Artículo

Wolosiuk, A.; Tognalli, N.G.; Martínez, E.D.; Granada, M.; Fuertes, M.C.; Troiani, H.; Bilmes, S.A.; Fainstein, A.; Soler-Illia, G.J.A.A. "Silver nanoparticle-mesoporous oxide nanocomposite thin films: A platform for spatially homogeneous SERS-active substrates with enhanced stability" (2014) ACS Applied Materials and Interfaces. 6(7):5263-5272
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Abstract:

We introduce a nanoparticle-mesoporous oxide thin film composite (NP-MOTF) as low-cost and straightforward sensing platforms for surface-enhanced Raman Spectroscopy (SERS). Titania, zirconia, and silica mesoporous matrices templated with Pluronics F-127 were synthesized via evaporation-induced self-assembly and loaded with homogeneously dispersed Ag nanoparticles by soft reduction or photoreduction. Both methods give rise to uniform and reproducible Raman signals using 4-mercaptopyridine as a probe molecule. Details on stability and reproducibility of the Raman enhancement are discussed. Extensions in the design of these composite structures were explored including detection of nonthiolated molecules, such as rhodamine 6-G or salicylic acid, patterning techniques for locating the enhancement regions and bilayered mesoporous structures to provide additional control on the environment, and potential size-selective filtration. These inorganic oxide-metal composites stand as extremely simple, reproducible, and versatile platforms for Raman spectroscopy analysis. © 2014 American Chemical Society.

Registro:

Documento: Artículo
Título:Silver nanoparticle-mesoporous oxide nanocomposite thin films: A platform for spatially homogeneous SERS-active substrates with enhanced stability
Autor:Wolosiuk, A.; Tognalli, N.G.; Martínez, E.D.; Granada, M.; Fuertes, M.C.; Troiani, H.; Bilmes, S.A.; Fainstein, A.; Soler-Illia, G.J.A.A.
Filiación:Gerencia Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica (CNEA), Av. Gral Paz 1499, B1650KNA San Martín, Buenos Aires, Argentina
Centro Atómico Bariloche, CNEA, 8400 San Carlos de Bariloche, Río Negro, Argentina
Centro de Innovación Tecnológica, Empresarial y Social (CITES), S2322 Sunchales, Santa Fe, Argentina
Instituto Sabato, Universidad Nacional de San Martín, CNEA, B1650HMP, San Martin, Buenos Aires, Argentina
DQIAyQF, FCEN, Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina
Palabras clave:mesoporous thin films; photodeposition; plasmonics; sensors; silver nanoparticles; surface-enhanced Raman spectroscopy (SERS); Mesoporous materials; Molecules; Nanoparticles; Raman spectroscopy; Self assembly; Sensors; Substrates; Synthesis (chemical); Zirconia; Mesoporous thin films; Photo-deposition; Plasmonics; Silver nanoparticles; Surface enhanced Raman spectroscopy; Silver
Año:2014
Volumen:6
Número:7
Página de inicio:5263
Página de fin:5272
DOI: http://dx.doi.org/10.1021/am500631f
Título revista:ACS Applied Materials and Interfaces
Título revista abreviado:ACS Appl. Mater. Interfaces
ISSN:19448244
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_19448244_v6_n7_p5263_Wolosiuk

Referencias:

  • Fleischmann, M., Hendra, P., McQuillan, A., Raman spectra of pyridine adsorbed at a silver electrode (1974) Chem. Phys. Lett., 26 (2), pp. 163-166
  • Nie, S., Emory, S.R., Probing single molecules and single nanoparticles by surface-enhanced Raman scattering (1997) Science, 275 (5303), pp. 1102-1106
  • Baker, G.A., Moore, D.S., Progress in plasmonic engineering of surface-enhanced Raman-scattering substrates toward ultra-trace analysis (2005) Anal. Bioanal. Chem., 382 (8), pp. 1751-1770
