pp. 1061-1085
  • Wang, X.S., Zhang, W., Removal of basic dye crystal violet from aqueous solution by Cu(II)-loaded montmorillonite (2011) Separation Science and Technology, 46, pp. 656-663
  • Monash, P., Pugazhenthi, G., Removal of crystal violet dye from aqueous solution using calcined and uncalcined mixed clay adsorbents (2009) Separation Science and Technology, 45, pp. 94-104
  • Wei, J., Zhu, R., Zhu, J., Ge, F., Yuan, P., He, H., Ming, C., Simultaneous sorption of crystal violet and 2-naphthol to bentonite with different CECs (2009) Journal of Hazardous Materials, 166, pp. 195-199
  • Neyens, E., Baeyens, J., A review of classic Fenton's peroxidation as an advanced oxidation technique (2003) Journal of Hazardous Materials, 98, pp. 33-50
  • Pignatello, J.J., Oliveros, E., Mackay, A., Advanced oxidation processes for organic contaminant destruction based on the Fenton reaction and related chemistry (2006) Critical Reviews in Environmental Science and Technology, 36, pp. 1-84
  • Ay, F., Catalkaya, E.C., Kargi, F., A statistical experiment design approach for advanced oxidation of Direct Red azo-dye by photo-Fenton treatment (2009) Journal of Hazardous Materials, 162, pp. 230-236
  • Fan, H.-J., Huang, S.-T., Chung, W.-H., Jan, J.-L., Lin, W.-Y., Chen, C.-C., Degradation pathways of crystal violet by Fenton and Fenton-like systems: Condition optimization and intermediate separation and identification (2009) Journal of Hazardous Materials, 171, pp. 1032-1044
  • Baldrian, P., Merhautová, V., Gabriel, J., Nerud, F., Stopka, P., Hrubý, M., Beneš, M.J., Decolorization of synthetic dyes by hydrogen peroxide with heterogeneous catalysis by mixed iron oxides (2006) Applied Catalysis B: Environmental, 66, pp. 258-264
  • Soon, A.N., Hameed, B.H., Heterogeneous catalytic treatment of synthetic dyes in aqueous media using Fenton and photo-assisted Fenton process (2011) Desalination, 269, pp. 1-16
  • Herney-Ramirez, J., Vicente, M.A., Madeira, L.M., Heterogeneous photo-Fenton oxidation with pillared clay-based catalysts for wastewater treatment: A review (2010) Applied Catalysis B: Environmental, 98, pp. 10-26
  • Chen, Q., Wu, P., Li, Y., Zhu, N., Dang, Z., Heterogeneous photo-Fenton photodegradation of reactive brilliant orange X-GN over iron-pillared montmorillonite under visible irradiation (2009) Journal of Hazardous Materials, 168, pp. 901-908
  • Gallard, H., De Laat, J., Legube, B., Spectrophotometric study of the formation of iron(III)-hydroperoxy complexes in homogeneous aqueous solutions (1999) Water Research, 33, pp. 2929-2936
  • Bossmann, S.H., Oliveros, E., Göb, S., Siegwart, S., Dahlen, E.P., Payawan, L., Straub, M., Braun, A.M., New evidence against hydroxyl radicals as reactive intermediates in the thermal and photochemically enhanced Fenton reactions (1998) Journal of Physical Chemistry A, 102, pp. 5542-5550
  • Magnoli, A.P., Tallone, L., Rosa, C.A.R., Dalcero, A.M., Chiacchiera, S.M., Torres Sanchez, R.M., Commercial bentonites as detoxifier of broiler feed contaminated with aflatoxin (2008) Applied Clay Science, 40, pp. 63-71
  • Komlósi, A., Kuzmann, E., Nagy, N.M., Homonnay, Z., Kubuki, S., Kónya, J., (2007) Incorporation of Fe in the Interlayer of Na-Montmorillonite Via Treatment with FeCl3 in Acetone, pp. 89-95
  • Li, T.-S., Zhang, Z.-H., Gao, Y.-J., A rapid preparation of acylals of aldehydes catalysed by Fe3+-montmorillonite (1998) Synthetic Communications, 28, pp. 4665-4671
  • Nguyen-Thanh, D., Block, K., Bandosz, T.J., Adsorption of hydrogen sulfide on montmorillonites modified with iron (2005) Chemosphere, 59, pp. 343-353
