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Abstract:

Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA)I·I3] and visible light. This methodology bypasses the use of metal(organo)catalysts where the complex [(TMEDA)I·I3] acts as a good electron donor/reductant radical initiating agent. Biologically relevant sulfides are easily substituted with RF moieties employing a mild and environmentally benign radical strategy starting from readily available RFI. © 2017 The Royal Society of Chemistry.

Registro:

Documento: Artículo
Título:Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator
Autor:Yerien, D.E.; Barata-Vallejo, S.; Camps, B.; Cristófalo, A.E.; Cano, M.E.; Uhrig, M.L.; Postigo, A.
Filiación:Departamento de Química Orgánica, Facultad de Farmacia y Bioquímica, Universidad de Buenos, Aires Junín 954, Buenos Aires, CP 1113, Argentina
Centro de Investigaciones en Hidratos de Carbono (CIHIDECAR), Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, Buenos Aires, 1428, Argentina
Palabras clave:Electron donors; Environmentally benign; Organic sulfides; Perfluoroalkylation; Radical initiators; Radical perfluoroalkylation; Visible light; Sulfur compounds
Año:2017
Volumen:7
Número:11
Página de inicio:2274
Página de fin:2282
DOI: http://dx.doi.org/10.1039/c7cy00236j
Título revista:Catalysis Science and Technology
Título revista abreviado:Catal. Sci. Technolog.
ISSN:20444753
CODEN:CSTAG
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20444753_v7_n11_p2274_Yerien

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Citas:

---------- APA ----------
Yerien, D.E., Barata-Vallejo, S., Camps, B., Cristófalo, A.E., Cano, M.E., Uhrig, M.L. & Postigo, A. (2017) . Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator. Catalysis Science and Technology, 7(11), 2274-2282.
http://dx.doi.org/10.1039/c7cy00236j
---------- CHICAGO ----------
Yerien, D.E., Barata-Vallejo, S., Camps, B., Cristófalo, A.E., Cano, M.E., Uhrig, M.L., et al. "Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator" . Catalysis Science and Technology 7, no. 11 (2017) : 2274-2282.
http://dx.doi.org/10.1039/c7cy00236j
---------- MLA ----------
Yerien, D.E., Barata-Vallejo, S., Camps, B., Cristófalo, A.E., Cano, M.E., Uhrig, M.L., et al. "Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator" . Catalysis Science and Technology, vol. 7, no. 11, 2017, pp. 2274-2282.
http://dx.doi.org/10.1039/c7cy00236j
---------- VANCOUVER ----------
Yerien, D.E., Barata-Vallejo, S., Camps, B., Cristófalo, A.E., Cano, M.E., Uhrig, M.L., et al. Electron-catalyzed radical perfluoroalkylation of organic sulfides: The serendipitous use of the TMEDA/I2 complex as a radical initiator. Catal. Sci. Technolog. 2017;7(11):2274-2282.
http://dx.doi.org/10.1039/c7cy00236j