  • Kneipp, K., Wang, Y., Kneipp, H., Perelman, L.T., Itzkan, I., Dasari, R., Feld, M.S., Single molecule detection using surface-enhanced Raman scattering (SERS) (1997) Phys. Rev. Lett., 78 (9), pp. 1667-1670
  • Moskovits, M., Surface-enhanced Raman spectroscopy: A brief retrospective (2005) J. Raman Spectrosc., 36 (67), pp. 485-496
  • Etchegoin, P., Maher, R.C., Cohen, L.F., Hartigan, H., Brown, R.J.C., Milton, M.J.T., Gallop, J.C., New limits in ultrasensitive trace detection by surface enhanced Raman scattering (SERS) (2003) Chem. Phys. Lett., 375 (12), pp. 84-90
  • Jiang, J., Bosnick, K., Maillard, M., Brus, L., Single molecule Raman spectroscopy at the junctions of large Ag nanocrystals (2003) J. Phys. Chem. B, 107 (37), pp. 9964-9972
  • Markel, V.A., Shalaev, V.M., Zhang, P., Huynh, W., Tay, L., Haslett, T.L., Moskovits, M., Near-field optical spectroscopy of individual surface-plasmon modes in colloid clusters (1999) Phys. Rev. B: Condens. Matter Mater. Phys., 59 (16), pp. 10903-10909
  • Zayak, A.T., Hu, Y.S., Choo, H., Bokor, J., Cabrini, S., Schuck, P.J., Neaton, J.B., Chemical Raman enhancement of organic adsorbates on metal surfaces (2011) Phys. Rev. Lett., 106 (8), pp. 083003-083006
  • Ko, H., Singamaneni, S., Tsukruk, V.V., Nanostructured surfaces and assemblies as SERS media (2008) Small, 4 (10), pp. 1576-1599
  • Jones, M.R., Osberg, K.D., Macfarlane, R.J., Langille, M.R., Mirkin, C.A., Templated techniques for the synthesis and assembly of plasmonic nanostructures (2011) Chem. Rev., 111 (6), pp. 3736-3827
  • Brolo, A.G., Arctander, E., Gordon, R., Leathem, B., Kavanagh, K.L., Nanohole-enhanced raman scattering (2004) Nano Lett., 4 (10), pp. 2015-2018
  • Jensen, T.R., Schatz, G.C., Van Duyne, R.P., Nanosphere lithography: Surface plasmon resonance spectrum of a periodic array of silver nanoparticles by ultraviolet-visible extinction spectroscopy and electrodynamic modeling (1999) J. Phys. Chem. B, 103 (13), pp. 2394-2401
  • Mahajan, S., Abdelsalam, M., Suguwara, Y., Cintra, S., Russell, A., Baumberg, J., Bartlett, P., Tuning plasmons on nano-structured substrates for NIR-SERS (2007) Phys. Chem. Chem. Phys., 9 (1), pp. 104-109
  • Wang, H., Levin, C.S., Halas, N.J., Nanosphere arrays with controlled sub-10-nm gaps as surface-enhanced Raman spectroscopy substrates (2005) J. Am. Chem. Soc., 127 (43), pp. 14992-14993
  • Lee, S.J., Morrill, A.R., Moskovits, M., Hot spots in silver nanowire bundles for surface-enhanced Raman spectroscopy (2006) J. Am. Chem. Soc., 128 (7), pp. 2200-2201
  • Wu, Y., Livneh, T., Zhang, Y.X., Cheng, G., Wang, J., Tang, J., Moskovits, M., Stucky, G.D., Templated synthesis of highly ordered mesostructured nanowires and nanowire arrays (2004) Nano Lett., 4 (12), pp. 2337-2342
  • Wang, X., Li, M., Meng, L., Lin, K., Feng, J., Huang, T., Yang, Z., Ren, B., Probing the location of hot spots by surface-enhanced Raman spectroscopy: Toward uniform substrates (2014) ACS Nano, 8 (1), pp. 528-536
  • Brown, R.J.C., Milton, M.J.T., Nanostructures and nanostructured substrates for surface-enhanced Raman scattering (SERS) (2008) J. Raman Spectrosc., 39 (10), pp. 1313-1326
  • López-Puente, V., Abalde-Cela, S., Angelomé, P.C., Alvarez-Puebla, R.A., Liz-Marzán, L.M., Plasmonic mesoporous composites as molecular sieves for SERS detection (2013) J. Phys. Chem. Lett., 4 (16), pp. 2715-2720
  • Malfatti, L., Falcaro, P., Marmiroli, B., Amenitsch, H., Piccinini, M., Falqui, A., Innocenzi, P., Nanocomposite mesoporous ordered films for lab-on-chip intrinsic surface enhanced Raman scattering detection (2011) Nanoscale, 3 (9), pp. 3760-3766
  • Mura, S., Greppi, G., Innocenzi, P., Piccinini, M., Figus, C., Marongiu, M.L., Guo, C., Irudayaraj, J., Nanostructured thin films as surface-enhanced Raman scattering substrates (2013) J. Raman Spectrosc., 44 (1), pp. 35-40
