Artículo

Franke, M.; Marchini, F.; Zhang, L.; Tariq, Q.; Tsud, N.; Vorokhta, M.; Vondráček, M.; Prince, K.; Röckert, M.; Williams, F.J.; Steinrück, H.-P.; Lytken, O. "Temperature-Dependent Reactions of Phthalic Acid on Ag(100)" (2015) Journal of Physical Chemistry C. 119(41):23580-23585
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Abstract:

We have investigated the adsorption and temperature-dependent reactions of phthalic acid on Ag(100), in the temperature range 110-700 K, by synchrotron radiation X-ray photoelectron spectrocopy (SR-XPS), temperature-programmed desorption (TPD) and near-edge X-ray absorption fine structure (NEXAFS). Phthalic acid adsorbs intact at 110 K, but decomposes to phthalic anhydride and polyanhdride at 150 K. When heated further, phthalic anhydride desorbs at 250 K, leaving only polyanhydride on the surface, which at 350 K decomposes into a carboxylate, through desorption of phthalic anhydride and water. The carboxylate is stable until 500 K, after which it decomposes, through desorption of CO2 and benzene, into carbon; the latter diffuses into the bulk, leaving only a little carbon on the Ag(100) surface at 600 K. © 2015 American Chemical Society.

Registro:

Documento: Artículo
Título:Temperature-Dependent Reactions of Phthalic Acid on Ag(100)
Autor:Franke, M.; Marchini, F.; Zhang, L.; Tariq, Q.; Tsud, N.; Vorokhta, M.; Vondráček, M.; Prince, K.; Röckert, M.; Williams, F.J.; Steinrück, H.-P.; Lytken, O.
Filiación:Lehrstuhl für Physikalische Chemie II, Universität Erlangen-Nürnberg, Egerlandstraße 3, Erlangen, D-91058, Germany
Departamento de Química Inorgánica, Analítica y Química-Física, INQUIMAE-CONICET, Facultad Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, 1053, Argentina
Faculty of Mathematics and Physics, Department of Surface and Plasma Science, Charles University, V Holešovičkách 2, Prague, 18000, Czech Republic
Institute of Physics, Academy of Sciences of the Czech Republic, Cukrovarnicka 10, Prague, CZ-16200, Czech Republic
Sincrotrone Trieste SCpA, Strada Statale 14, km 163.5, Basovizza-Trieste, 34149, Italy
IOM, Strada Statale 14, km 163.5, Basovizza-Trieste, 34149, Italy
Palabras clave:Carbon dioxide; Carboxylation; Carboxylic acids; Desorption; Silver; Synchrotron radiation; X ray absorption; Ag(100); Near edge x ray absorption fine structure; Phthalic acid; Phthalic anhydrides; Polyanhydrides; Synchrotron radiation x-rays; Temperature dependent; Temperature range; Temperature programmed desorption
Año:2015
Volumen:119
Número:41
Página de inicio:23580
Página de fin:23585
DOI: http://dx.doi.org/10.1021/acs.jpcc.5b07858
Título revista:Journal of Physical Chemistry C
Título revista abreviado:J. Phys. Chem. C
ISSN:19327447
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_19327447_v119_n41_p23580_Franke

Referencias:

