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Abstract:

Among the potential applications of coordination polymers, electrical conductivity ranks high in technological interest. We report the synthesis, crystal structure and spectroscopic analysis of an AgI-thiosaccharinate one-dimensional coordination polymer {systematic name: Catena-poly[[[aquatetrakis(μ3-1,1-dioxo-1,2-benzisothiazole-3-thiolato-κ3N:S3:S3)tetrasilver(I)]-μ2-4,4′-(propane-1,3-diyl)dipyridine-κ2N:N′] dimethyl sulfoxide hemisolvate]}, {[Ag4(C7H4NO2S2)4(C13H14N2)(H2O)]·0.5C2H6OS}n, with the 4,4′-(propane-1,3-diyl)dipyridine ligand acting as a spacer. A relevant feature of the structure is the presence of an unusually short Ag.Ag distance of 2.8306'(9)'Å, well within the range of argentophilic interactions, confirmed experimentally as such by a Raman study on the low-frequency spectrum, and corroborated theoretically by an Atoms in Molecules (AIM) analysis of the calculated electron density. Electrical conductivity measurements show that this complex can act as a semiconductor with moderate conductivity.A one-dimensional polymeric silver thiosaccharinate complex displays an unusually short Ag.Ag distance of 2.830Å. The crystal structure consists of weakly interacting columns. The complex behaves as a semiconductor, with a moderately low conductivity. © 2018 International Union of Crystallography.

Registro:

Documento: Artículo
Título:Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions:
Autor:Dennehy, M.; Amo-Ochoa, P.; Freire, E.; Suárez, S.; Halac, E.; Baggio, R.
Filiación:Departamento de Química, Universidad Nacional Del sur, Bahiá Blanca, Argentina
Departamento de Química Inorgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Madrid, Spain
Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energiá Atómica, Buenos Aires, Argentina
Escuela de Ciencia y Tecnologiá, Universidad Nacional General San Martín, Buenos Aires, Argentina
Departamento de Química Inorgánica, Analítica y Química, Física/INQUIMAE, CONICET, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Palabras clave:argentophilic interaction; electrical propertiescrystal structure; low conductivity semiconductor; one-dimensional coordination polymer; silver(I) polymeric structure; Chelation; Coordination reactions; Crystal atomic structure; Dimethyl sulfoxide; Electric conductivity; Polymers; Polyols; Propane; Silver; Silver compounds; Spectroscopic analysis; Argentophilic interaction; Coordination Polymers; Electrical conductivity; Electrical conductivity measurements; Low conductivity; Low-frequency spectra; One-dimensional coordination polymer; Polymeric structures; Crystal structure; coordination compound; ligand; polymer; saccharin; silver; analogs and derivatives; chemical model; chemical structure; chemistry; electric conductivity; quantum theory; synthesis; X ray crystallography; Coordination Complexes; Crystallography, X-Ray; Electric Conductivity; Ligands; Models, Chemical; Molecular Structure; Polymers; Quantum Theory; Saccharin; Silver
Año:2018
Volumen:74
Número:2
Página de inicio:186
Página de fin:193
DOI: http://dx.doi.org/10.1107/S2053229618000128
Título revista:Acta Crystallographica Section C: Structural Chemistry
Título revista abreviado:Acta crystallogr., C Struct. Chem.
ISSN:20532296
CODEN:ACSCG
CAS:saccharin, 81-07-2; silver, 7440-22-4; Coordination Complexes; Ligands; Polymers; Saccharin; Silver
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20532296_v74_n2_p186_Dennehy

Referencias:

  • Bader, R.F.W., (1990) Atoms in Molecules-a Quantum Theory, , Oxford University Press
  • Becke, A.D., (1988) Phys. Rev. A, 38, pp. 3098-3100
  • Becke, A.D., (1993) J. Chem. Phys., 98, pp. 5648-5652
  • Bondi, A., (1964) J. Phys. Chem., 68, pp. 441-451
  • Brown, I.D., (2002) The Chemical Bond in Inorganic Chemistry: The Bond Valence Model, , Oxford University Press
  • Burrow, R.A., Belmonte, G.Z., Dorn, V., Dennehy, M., (2016) Inorg. Chim. Acta, 450, pp. 39-49
  • Cao, X.Y., Dolg, M., (2002) J. Mol. Struct. Theochem, 581, pp. 139-147
  • Castiñeiras, A., (2006) Polyhedron, 25, pp. 3653-3660
  • Dennehy, M., Delgado, F., Freire, E., Halac, E., Baggio, R., (2016) Acta Cryst. C, 72, pp. 572-577
  • Dennehy, M., Ferullo, R.M., Quinzani, O.V., Mandolesi, S.D., Castellani, N., Jennings, M., (2008) Polyhedron, 27, pp. 2243-2250
  • Dennehy, M., Quinzani, O.V., Granados, A., Burrow, R.A., (2010) Polyhedron, 29, pp. 1344-1352
  • Dennehy, M., Quinzani, O.V., Jennings, M., (2007) J. Mol. Struct., 841, pp. 110-117
  • Ditchfield, R., Hehre, W.J., Pople, J.A., (1971) J. Chem. Phys., 54, pp. 724-728
  • Fuentealba, P., Preuss, H., Stoll, H., Szentpaly, L., (1989) Chem. Phys. Lett., 89, pp. 418-422
  • Givaja, G., Amo-Ochoa, P., Gómez-Garcá, C.J., Zamora, F., (2012) Chem. Soc. Rev., 41, pp. 115-147
  • Groom, C.R., Bruno, I.J., Lightfoot, M.P., Ward, S.C., (2016) Acta Cryst. B, 72, pp. 171-179
  • Harvey, P.D., (1996) Coord. Chem. Rev., 153, pp. 175-198
  • Jansen, M., (1987) Angew. Chem., 99, pp. 1136-1149
  • Kristiansson, O., (2001) Inorg. Chem., 40, pp. 5058-5059
  • Lamming, G., Kolokotroni, J., Harrison, T., Penfold, T.J., Clegg, W., Waddell, P.G., Probert, M.R., Houlton, A., (2017) Cryst. Growth Des., 17, pp. 5935-5944
  • Lu, T., Chen, F., (2012) J. Comput. Chem., 33, pp. 580-592
  • Martina, I., Wiesinger, R., Jembrih-Simbürger, D., Schreiner, M., (2012) E-Preserv. Sci., 9, pp. 1-8
  • Morishima, Y., Young, D.J., Fujisawa, K., (2014) Dalton Trans., 43, pp. 15915-15928
  • Rassolov, V.A., Ratner, M.A., Pople, J.A., Redfern, P.C., Curtiss, L.A., (2001) J. Comput. Chem., 22, pp. 976-984
  • Rigaku, O.D., (2015) CrysAlis PRO, , Rigaku Oxford Diffraction Yarnton Oxfordshire England
  • Schmidbaur, H., Schier, A., (2015) Angew. Chem. Int. Ed., 54, pp. 746-784
  • Schwerdtfeger, P., Dolg, M., Schwarz, W.H.E., Bowmaker, G.A., Boyd, P.D.W.J., (1989) Chem. Phys., 91, pp. 1762-1774
  • Serpe, A., Artizzu, F., Marchio, L., Mercuri, M.L., Pilia, L., Deplano, P., (2001) Cryst. Growth Des., 2011, pp. 1278-1286
  • Sheldrick, G.M., (2008) Acta Cryst. A, 64, pp. 112-122
  • Sheldrick, G.M., (2015) Acta Cryst. C, 71, pp. 3-8
  • Spek, A.L., (2009) Acta Cryst. D, 65, pp. 148-155
  • Su, W.P., Hong, M.C., Weng, J.B., Cao, R., Lu, S., (2000) Angew. Chem. Int. Ed., 39, pp. 2911-2914

Citas:

---------- APA ----------
Dennehy, M., Amo-Ochoa, P., Freire, E., Suárez, S., Halac, E. & Baggio, R. (2018) . Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions:. Acta Crystallographica Section C: Structural Chemistry, 74(2), 186-193.
http://dx.doi.org/10.1107/S2053229618000128
---------- CHICAGO ----------
Dennehy, M., Amo-Ochoa, P., Freire, E., Suárez, S., Halac, E., Baggio, R. "Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions:" . Acta Crystallographica Section C: Structural Chemistry 74, no. 2 (2018) : 186-193.
http://dx.doi.org/10.1107/S2053229618000128
---------- MLA ----------
Dennehy, M., Amo-Ochoa, P., Freire, E., Suárez, S., Halac, E., Baggio, R. "Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions:" . Acta Crystallographica Section C: Structural Chemistry, vol. 74, no. 2, 2018, pp. 186-193.
http://dx.doi.org/10.1107/S2053229618000128
---------- VANCOUVER ----------
Dennehy, M., Amo-Ochoa, P., Freire, E., Suárez, S., Halac, E., Baggio, R. Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions:. Acta crystallogr., C Struct. Chem. 2018;74(2):186-193.
http://dx.doi.org/10.1107/S2053229618000128