  • Sugikawa, K., Nagata, S., Furukawa, Y., Kokado, K., Sada, K., Stable and functional gold nanorod composites with a metal-organic framework crystalline shell (2013) Chem. Mater., 25 (13), pp. 2565-2570
  • Fuertes, M.C., Marchena, M., Marchi, M.C., Wolosiuk, A., Soler-Illia, G.J.A.A., Controlled deposition of silver nanoparticles in mesoporous single- or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects (2009) Small, 5 (2), pp. 272-280
  • Martínez, E.D., Granja, L., Bellino, M.G., Soler-Illia, G.J.A.A., Electrical conductivity in patterned silver-mesoporous titania nanocomposite thin films: Towards robust 3D nano-electrodes (2010) Phys. Chem. Chem. Phys., 12 (43), pp. 14445-14448
  • Soler-Illia, G.J.D.A.A., Sanchez, C., Lebeau, B., Patarin, J., Chemical strategies to design textured materials: From microporous and mesoporous oxides to nanonetworks and hierarchical structures (2002) Chem. Rev., 102 (11), pp. 4093-4138
  • Yamauchi, Y., Momma, T., Kitoh, H., Osaka, T., Kuroda, K., Fabrication of mesoporous Pt inside micrometer channels via "solvent-evaporation-mediated direct physical casting" (2005) Electrochem. Commun., 7 (12), pp. 1364-1370
  • Yang, P., Deng, T., Zhao, D., Feng, P., Pine, D., Chmelka, B.F., Whitesides, G.M., Stucky, G.D., Hierarchically ordered oxides (1998) Science, 282 (5397), pp. 2244-2246
  • Fuertes, M.C., Colodrero, S., Lozano, G., González-Elipe, A.R., Grosso, D., Boissière, C., Sánchez, C., Míguez, H., Sorption properties of mesoporous multilayer thin films (2008) J. Phys. Chem. C, 112 (9), pp. 3157-3163
  • Yang, P., Rizvi, A.H., Messer, B., Chmelka, B.F., Whitesides, G.M., Stucky, G.D., Patterning porous oxides within microchannel networks (2001) Adv. Mater., 13 (6), pp. 427-431
  • Calvo, A., Angelomé, P.C., Sánchez, V.M., Scherlis, D.A., Williams, F.J., Soler-Illia, G.J.A.A., Mesoporous aminopropyl-functionalized hybrid thin films with modulable surface and environment-responsive behavior (2008) Chem. Mater., 20 (14), pp. 4661-4668
  • Calvo, A., Yameen, B., Williams, F.J., Azzaroni, O., Soler-Illia, G.J.A.A., Facile molecular design of hybrid functional assemblies with controllable transport properties: Mesoporous films meet polyelectrolyte brushes (2009) Chem. Commun., 18, pp. 2553-2555
  • Angelomé, P.C., Cecilia Fuertes, M., Soler-Illia, G.J.A.A., Multifunctional, multilayer, multiscale: Integrative synthesis of complex macroporous and mesoporous thin films with spatial separation of porosity and function (2006) Adv. Mater., 18 (18), pp. 2397-2402
  • Fuertes, M.C., López-Alcaraz, F.J., Marchi, M.C., Troiani, H.E., Luca, V., Míguez, H., Soler-Illia, G.J.D.A.A., Photonic crystals from ordered mesoporous thin-film functional building blocks (2007) Adv. Funct. Mater., 17 (8), pp. 1247-1254
  • Zelcer, A., Wolosiuk, A., Soler-Illia, G.J.A.A., Carbonaceous submicron sized islands: A surface patterning route to hierarchical macro/mesoporous thin films (2009) J. Mater. Chem., 19 (24), pp. 4191-4196
  • Crepaldi, E.L., Soler-Illia, G.J.D.A.A., Grosso, D., Cagnol, F., Ribot, F., Sanchez, C., Controlled formation of highly organized mesoporous titania thin films: From mesostructured hybrids to mesoporous nanoanatase TiO 2 (2003) J. Am. Chem. Soc., 125 (32), pp. 9770-9786
  • Sanchez, C., Boissière, C., Grosso, D., Laberty, C., Nicole, L., Design, synthesis, and properties of inorganic and hybrid thin films having periodically organized nanoporosity (2008) Chem. Mater., 20 (3), pp. 682-737
  • Attard, G.S., Bartlett, P.N., Coleman, N.R.B., Elliott, J.M., Owen, J.R., Wang, J.H., Mesoporous platinum films from lyotropic liquid crystalline phases (1997) Science, 278 (5339), pp. 838-840