  • Verykios, X.E., Stein, F.P., Coughlin, R.W., Oxidation of Ethylene over Silver: Adsorption, Kinetics, Catalyst (1980) Catal. Rev.: Sci. Eng., 22, pp. 197-234
  • Qian, M., Liauw, M.A., Emig, G., Formaldehyde Synthesis from Methanol over Silver Catalysts (2003) Appl. Catal., A, 238, pp. 211-222
  • Barth, J.V., Weckesser, J., Trimarchi, G., Vladimirova, M., De Vita, A., Cai, C., Brune, H., Kern, K., Stereochemical Effects in Supramolecular Self-Assembly at Surfaces: 1-D versus 2-D Enantiomorphic Ordering for PVBA and PEBA on Ag(111) (2002) J. Am. Chem. Soc., 124, pp. 7991-8000
  • Fuhr, J.D., Carrera, A., Murillo-Quirós, N., Cristina, L.J., Cossaro, A., Verdini, A., Floreano, L., Ascolani, H., Interplay between Hydrogen Bonding and Molecule-Substrate Interactions in the Case of Terephthalic Acid Molecules on Cu(001) Surfaces (2013) J. Phys. Chem. C, 117, pp. 1287-1296
  • Gao, H.Y., Held, P.A., Knor, M., Muck-Lichtenfeld, C., Neugebauer, J., Studer, A., Fuchs, H., Decarboxylative Polymerization of 2,6-Naphthalenedicarboxylic Acid at Surfaces (2014) J. Am. Chem. Soc., 136, pp. 9658-9663
  • Lin, N., Payer, D., Dmitriev, A., Strunskus, T., Woll, C., Barth, J.V., Kern, K., Two-Dimensional Adatom Gas Bestowing Dynamic Heterogeneity on Surfaces (2005) Angew. Chem., Int. Ed., 44, pp. 1488-1491
  • Lingenfelder, M.A., Spillmann, H., Dmitriev, A., Stepanow, S., Lin, N., Barth, J.V., Kern, K., Towards Surface-Supported Supramolecular Architectures: Tailored Coordination Assembly of 1,4-Benzenedicarboxylate and Fe on Cu(100) (2004) Chem. - Eur. J., 10, pp. 1913-1919
  • Payer, D., Comisso, A., Dmitriev, A., Strunskus, T., Lin, N., Woll, C., Devita, A., Kern, K., Ionic Hydrogen Bonds Controlling Two-Dimensional Supramolecular Systems at a Metal Surface (2007) Chem. - Eur. J., 13, pp. 3900-3906
  • Ruben, M., Payer, D., Landa, A., Comisso, A., Gattinoni, C., Lin, N., Collin, J.P., Kern, K., 2D Supramolecular Assemblies of Benzene-1,3,5-triyl-tribenzoic Acid: Temperature-Induced Phase Transformations and Hierarchical Organization with Macrocyclic Molecules (2006) J. Am. Chem. Soc., 128, pp. 15644-15651
  • Stepanow, S., Strunskus, T., Lingenfelder, M., Dmitriev, A., Spillmann, H., Lin, N., Barth, J.V., Kern, K., Deprotonation-Driven Phase Transformations in Terephthalic Acid Self-Assembly on Cu(100) (2004) J. Phys. Chem. B, 108, pp. 19392-19397
  • Bisti, F., Stroppa, A., Perrozzi, F., Donarelli, M., Picozzi, S., Coreno, M., De Simone, M., Ottaviano, L., The Electronic Structure of Gas Phase Croconic Acid Compared to the Condensed Phase: More Insight into the Hydrogen Bond Interaction (2013) J. Chem. Phys., 138, p. 014308
  • Mohr, S., Doepper, T., Xu, T., Tariq, Q., Lytken, O., Laurin, M., Steinrueck, H.-P., Libuda, J., Organic Linkers on Oxide Surfaces: Adsorption and Chemical Bonding of Phthalic Anhydride on MgO(100) (2015) Surf. Sci.
  • Schöll, A., Zou, Y., Schmidt, T., Fink, R., Umbach, E., High-Resolution Photoemission Study of Different NTCDA Monolayers on Ag(111): Bonding and Screening Influences on the Line Shapes (2004) J. Phys. Chem. B, 108, pp. 14741-14748
  • Scholl, A., Zou, Y., Jung, M., Schmidt, T., Fink, R., Umbach, E., Line Shapes and Satellites in High-Resolution X-ray Photoelectron Spectra of Large Pi-Conjugated Organic Molecules (2004) J. Chem. Phys., 121, pp. 10260-10267
  • Kumar, N., Langer, R.S., Domb, A.J., Polyanhydrides: An Overview (2002) Adv. Drug Delivery Rev., 54, pp. 889-910
  • Davies, M.C., Khan, M.A., Domb, A., Langer, R., Watts, J.F., Paul, A.J., The Analysis of the Surface Chemical-Structure of Biomedical Aliphatic Polyanhydrides Using Xps and Tof-Sims (1991) J. Appl. Polym. Sci., 42, pp. 1597-1605
  • Rockey, T.J., Yang, M.C., Dai, H.L., Adsorption Energies, Inter-Adsorbate Interactions, and the Two Binding Sites within Monolayer Benzene on Ag(111) (2006) J. Phys. Chem. B, 110, pp. 19973-19978
  • Haq, S., Bainbridge, R.C., Frederick, B.G., Richardson, N.V., Anhydride Ring Chemistry at a Metal Surface (1998) J. Phys. Chem. B, 102, pp. 8807-8815
  • Perry, C.C., Haq, S., Frederick, B.G., Richardson, N.V., Face Specificity and the Role of Metal Adatoms in Molecular Reorientation at Surfaces (1998) Surf. Sci., 409, pp. 512-520
  • Frederick, B.G., Ashton, M.R., Richardson, N.V., Jones, T.S., Orientation and Bonding of Benzoic-Acid, Phthalic-Anhydride and Pyromellitic Dianhydride on Cu(110) (1993) Surf. Sci., 292, pp. 33-46
  • Jakob, P., Menzel, D., Benzene Multilayers - A Model for Their Anisotropic Growth from Vibrational Spectroscopy and Thermal-Desorption (1989) Surf. Sci., 220, pp. 70-95
  • Leon-Gutierrez, E., Garcia, G., Lopeandia, A.F., Fraxedas, J., Clavaguera-Mora, M.T., Rodriguez-Viejo, J., In Situ Nanocalorimetry of Thin Glassy Organic Films (2008) J. Chem. Phys., 129, p. 181101
  • Souda, R., Morphology, Intermixing, and Glass Transition of Amorphous Acetic-Acid Films Studied by Temperature-Programmed TOF-SIMS and TPD (2005) Chem. Phys. Lett., 413, pp. 171-175
  • Yang, M.C., Rockey, T.J., Pursell, D., Dai, H.L., Layer-by-Layer Structure in Ultrathin Aniline and Pyridine Films on Ag(111) (2001) J. Phys. Chem. B, 105, pp. 11945-11948
  • Mohr, S., Xu, T., Dopper, T., Laurin, M., Gorling, A., Libuda, J., Molecular Orientation and Structural Transformations in Phthalic Anhydride Thin Films on MgO(100)/Ag(100) (2015) Langmuir, 31, pp. 7806-7814

