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Abstract:

Chitin hybrid materials reinforced with graphene oxide nanosheets (nGO) have been prepared. The chitin : nGO ratio ranged from proportions where chitin was the main component to ones where nGO exceeded chitin. SEM and TEM images showed that high proportions of nGO may result in nanosheet association. FTIR, 13C solid-state NMR and DSC analyses showed that the interaction among the components would not involve the formation of new molecular bonds. nGO was shown to act as a filler that induces structural rearrangements in chitin which lead to new hydrogen bonds among the chains. The mechanical stability proved to be higher when the nGO content in the hybrid was similar to or higher than that of chitin. The rheological behaviour of the material was shown to become more solid-like with increasing nGO content. The nGO did not interfere with lysozyme activity on chitin chains, indicating that these materials would be biodegradable. © 2014 the Partner Organisations.

Registro:

Documento: Artículo
Título:Chitin hybrid materials reinforced with graphene oxide nanosheets: Chemical and mechanical characterisation
Autor:González, J.A.; Mazzobre, M.F.; Villanueva, M.E.; Díaz, L.E.; Copello, G.J.
Filiación:Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires (UBA), IQUIMEFA (UBA-CONICET), Junín 956, C1113AAD Buenos Aires, Argentina
Departamento de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires y CONICET, Intendente Guiraldes 2160, CP 1428, Buenos Aires, Argentina
Palabras clave:Chains; Graphene; Hybrid materials; Hydrogen bonds; Nuclear magnetic resonance spectroscopy; Reinforcement; FTIR; Graphene oxide nanosheets; Mechanical characterisation; Molecular bonds; Rheological behaviour; SEM and TEM; Solid state NMR; Structural rearrangement; Chitin
Año:2014
Volumen:4
Número:32
Página de inicio:16480
Página de fin:16488
DOI: http://dx.doi.org/10.1039/c3ra47986b
Título revista:RSC Advances
Título revista abreviado:RSC Adv.
ISSN:20462069
CODEN:RSCAC
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20462069_v4_n32_p16480_Gonzalez

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Citas:

---------- APA ----------
González, J.A., Mazzobre, M.F., Villanueva, M.E., Díaz, L.E. & Copello, G.J. (2014) . Chitin hybrid materials reinforced with graphene oxide nanosheets: Chemical and mechanical characterisation. RSC Advances, 4(32), 16480-16488.
http://dx.doi.org/10.1039/c3ra47986b
---------- CHICAGO ----------
González, J.A., Mazzobre, M.F., Villanueva, M.E., Díaz, L.E., Copello, G.J. "Chitin hybrid materials reinforced with graphene oxide nanosheets: Chemical and mechanical characterisation" . RSC Advances 4, no. 32 (2014) : 16480-16488.
http://dx.doi.org/10.1039/c3ra47986b
---------- MLA ----------
González, J.A., Mazzobre, M.F., Villanueva, M.E., Díaz, L.E., Copello, G.J. "Chitin hybrid materials reinforced with graphene oxide nanosheets: Chemical and mechanical characterisation" . RSC Advances, vol. 4, no. 32, 2014, pp. 16480-16488.
http://dx.doi.org/10.1039/c3ra47986b
---------- VANCOUVER ----------
González, J.A., Mazzobre, M.F., Villanueva, M.E., Díaz, L.E., Copello, G.J. Chitin hybrid materials reinforced with graphene oxide nanosheets: Chemical and mechanical characterisation. RSC Adv. 2014;4(32):16480-16488.
http://dx.doi.org/10.1039/c3ra47986b