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Abstract:

Light absorption in gold nanoparticles leads to metal heating that induces photothermal reshaping because of atomic surface diffusion at temperatures well below the gold melting point. In this work, we perform time-resolved experiments to measure the frequencies of the extensional coherent mechanical mode in single gold nanorods, as a monitor of the changes in their aspect ratio produced by this photoinduced reshaping. We show that photothermal reshaping always occurs in typical pump-probe experiments conducted in air even at low-excitation light irradiance and usually long measuring times. The reshaping effect can be reduced by a polymer coating, which allows faster heat dissipation from the nanoparticle to the environment. © Copyright 2018 American Chemical Society.

Registro:

Documento: Artículo
Título:Monitoring the Photothermal Reshaping of Individual Plasmonic Nanorods with Coherent Mechanical Oscillations
Autor:Della Picca, F.; Gutiérrez, M.V.; Bragas, A.V.; Scarpettini, A.F.
Filiación:Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, 1428, Argentina
Facultad Regional Delta, Universidad Tecnológica Nacional, Campana, Provincia de Buenos Aires, 2804, Argentina
IFIBA, UBA-CONICET, Buenos Aires, 1428, Argentina
Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires, 1425, Argentina
Palabras clave:Aspect ratio; Light absorption; Metal nanoparticles; Nanorods; Plasmonics; Plasmons; Plastic coatings; Excitation light; Mechanical oscillations; Photo-induced; Photo-thermal; Polymer Coating; Pump-probe experiments; Reshaping effect; Time resolved experiments; Gold nanoparticles
Año:2018
Volumen:122
Número:51
Página de inicio:29598
Página de fin:29606
DOI: http://dx.doi.org/10.1021/acs.jpcc.8b09458
Título revista:Journal of Physical Chemistry C
Título revista abreviado:J. Phys. Chem. C
ISSN:19327447
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_19327447_v122_n51_p29598_DellaPicca

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Citas:

---------- APA ----------
Della Picca, F., Gutiérrez, M.V., Bragas, A.V. & Scarpettini, A.F. (2018) . Monitoring the Photothermal Reshaping of Individual Plasmonic Nanorods with Coherent Mechanical Oscillations. Journal of Physical Chemistry C, 122(51), 29598-29606.
http://dx.doi.org/10.1021/acs.jpcc.8b09458
---------- CHICAGO ----------
Della Picca, F., Gutiérrez, M.V., Bragas, A.V., Scarpettini, A.F. "Monitoring the Photothermal Reshaping of Individual Plasmonic Nanorods with Coherent Mechanical Oscillations" . Journal of Physical Chemistry C 122, no. 51 (2018) : 29598-29606.
http://dx.doi.org/10.1021/acs.jpcc.8b09458
---------- MLA ----------
Della Picca, F., Gutiérrez, M.V., Bragas, A.V., Scarpettini, A.F. "Monitoring the Photothermal Reshaping of Individual Plasmonic Nanorods with Coherent Mechanical Oscillations" . Journal of Physical Chemistry C, vol. 122, no. 51, 2018, pp. 29598-29606.
http://dx.doi.org/10.1021/acs.jpcc.8b09458
---------- VANCOUVER ----------
Della Picca, F., Gutiérrez, M.V., Bragas, A.V., Scarpettini, A.F. Monitoring the Photothermal Reshaping of Individual Plasmonic Nanorods with Coherent Mechanical Oscillations. J. Phys. Chem. C. 2018;122(51):29598-29606.
http://dx.doi.org/10.1021/acs.jpcc.8b09458