Abstract:
Despite the large number of reported crystalline structures of coordination complexes bearing pyridines as ligands, the relevance of π-π interactions among these hereroaromatic systems in the stabilization of their supramolecular structures and properties is not very well documented in the recent literature. The title compound, [CoCl2(C5H6N2)2], was obtained as bright-blue crystals suitable for single-crystal X-ray diffraction analysis from the reaction of 4-aminopyridine with cobalt(II) chloride in ethanol. The new complex was fully characterized by a variety of spectroscopic techniques and single-crystal X-ray diffraction. The crystal structure showed a tetrahedral complex stabilized mainly by bidimensional motifs constructed by π-π interactions with large horizontal displacements between the 4-aminopyridine units, and N - H...Cl hydrogen bonds. Other short contacts, such as C - H...Cl interactions, complete the three-dimensional arrangement. The supramolecular investigation was extended by statistical studies using the Cambridge Structural Database and a Hirshfeld surface analysis.A new cobalt(II) pyridine-based coordination compound showing π-π interactions with large horizontal displacements between the 4-aminopyridine ligands and N - H...Cl and C - H...Cl hydrogen bonds is reported. The molecular and supramolecular structures have been studied in detail and compared with those of similar complexes found in a search of the Cambridge Structural Database. The supramolecular structure was also investigated by Hirshfeld surface analysis. © International Union of Crystallography, 2017.
Registro:
Documento: |
Artículo
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Título: | Synthesis, crystal structure and study of the crystal packing in the complex bis(4-aminopyridine-κN1)dichloridocobalt(II) |
Autor: | Sanchez Montilva, O.C.; Movilla, F.; Rodriguez, M.G.; Di Salvo, F. |
Filiación: | Departamento de Química Inorgánica, Analítica y Química Física/INQUIMAE-CONICET, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Intendente Güiraldes 2160, Buenos Aires, Argentina
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Palabras clave: | 4-aminopyridine; cobalt complex; crystal structure; fingerprint plots; Hirshfeld analysis; pyridine-pyridine dimer; π-π stacking; Cobalt; Cobalt compounds; Complexation; Coordination reactions; Dimers; Hydrogen bonds; Ligands; Pyridine; Single crystals; Supramolecular chemistry; Surface analysis; X ray diffraction analysis; Chlorine compounds; 4-Aminopyridine; Cambridge Structural Databases; Cobalt complexes; fingerprint plots; Hirshfeld analysis; Horizontal displacements; Single crystal x-ray diffraction; Single crystal X-ray diffraction analysis; Supramolecular structure; Crystal structure |
Año: | 2017
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Volumen: | 73
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Número: | 5
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Página de inicio: | 399
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Página de fin: | 406
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DOI: |
http://dx.doi.org/10.1107/S2053229617004880 |
Título revista: | Acta Crystallographica Section C: Structural Chemistry
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Título revista abreviado: | Acta crystallogr., C Struct. Chem.
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ISSN: | 20532296
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CODEN: | ACSCG
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20532296_v73_n5_p399_SanchezMontilva |
Referencias:
- (2013) CrysAlis PRO, , Agilent Agilent Technologies Ltd, Yarnton, Oxfordshire, England
- Bacchi, A., Cantoni, G., Crocco, D., Granelli, M., Pagano, P., Pelagatti, P., (2014) Cryst Eng Comm, 16, pp. 1001-1009
