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Abstract:

The CoII cation in poly[[aqua(μ-benzene-1,2-dicarboxylato- κ3 O 1,O 2:O 1)(μ-4,4'- bipyridine-κ2 N:N')cobalt(II)] trihydrate], {[Co(C 8H4O4)(C10H8N 2)(H2O)] 3H2O} n , is octahedrally coordinated by two N atoms of two 4,4'-bipyridine ligands, three O atoms from phthalate anions and a fourth O atom from a coordinated water molecule. The packing consists of planes of coordination polymers linked by hydrogen bonds mediated by three solvent water molecules; the linkage is achieved by the water molecules forming intricate oligomeric clusters which also involve the O atoms of the phthalate ligands. © 2014 International Union of Crystallography.

Registro:

Documento: Artículo
Título:The structure of {[Co(pht)(bpy)(H2O)] 3H2O} n (pht is phthalate and bpy is 4,4'-bipyridine) and the role of solvent water clusters in structure stability
Autor:Harvey, M.A.; Suarez, S.; Doctorovich, F.; Cukiernik, F.D.; Baggio, R.
Filiación:Universidad Nacional de la Patagonia SJB, Sede Trelew, 9100 Trelew, Chubut, Argentina
CenPat, CONICET, 9120 Puerto Madryn, Chubut, Argentina
Departamento de Química Inorgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina
Palabras clave:crystal structure; hydrated cobalt complex; stabilizing water clusters; TBG porous coordination polymer; two-dimensional coordination polymer; two-dimensional covalent arrays; Atoms; Cobalt; Crystal structure; Esters; Hydrogen bonds; Ligands; Molecules; Polymers; Bipyridine ligands; Cobalt complexes; Coordination Polymers; Octahedrally coordinated; Oligomeric clusters; Porous coordination polymer; Structure stability; Water cluster; Cobalt compounds
Año:2014
Volumen:70
Número:5
Página de inicio:440
Página de fin:444
DOI: http://dx.doi.org/10.1107/S2053229614006950
Título revista:Acta Crystallographica Section C: Structural Chemistry
Título revista abreviado:Acta Crystallogr., C Struct. Chem.
ISSN:20532296
CODEN:ACSCE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20532296_v70_n5_p440_Harvey

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Citas:

---------- APA ----------
Harvey, M.A., Suarez, S., Doctorovich, F., Cukiernik, F.D. & Baggio, R. (2014) . The structure of {[Co(pht)(bpy)(H2O)] 3H2O} n (pht is phthalate and bpy is 4,4'-bipyridine) and the role of solvent water clusters in structure stability. Acta Crystallographica Section C: Structural Chemistry, 70(5), 440-444.
http://dx.doi.org/10.1107/S2053229614006950
---------- CHICAGO ----------
Harvey, M.A., Suarez, S., Doctorovich, F., Cukiernik, F.D., Baggio, R. "The structure of {[Co(pht)(bpy)(H2O)] 3H2O} n (pht is phthalate and bpy is 4,4'-bipyridine) and the role of solvent water clusters in structure stability" . Acta Crystallographica Section C: Structural Chemistry 70, no. 5 (2014) : 440-444.
http://dx.doi.org/10.1107/S2053229614006950
---------- MLA ----------
Harvey, M.A., Suarez, S., Doctorovich, F., Cukiernik, F.D., Baggio, R. "The structure of {[Co(pht)(bpy)(H2O)] 3H2O} n (pht is phthalate and bpy is 4,4'-bipyridine) and the role of solvent water clusters in structure stability" . Acta Crystallographica Section C: Structural Chemistry, vol. 70, no. 5, 2014, pp. 440-444.
http://dx.doi.org/10.1107/S2053229614006950
---------- VANCOUVER ----------
Harvey, M.A., Suarez, S., Doctorovich, F., Cukiernik, F.D., Baggio, R. The structure of {[Co(pht)(bpy)(H2O)] 3H2O} n (pht is phthalate and bpy is 4,4'-bipyridine) and the role of solvent water clusters in structure stability. Acta Crystallogr., C Struct. Chem. 2014;70(5):440-444.
http://dx.doi.org/10.1107/S2053229614006950