Artículo

Franke, M.; Marchini, F.; Steinrück, H.-P.; Lytken, O.; Williams, F.J. "Surface Porphyrins Metalate with Zn Ions from Solution" (2015) Journal of Physical Chemistry Letters. 6(23):4845-4849
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Abstract:

Controlling the metalation of surface porphyrins is a critical process in porphyrin-based devices. Indeed, surface porphyrins are known to metalate in ultrahigh vacuum from codeposited metal atoms or substrate atoms; however, it is not yet known if surface porphyrins could metalate from ions in solution, that is, the most likely environment for porphyrin-based devices. Using X-ray photoelectron spectroscopy we have studied the metalation of monolayers and multilayers of a free-base tetraphenyl porphyrin adsorbed on Au(111) with ions in solution. We found that full metalation with Zn2+ can be achieved already at room temperature in contrast with the elevated temperatures required for metalation with codeposited metal atoms. © 2015 American Chemical Society.

Registro:

Documento: Artículo
Título:Surface Porphyrins Metalate with Zn Ions from Solution
Autor:Franke, M.; Marchini, F.; Steinrück, H.-P.; Lytken, O.; Williams, F.J.
Filiación:Lehrstuhl für Physikalische Chemie II, Universität Erlangen-Nürnberg, Egerlandstraße 3, Erlangen, 91058, Germany
Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE-CONICET, Facultad Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, C1428EHA, Argentina
Palabras clave:free-base porphyrin; metalation; surface; XPS; ZnTPP; Atoms; Chemical reactions; Ions; Porphyrins; Surfaces; X ray photoelectron spectroscopy; Zinc; Elevated temperature; Free base porphyrins; Metal atoms; Metalations; Most likely; Substrate atom; Tetraphenyl porphyrins; ZnTPP; Metals
Año:2015
Volumen:6
Número:23
Página de inicio:4845
Página de fin:4849
DOI: http://dx.doi.org/10.1021/acs.jpclett.5b02218
Título revista:Journal of Physical Chemistry Letters
Título revista abreviado:J. Phys. Chem. Lett.
ISSN:19487185
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_19487185_v6_n23_p4845_Franke

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Citas:

---------- APA ----------
Franke, M., Marchini, F., Steinrück, H.-P., Lytken, O. & Williams, F.J. (2015) . Surface Porphyrins Metalate with Zn Ions from Solution. Journal of Physical Chemistry Letters, 6(23), 4845-4849.
http://dx.doi.org/10.1021/acs.jpclett.5b02218
---------- CHICAGO ----------
Franke, M., Marchini, F., Steinrück, H.-P., Lytken, O., Williams, F.J. "Surface Porphyrins Metalate with Zn Ions from Solution" . Journal of Physical Chemistry Letters 6, no. 23 (2015) : 4845-4849.
http://dx.doi.org/10.1021/acs.jpclett.5b02218
---------- MLA ----------
Franke, M., Marchini, F., Steinrück, H.-P., Lytken, O., Williams, F.J. "Surface Porphyrins Metalate with Zn Ions from Solution" . Journal of Physical Chemistry Letters, vol. 6, no. 23, 2015, pp. 4845-4849.
http://dx.doi.org/10.1021/acs.jpclett.5b02218
---------- VANCOUVER ----------
Franke, M., Marchini, F., Steinrück, H.-P., Lytken, O., Williams, F.J. Surface Porphyrins Metalate with Zn Ions from Solution. J. Phys. Chem. Lett. 2015;6(23):4845-4849.
http://dx.doi.org/10.1021/acs.jpclett.5b02218