Citas:

---------- APA ----------
Franke, M., Marchini, F., Zhang, L., Tariq, Q., Tsud, N., Vorokhta, M., Vondráček, M.,..., Lytken, O. (2015) . Temperature-Dependent Reactions of Phthalic Acid on Ag(100). Journal of Physical Chemistry C, 119(41), 23580-23585.
http://dx.doi.org/10.1021/acs.jpcc.5b07858
---------- CHICAGO ----------
Franke, M., Marchini, F., Zhang, L., Tariq, Q., Tsud, N., Vorokhta, M., et al. "Temperature-Dependent Reactions of Phthalic Acid on Ag(100)" . Journal of Physical Chemistry C 119, no. 41 (2015) : 23580-23585.
http://dx.doi.org/10.1021/acs.jpcc.5b07858
---------- MLA ----------
Franke, M., Marchini, F., Zhang, L., Tariq, Q., Tsud, N., Vorokhta, M., et al. "Temperature-Dependent Reactions of Phthalic Acid on Ag(100)" . Journal of Physical Chemistry C, vol. 119, no. 41, 2015, pp. 23580-23585.
http://dx.doi.org/10.1021/acs.jpcc.5b07858
---------- VANCOUVER ----------
Franke, M., Marchini, F., Zhang, L., Tariq, Q., Tsud, N., Vorokhta, M., et al. Temperature-Dependent Reactions of Phthalic Acid on Ag(100). J. Phys. Chem. C. 2015;119(41):23580-23585.
http://dx.doi.org/10.1021/acs.jpcc.5b07858