  • Pérez, M.D., Otal, E., Bilmes, S.A., Soler-Illia, G.J.A.A., Crepaldi, E.L., Grosso, D., Sanchez, C., Growth of gold nanoparticle arrays in TiO 2 mesoporous matrixes (2004) Langmuir, 20 (16), pp. 6879-6886
  • Besson, S., Gacoin, T., Ricolleau, C., Boilot, J.P., Silver nanoparticle growth in 3D-hexagonal mesoporous silica films (2003) Chem. Commun., 9 (3), pp. 360-361
  • Huang, M.H., Choudrey, A., Yang, P., Ag nanowire formation within mesoporous silica (2000) Chem. Commun., 12, pp. 1063-1064
  • Kumai, Y., Tsukada, H., Akimoto, Y., Sugimoto, N., Seno, Y., Fukuoka, A., Ichikawa, M., Inagaki, S., Highly ordered platinum nanodot arrays with cubic symmetry in mesoporous thin films (2006) Adv. Mater., 18 (6), pp. 760-762
  • Wright, A., Gabaldon, J., Burckel, D.B., Jiang, Y.B., Tian, Z.R., Liu, J., Brinker, C.J., Fan, H., Hierarchically organized nanoparticle mesostructure arrays formed through hydrothermal self-assembly (2006) Chem. Mater., 18 (13), pp. 3034-3038
  • Bronstein, L., Nanoparticles made in mesoporous solids (2003) Colloid Chemistry i, pp. 55-89. , Antonietti, M. Springer: Berlin, Chapter 3
  • Martínez, E.D., Bellino, M.G., Soler-Illia, G.J.A.A., Patterned production of silver-mesoporous titania nanocomposite thin films using lithography-assisted metal reduction (2009) ACS Appl. Mater. Interfaces, 1 (4), pp. 746-749
  • Koura, N., Electroless plating of silver (1990) Electroless Plating: Fundamentals and Applications, pp. 441-462. , Mallory, G. O. Hajdu, J. B. American Electroplaters and Surface Finishers Society: Orlando, FL, Chapter 17
  • Boissiere, C., Grosso, D., Lepoutre, S., Nicole, L., Bruneau, A.B., Sanchez, C., Porosity and mechanical properties of mesoporous thin films assessed by environmental ellipsometric porosimetry (2005) Langmuir, 21 (26), pp. 12362-12371
  • Sánchez, V.M., Martínez, E.D., Martínez Ricci, M.L., Troiani, H., Soler-Illia, G.J.A.A., Optical properties of Au nanoparticles included in mesoporous TiO 2 thin films: A dual experimental and modeling study (2013) J. Phys. Chem. C, 117 (14), pp. 7246-7259
  • Gibaud, A., Dourdain, S., Vignaud, G., Analysis of mesoporous thin films by X-ray reflectivity, optical reflectivity and grazing incidence small angle X-ray scattering (2006) Appl. Surf. Sci., 253 (1), pp. 3-11
  • Baldwin, J.A., Vlčková, B., Andrews, M.P., Butler, I.S., Surface-enhanced raman scattering of mercaptopyridines and pyrazinamide incorporated in silver colloid-adsorbate films (1997) Langmuir, 13 (14), pp. 3744-3751
  • Tognalli, N., Fainstein, A., Calvo, E., Bonazzola, C., Pietrasanta, L., Campoy-Quiles, M., Etchegoin, P., SERS in PAH-Os and gold nanoparticle self-assembled multilayers (2005) J. Chem. Phys., 123 (4). , (044707
  • Jain, P.K., El-Sayed, M.A., Plasmonic coupling in noble metal nanostructures (2010) Chem. Phys. Lett., 487 (46), pp. 153-164
  • Ung, T., Liz-Marzán, L.M., Mulvaney, P., Optical properties of thin films of AuO/SiO 2 particles (2001) J. Phys. Chem. B, 105 (17), pp. 3441-3452
  • Jiang, X., Yang, M., Meng, Y., Jiang, W., Zhan, J., Cysteamine-modified silver nanoparticle aggregates for quantitative SERS sensing of pentachlorophenol with a portable Raman spectrometer (2013) ACS Appl. Mater. Interfaces, 5 (15), pp. 6902-6908
  • Norrod, K.L., Sudnik, L.M., Rousell, D., Rowlen, K.L., Quantitative comparison of five SERS substrates: Sensitivity and limit of detection (1997) Appl. Spectrosc., 51 (7), pp. 994-1001
  • Sudnik, L.M., Norrod, K.L., Rowlen, K.L., SERS-active Ag films from photoreduction of Ag+ on TiO 2 (1996) Appl. Spectrosc., 50 (3), pp. 422-424