  • Borgnino, L., Avena, M.J., De Pauli, C.P., Synthesis and characterization of Fe(III)-montmorillonites for phosphate adsorption (2009) Colloids and Surfaces A: Physicochemical and Engineering Aspects, 341, pp. 46-52
  • Chen, J.P., Hausladen, M.C., Yang, R.T., Delaminated Fe2O3-pillared clay: Its preparation, characterization, and activities for selective catalytic reduction of NO by NH3 (1995) Journal of Catalysis, 151, pp. 135-146
  • Luengo, C., Puccia, V., Avena, M., Arsenate adsorption and desorption kinetics on a Fe(III)-modified montmorillonite (2011) Journal of Hazardous Materials, 186, pp. 1713-1719
  • Michot, L., Masion, I.A., Thomas, F., Mechanism of adsorption and desorption of water vapor by homoionic montmorillonites: 2. The Li+, Na+, K+, Rb+ and Cs+-exchanged forms (1995) Clays and Clay Minerals, 43, pp. 324-336
  • Koresh, J., Soffer, A., Application of the two-site Langmuir isotherm to microporous adsorbents (1983) Journal of Colloid and Interface Science, 92, pp. 517-524
  • Gordon, T., Marsh, A., Temperature dependence of the oxidation of 2-chlorophenol by hydrogen peroxide in the presence of goethite (2009) Catalysis Letters, 132, pp. 349-354
  • Chen, J., Zhu, L., Comparative study of catalytic activity of different Fe-pillared bentonites in the presence of UV light and H2O2 (2009) Separation and Purification Technology, 67, pp. 282-288
  • Ramirez, J.H., Duarte, F.M., Martins, F.G., Costa, C.A., Madeira, L.M., Modelling of the synthetic dye Orange II degradation using Fenton's reagent: From batch to continuous reactor operation (2009) Chemical Engineering Journal, 148, pp. 394-404
  • Ramirez, J.H., Costa, C.A., Madeira, L.M., Experimental design to optimize the degradation of the synthetic dye Orange II using Fenton's reagent (2005) Catalysis Today, 107-108, pp. 68-76
  • Malik, P.K., Saha, S.K., Oxidation of direct dyes with hydrogen peroxide using ferrous ion as catalyst (2003) Separation and Purification Technology, 31, pp. 241-250
  • González-Bahamón, L.F., Hoyos, D.F., Benítez, N., Pulgarín, C., New Fe-immobilized natural bentonite plate used as photo-Fenton catalyst for organic pollutant degradation (2011) Chemosphere, 82, pp. 1185-1189

Citas:

---------- APA ----------
Guz, L., Curutchet, G., Torres Sánchez, R.M. & Candal, R. (2014) . Adsorption of crystal violet on montmorillonite (or iron modified montmorillonite) followed by degradation through Fenton or photo-Fenton type reactions. Journal of Environmental Chemical Engineering, 2(4), 2344-2351.
http://dx.doi.org/10.1016/j.jece.2014.02.007
---------- CHICAGO ----------
Guz, L., Curutchet, G., Torres Sánchez, R.M., Candal, R. "Adsorption of crystal violet on montmorillonite (or iron modified montmorillonite) followed by degradation through Fenton or photo-Fenton type reactions" . Journal of Environmental Chemical Engineering 2, no. 4 (2014) : 2344-2351.
http://dx.doi.org/10.1016/j.jece.2014.02.007
---------- MLA ----------
Guz, L., Curutchet, G., Torres Sánchez, R.M., Candal, R. "Adsorption of crystal violet on montmorillonite (or iron modified montmorillonite) followed by degradation through Fenton or photo-Fenton type reactions" . Journal of Environmental Chemical Engineering, vol. 2, no. 4, 2014, pp. 2344-2351.
http://dx.doi.org/10.1016/j.jece.2014.02.007
---------- VANCOUVER ----------
Guz, L., Curutchet, G., Torres Sánchez, R.M., Candal, R. Adsorption of crystal violet on montmorillonite (or iron modified montmorillonite) followed by degradation through Fenton or photo-Fenton type reactions. J. Environ. Chem. Eng. 2014;2(4):2344-2351.
http://dx.doi.org/10.1016/j.jece.2014.02.007