Abstract:
A nickel(II) coordination complex, bis[2,6-bis(1H-benzimidazol-2-yl-κN3)pyridine-κN]nickel(II) sulfate, [Ni(C19H13N5)2]SO4 or [Ni(H2L)2]SO4, having four peripheral tetrahedrally oriented N - H donor units, combines with sulfate bridges to create hydrogen-bonded structures of varied dimensionality. The three crystal structures reported herein in the space groups P212121, I and Pccn are defined solely by strong charge-assisted N - H...O hydrogen bonds and contain disordered guests (water and dimethylformamide) that vary in size, shape and degree of hydrophilicity. Two of the compounds are channelled solids with three-dimensional structures, while the third is one-dimensional in nature. In spite of their differences, all three present a striking resemblance to the previously reported anhydrous relative [Guo et al. (2011). Chin. J. Inorg. Chem.27, 1517-1520], which is considered as the reference framework from which all three title compounds are derived. The hydrogen-bonded frameworks are described and compared using crystallographic and topological approaches. © International Union of Crystallography, 2018.
Registro:
Documento: |
Artículo
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Título: | Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion |
Autor: | Harvey, M.A.; Suarez, S.; Zolotarev, P.N.; Proserpio, D.M.; Baggio, R. |
Filiación: | Universidad Nacional de la Patagonia, Sede Trelew, Trelew, Chubut, 9100, Argentina CenPat, CONICET, Puerto Madryn, Chubut, 9120, Argentina Departamento de Química Inorgánica, Analítica y Química, Física/INQUIMAE-CONICET, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina Samara Center for Theoretical Materials Science (SCTMS), Samara State Technical University, Molodogvardeyskaya St. 244, Samara, 443100, Russian Federation Dipartimento di Chimica, Università degli Studi di Milano, Via C. Golgi 19, Milano, 20133, Italy Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina
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Palabras clave: | crystal structure; hydrogen-bonded porous structures; sulfate bridge; topological analysis; Complexation; Coordination reactions; Crystal structure; Nickel; Nickel sulfates; Sulfur compounds; Topology; Coordination complex; Hydrogen-bonded structures; Porous structures; Reference frameworks; Three-dimensional structure; Title compounds; Topological analysis; Topological approach; Hydrogen bonds |
Año: | 2018
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Volumen: | 74
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Número: | 3
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Página de inicio: | 351
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Página de fin: | 359
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DOI: |
http://dx.doi.org/10.1107/S2053229618002413 |
Título revista: | Acta Crystallographica Section C: Structural Chemistry
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Título revista abreviado: | Acta crystallogr., C Struct. Chem.
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ISSN: | 20532296
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CODEN: | ACSCG
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20532296_v74_n3_p351_Harvey |
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Citas:
---------- APA ----------
Harvey, M.A., Suarez, S., Zolotarev, P.N., Proserpio, D.M. & Baggio, R.
(2018)
. Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion. Acta Crystallographica Section C: Structural Chemistry, 74(3), 351-359.
http://dx.doi.org/10.1107/S2053229618002413---------- CHICAGO ----------
Harvey, M.A., Suarez, S., Zolotarev, P.N., Proserpio, D.M., Baggio, R.
"Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion"
. Acta Crystallographica Section C: Structural Chemistry 74, no. 3
(2018) : 351-359.
http://dx.doi.org/10.1107/S2053229618002413---------- MLA ----------
Harvey, M.A., Suarez, S., Zolotarev, P.N., Proserpio, D.M., Baggio, R.
"Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion"
. Acta Crystallographica Section C: Structural Chemistry, vol. 74, no. 3, 2018, pp. 351-359.
http://dx.doi.org/10.1107/S2053229618002413---------- VANCOUVER ----------
Harvey, M.A., Suarez, S., Zolotarev, P.N., Proserpio, D.M., Baggio, R. Topological study of diverse hydrogen-bonded patterns found in a system of a nickel(II) complex and the sulfate anion. Acta crystallogr., C Struct. Chem. 2018;74(3):351-359.
http://dx.doi.org/10.1107/S2053229618002413