  • Henglein, A., Colloidal silver nanoparticles: Photochemical preparation and interaction with O 2 , CCl 4 , and some metal ions (1998) Chem. Mater., 10 (1), pp. 444-450
  • Angelomé, P.C., Andrini, L., Calvo, M.E., Requejo, F.G., Bilmes, S.A., Soler-Illia, G.J.A.A., Mesoporous anatase TiO 2 films: Use of Ti K XANES for the quantification of the nanocrystalline character and substrate effects in the photocatalysis behavior (2007) J. Phys. Chem. C, 111 (29), pp. 10886-10893
  • Yu, J., Zhao, X., Effect of substrates on the photocatalytic activity of nanometer TiO 2 thin films (2000) Mater. Res. Bull., 35 (8), pp. 1293-1301
  • Pierre, M.C.S., Haes, A.J., Purification implications on SERS activity of silica coated gold nanospheres (2012) Anal. Chem., 84 (18), pp. 7906-7911
  • Soler-Illia, G.J.A.A., Angelome, P.C., Fuertes, M.C., Calvo, A., Wolosiuk, A., Zelcer, A., Bellino, M.G., Martinez, E.D., Mesoporous hybrid and nanocomposite thin films. A sol-gel toolbox to create nanoconfined systems with localized chemical properties (2012) J. Sol-Gel Sci. Technol., 57 (3), pp. 299-312
  • Scodeller, P., Flexer, V., Szamocki, R., Calvo, E.J., Tognalli, N., Troiani, H., Fainstein, A., Wired-enzyme core-shell Au nanoparticle biosensor (2008) J. Am. Chem. Soc., 130 (38), pp. 12690-12697
  • Calvo, A., Yameen, B., Williams, F.J., Soler-Illia, G.J.A.A., Azzaroni, O., Mesoporous films and polymer brushes helping each other to modulate ionic transport in nanoconfined environments. An interesting example of synergism in functional hybrid assemblies (2009) J. Am. Chem. Soc., 131 (31), pp. 10866-10868
  • Fattakhova-Rohlfing, D., Wark, M., Rathouský, J., Ion-permselective pH-switchable mesoporous silica thin layers (2007) Chem. Mater., 19 (7), pp. 1640-1647
  • Taffa, D.H., Kathiresan, M., Walder, L., Seelandt, B., Wark, M., Pore size and surface charge control in mesoporous TiO 2 using post-grafted SAMs (2010) Phys. Chem. Chem. Phys., 12 (7), pp. 1473-1482
  • Mahajan, S., Richardson, J., Brown, T., Bartlett, P.N., SERS-melting: A new method for discriminating mutations in DNA sequences (2008) J. Am. Chem. Soc., 130 (46), pp. 15589-15601

Citas:

---------- APA ----------
Wolosiuk, A., Tognalli, N.G., Martínez, E.D., Granada, M., Fuertes, M.C., Troiani, H., Bilmes, S.A.,..., Soler-Illia, G.J.A.A. (2014) . Silver nanoparticle-mesoporous oxide nanocomposite thin films: A platform for spatially homogeneous SERS-active substrates with enhanced stability. ACS Applied Materials and Interfaces, 6(7), 5263-5272.
http://dx.doi.org/10.1021/am500631f
---------- CHICAGO ----------
Wolosiuk, A., Tognalli, N.G., Martínez, E.D., Granada, M., Fuertes, M.C., Troiani, H., et al. "Silver nanoparticle-mesoporous oxide nanocomposite thin films: A platform for spatially homogeneous SERS-active substrates with enhanced stability" . ACS Applied Materials and Interfaces 6, no. 7 (2014) : 5263-5272.
http://dx.doi.org/10.1021/am500631f
---------- MLA ----------
Wolosiuk, A., Tognalli, N.G., Martínez, E.D., Granada, M., Fuertes, M.C., Troiani, H., et al. "Silver nanoparticle-mesoporous oxide nanocomposite thin films: A platform for spatially homogeneous SERS-active substrates with enhanced stability" . ACS Applied Materials and Interfaces, vol. 6, no. 7, 2014, pp. 5263-5272.
http://dx.doi.org/10.1021/am500631f
---------- VANCOUVER ----------
Wolosiuk, A., Tognalli, N.G., Martínez, E.D., Granada, M., Fuertes, M.C., Troiani, H., et al. Silver nanoparticle-mesoporous oxide nanocomposite thin films: A platform for spatially homogeneous SERS-active substrates with enhanced stability. ACS Appl. Mater. Interfaces. 2014;6(7):5263-5272.
http://dx.doi.org/10.1021/am500631f