- Brown, D.J., (1985) The Chemistry of Heterocyclic Compounds: Pyridine Metal Complexes, , New York Wiley
- Bruno, I.J., Cole, J.C., Edgington, P.R., Kessler, M., Macrae, C.F., McCabe, P., Pearson, J., Taylor, R., (2002) Acta Cryst, B58, pp. 389-397
- Bruno, I.J., Cole, J.C., Kessler, M., Luo, J., Motherwell, W.D.S., Purkis, L.H., Smith, B.R., Orpen, A.G., (2005) J. Chem. Inf. Comput. Sci, 44, pp. 2133-2144
- Bujak, M., (2015) Cryst. Growth des, 15, pp. 1295-1302
- Chi, Y., Chou, P.T., (2007) Chem. Soc. Rev, 36, pp. 1421-1431
- Clarke, P.J., Milledge, H.J., (1975) Acta Cryst, B31, pp. 1543-1553
- Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., Puschmann, H., (2009) J. Appl. Cryst, 42, pp. 339-341
- Férey, G., (2008) Chem. Soc. Rev, 37, pp. 191-214
- Gill, N.S., Nyholm, R.S., (1961) J. Inorg. Nucl. Chem, 18, pp. 88-97
- Groom, C.R., Bruno, I.J., Lightfoot, M.P., Ward, S.C., (2016) Acta Cryst, B72, pp. 171-179
- Hardy, J.G., (2013) Chem. Soc. Rev, 42, pp. 7881-7899
- Hirshfeld, F.L., (1977) Theor. Chim. Acta, 44, pp. 129-138
- Janiak, C., (2000) J. Chem. Soc. Dalton Trans, 21, pp. 3885-3896
- Jian, F., Zheng, J., Zhao, P., Li, Y., (2008) J. Coord. Chem, 61, pp. 705-714
- Lever, A.B.P., (1968) Inorganic Electronic Spectroscopy, , New York Elsevier
- Ni, Y., Pan, Y.-Z., Wei, Z.-R., Cong, Q., Zhang, D., Wang, Y.-G., Liu, X.-Y., (2013) Inorg. Chem. Commun, 30, pp. 17-20
- Nincovic, D.C., Andric, J.M., Snezana, D.Z., (2013) Chem-PhysChem, 14, pp. 237-243
- Robin, A.Y., Fromm, K.M., (2006) Coord. Chem. Rev, 250, pp. 2127-2157
- Sheldrick, G.M., (2008) Acta Cryst, A64, pp. 112-122
- Sheldrick, G.M., (2015) Acta Cryst, C71, pp. 3-8
- Smith, Q.A., Gordon, M.S., (2011) J. Phys. Chem. A, 115, pp. 4598-4609
- Spackman, M.A., Jayatilaka, D., (2009) Cryst Eng Comm, 11, pp. 19-32
- Spackman, M.A., McKinnon, J.J., (2002) Cryst Eng Comm, 4, pp. 378-392
- Spek, A.L., (2009) Acta Cryst, D65, pp. 148-155
- Steed, J.W., Atwood, J.L., (2009) Supramolecular Chemistry, , 2nd ed. Chichester Wiley
- Sun, H.-L., Wang, Z.-M., Gao, S., (2010) Coord. Chem. Rev, 254, pp. 1081-1100
- Teo, P., Hor, T.S.A., (2011) Coord. Chem. Rev, 255, pp. 273-289
- Wang, W., Wnag, Y.-X., Yang, H.-B., (2016) Chem. Soc. Rev, 45, pp. 2656-2693
- Wheeler, S.E., (2011) J. Am. Chem. Soc, 133, pp. 10262-10274
- Zhou, T., Xu, W., Li, C., Guo, J., (2007) Z. Kristallogr, 222, pp. 249-250
Citas:
---------- APA ----------
Sanchez Montilva, O.C., Movilla, F., Rodriguez, M.G. & Di Salvo, F.
(2017)
. Synthesis, crystal structure and study of the crystal packing in the complex bis(4-aminopyridine-κN1)dichloridocobalt(II). Acta Crystallographica Section C: Structural Chemistry, 73(5), 399-406.
http://dx.doi.org/10.1107/S2053229617004880---------- CHICAGO ----------
Sanchez Montilva, O.C., Movilla, F., Rodriguez, M.G., Di Salvo, F.
"Synthesis, crystal structure and study of the crystal packing in the complex bis(4-aminopyridine-κN1)dichloridocobalt(II)"
. Acta Crystallographica Section C: Structural Chemistry 73, no. 5
(2017) : 399-406.
http://dx.doi.org/10.1107/S2053229617004880---------- MLA ----------
Sanchez Montilva, O.C., Movilla, F., Rodriguez, M.G., Di Salvo, F.
"Synthesis, crystal structure and study of the crystal packing in the complex bis(4-aminopyridine-κN1)dichloridocobalt(II)"
. Acta Crystallographica Section C: Structural Chemistry, vol. 73, no. 5, 2017, pp. 399-406.
http://dx.doi.org/10.1107/S2053229617004880---------- VANCOUVER ----------
Sanchez Montilva, O.C., Movilla, F., Rodriguez, M.G., Di Salvo, F. Synthesis, crystal structure and study of the crystal packing in the complex bis(4-aminopyridine-κN1)dichloridocobalt(II). Acta crystallogr., C Struct. Chem. 2017;73(5):399-406.
http://dx.doi.org/10.1107/S2053229617004880