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Abstract:

We report herein the synthesis, crystallographic analysis and a study of the non-covalent interactions observed in the new 4′-substituted terpyridine-based derivative bis[4′-(isoquinolin-2-ium-4-yl)-4,2′:6′,4′′-terpyridine-1,1′′-diium] tris-[tetrachloridozincate(II)], (C24H19N4)2[ZnCl4]3 or (44TPH3)2[ZnCl4]3, where (44TPH3)3+ is the triply protonated cation 4′-(isoquinolinium-4-yl)-4,2′:6′,4′′ terpyridinium. The compound is similar in its formulation to the recently reported 2,2′:6′,2′′ terpyridinium analogue {bis[4′-(isoquinolin-2-ium-4-yl)-2,2′:6′,2′′-terpyridine-1,1′′-diium] tris[tetrachloridozincate(II)] monohydrate; Granifo et al. (2017). Acta Cryst. C73, 1121-1130}, although rather different and much simpler in its structural features, mainly in the number and type of non-covalent interactions present, as well as in the supramolecular structure they define. © 2018 International Union of Crystallography. All rights reserved.

Registro:

Documento: Artículo
Título:The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion
Autor:Granifo, J.; Suárez, S.; Baggio, R.
Filiación:Departamento de Ciencias Químicas y Recursos Naturales, Facultad de Ingeniería y Ciencias, Universidad de la Frontera, Casilla 54-D, Temuco, Chile
Departamento de Química Inorgánica, Analítica y Química, Física/INQUIMAE-CONICET, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina
Palabras clave:Anion⋯π interactions; crystal structure; Hirshfeld surfaces; terpyridine
Año:2018
Volumen:74
Página de inicio:1881
Página de fin:1886
DOI: http://dx.doi.org/10.1107/S2056989018016250
Título revista:Acta Crystallographica Section E: Crystallographic Communications
Título revista abreviado:Acta Crystallographica Section E: Crystallographic Communications
ISSN:20569890
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20569890_v74_n_p1881_Granifo

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Citas:

---------- APA ----------
Granifo, J., Suárez, S. & Baggio, R. (2018) . The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion. Acta Crystallographica Section E: Crystallographic Communications, 74, 1881-1886.
http://dx.doi.org/10.1107/S2056989018016250
---------- CHICAGO ----------
Granifo, J., Suárez, S., Baggio, R. "The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion" . Acta Crystallographica Section E: Crystallographic Communications 74 (2018) : 1881-1886.
http://dx.doi.org/10.1107/S2056989018016250
---------- MLA ----------
Granifo, J., Suárez, S., Baggio, R. "The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion" . Acta Crystallographica Section E: Crystallographic Communications, vol. 74, 2018, pp. 1881-1886.
http://dx.doi.org/10.1107/S2056989018016250
---------- VANCOUVER ----------
Granifo, J., Suárez, S., Baggio, R. The enrichment ratio of atomic contacts in the crystal structure of isomeric, triply protonated, 4′-functionalized terpyridine cations with [ZnCl4]2- as counter-ion. Acta Crystallographica Section E: Crystallographic Communications. 2018;74:1881-1886.
http://dx.doi.org/10.1107/S2056989018016250