Artículo
Di Paolo, M.; Bossi, M.L.; Baggio, R.; Suarez, S.A. "Two rhodamine 6G derivative compounds: A structural and fluorescence single-crystal study" (2016) Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials. 72:684-692
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Abstract:
The synthesis, characterization, structural analysis and fluorescence properties of two rhodamine 6G derivatives are described, namely a propargylamine derivative, 3′,6′-bis(ethylamino)-2′,7′-dimethyl-2-(methylcyanide)spiro[isoindole-1,9′-xanthen]-3(2H)-one (I), and a γ-aminobutyric acid (GABA) derivative, 3′,6′-bis(ethylamino)-2′,7′-dimethyl-3-oxospiro[isoindole-1,9′-xanthen]-2(3H)-yl)butyricacid (II). Both structures are compared with four similar ones from the Cambridge Structural Database (CSD), and the interactions involved in the stabilization are analyzed using the atoms in molecules (AIM) theory. Finally, a single-crystal in-situ reaction study is presented, carried out by fluorescence methods, which enabled the 'opening' of the spirolactam ring in the solid phase. © 2016 International Union of Crystallography.
Registro:
| Documento: | Artículo |
| Título: | Two rhodamine 6G derivative compounds: A structural and fluorescence single-crystal study |
| Autor: | Di Paolo, M.; Bossi, M.L.; Baggio, R.; Suarez, S.A. |
| Filiación: | Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria Pab. II, Buenos Aires, 1428, Argentina Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energiá Atómica, Buenos Aires, Argentina |
| Palabras clave: | atoms in molecules theory; fluorescence; photocrystallography; rhodamine 6G derivatives; weak interactions; Amino acids; Fluorescence; Molecules; Single crystals; Structural analysis; Atoms in molecules theory; Cambridge structural database; Fluorescence properties; Gamma-aminobutyric acids; Photocrystallography; Rhodamine 6G; Single-crystal study; Weak interactions; Crystal atomic structure; fluorescent dye; rhodamine; rhodamine 6G; chemical structure; chemistry; fluorescence; molecular model; synthesis; X ray crystallography; Chemistry Techniques, Synthetic; Crystallography, X-Ray; Fluorescence; Fluorescent Dyes; Models, Molecular; Molecular Structure; Rhodamines |
| Año: | 2016 |
| Volumen: | 72 |
| Página de inicio: | 684 |
| Página de fin: | 692 |
| DOI: | http://dx.doi.org/10.1107/S2052520616009343 |
| Título revista: | Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials |
| Título revista abreviado: | Acta Crystallogr. Sect. B Struct. Sci. Crys. Eng. Mater. |
| ISSN: | 20525192 |
| CODEN: | ACSBD |
| CAS: | rhodamine 6G, 989-38-8; Fluorescent Dyes; rhodamine 6G; Rhodamines |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20525192_v72_n_p684_DiPaolo |
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Citas:
---------- APA ----------
Di Paolo, M., Bossi, M.L., Baggio, R. & Suarez, S.A. (2016) . Two rhodamine 6G derivative compounds: A structural and fluorescence single-crystal study. Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 72, 684-692.http://dx.doi.org/10.1107/S2052520616009343
---------- CHICAGO ----------
Di Paolo, M., Bossi, M.L., Baggio, R., Suarez, S.A. "Two rhodamine 6G derivative compounds: A structural and fluorescence single-crystal study" . Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials 72 (2016) : 684-692.http://dx.doi.org/10.1107/S2052520616009343
---------- MLA ----------
Di Paolo, M., Bossi, M.L., Baggio, R., Suarez, S.A. "Two rhodamine 6G derivative compounds: A structural and fluorescence single-crystal study" . Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, vol. 72, 2016, pp. 684-692.http://dx.doi.org/10.1107/S2052520616009343
---------- VANCOUVER ----------
Di Paolo, M., Bossi, M.L., Baggio, R., Suarez, S.A. Two rhodamine 6G derivative compounds: A structural and fluorescence single-crystal study. Acta Crystallogr. Sect. B Struct. Sci. Crys. Eng. Mater. 2016;72:684-692.http://dx.doi.org/10.1107/S2052520616009343
