Abstract:
Highly ordered mesoporous ZrO2 thin films were prepared by evaporation induced self-assembly. Complexing agents and low pH were simultaneously employed in order to control the hydrolysis-condensation kinetics, permitting to cast films in one step. Many commercially available PPO-based surfactants can be used as templates, yielding different pore sizes. The mesoporosity is well preserved at high temperatures (600 °C) and after exposing the films to extreme alkaline conditions (1 M NaOH, 18 h). The procedure has been used to cast multilayer films, paving the way to mesoporous thin films-based UV photonics. © The Royal Society of Chemistry 2013.
Registro:
Documento: |
Artículo
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Título: | One-step preparation of UV transparent highly ordered mesoporous zirconia thin films |
Autor: | Zelcer, A.; Soler-Illia, G.J.A.A. |
Filiación: | Escuela de Ciencia y Tecnología, Universidad Nacional de San Martín, Argentina Gerencia Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. Gral Paz 1499, B1650KNA, Argentina DQIAyQF, FCEyN, Universidad de Buenos Aires, Argentina
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Palabras clave: | Alkalinity; Multilayer films; Thin films; Zirconia; Alkaline conditions; Cast film; Complexing agents; Different pore sizes; High temperature; Mesoporosity; Mesoporous; Ordered mesoporous; Mesoporous materials |
Año: | 2013
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Volumen: | 1
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Número: | 7
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Página de inicio: | 1359
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Página de fin: | 1367
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DOI: |
http://dx.doi.org/10.1039/c2tc00319h |
Título revista: | Journal of Materials Chemistry C
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Título revista abreviado: | J. Mater. Chem. C
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ISSN: | 20507534
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CODEN: | JMCCC
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20507534_v1_n7_p1359_Zelcer |
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Citas:
---------- APA ----------
Zelcer, A. & Soler-Illia, G.J.A.A.
(2013)
. One-step preparation of UV transparent highly ordered mesoporous zirconia thin films. Journal of Materials Chemistry C, 1(7), 1359-1367.
http://dx.doi.org/10.1039/c2tc00319h---------- CHICAGO ----------
Zelcer, A., Soler-Illia, G.J.A.A.
"One-step preparation of UV transparent highly ordered mesoporous zirconia thin films"
. Journal of Materials Chemistry C 1, no. 7
(2013) : 1359-1367.
http://dx.doi.org/10.1039/c2tc00319h---------- MLA ----------
Zelcer, A., Soler-Illia, G.J.A.A.
"One-step preparation of UV transparent highly ordered mesoporous zirconia thin films"
. Journal of Materials Chemistry C, vol. 1, no. 7, 2013, pp. 1359-1367.
http://dx.doi.org/10.1039/c2tc00319h---------- VANCOUVER ----------
Zelcer, A., Soler-Illia, G.J.A.A. One-step preparation of UV transparent highly ordered mesoporous zirconia thin films. J. Mater. Chem. C. 2013;1(7):1359-1367.
http://dx.doi.org/10.1039/c2tc00319h