Abstract:
Sphere segment void (SSV) arrays allow the reproducible engineering of plasmon-polariton modes from the near-infrared to the ultraviolet through the tuning of the void height and diameter. The wavelength dependence of surface-enhanced Raman scattering (SERS) can then in principle be controlled by selecting these parameters. Using 4-mercaptopyridine as a covalently bonded nonresonant molecular probe, we report a detailed study of such wavelength dependence of SERS in Au SSV arrays as a function of void diameter and height. We conclude that the SERS mechanism on SSV arrays depends on the plasmonic properties of the substrates and also that additional effects contribute significantly to the observed enhancement including a chemical contribution related to the molecular probe and a nanostructuring induced surface plasmon localization existent for the smaller cavity dimensions. © 2012 American Chemical Society.
Registro:
Documento: |
Artículo
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Título: | Incident wavelength resolved resonant SERS on au sphere segment void (SSV) arrays |
Autor: | Tognalli, N.G.; Fainstein, A.; Calvo, E.J.; Abdelsalam, M.; Bartlett, P.N. |
Filiación: | Centro Atómico Bariloche and Instituto Balseiro, Comisión Nacional de Energía Atómica, 8400 S. C. de Bariloche, Río Negro, Argentina Electrochemistry Group, INQUIMAE FCEyN, Pabellon 2, Ciudad Universitaria, AR-1428 Buenos Aires, Argentina School of Chemistry, University of Southampton, Southampton, SO17 1BJ, United Kingdom
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Palabras clave: | 4-mercaptopyridine; Cavity dimension; Covalently bonded; Incident wavelength; Molecular Probes; Nano-structuring; Near Infrared; Nonresonant; Plasmon-polariton modes; Plasmonic properties; Surface plasmons; Surface-enhanced Raman scattering; Void diameter; Wavelength dependence; Probes; Spheres; Substrates |
Año: | 2012
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Volumen: | 116
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Número: | 5
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Página de inicio: | 3414
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Página de fin: | 3420
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DOI: |
http://dx.doi.org/10.1021/jp211049u |
Título revista: | Journal of Physical Chemistry C
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Título revista abreviado: | J. Phys. Chem. C
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ISSN: | 19327447
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_19327447_v116_n5_p3414_Tognalli |
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Citas:
---------- APA ----------
Tognalli, N.G., Fainstein, A., Calvo, E.J., Abdelsalam, M. & Bartlett, P.N.
(2012)
. Incident wavelength resolved resonant SERS on au sphere segment void (SSV) arrays. Journal of Physical Chemistry C, 116(5), 3414-3420.
http://dx.doi.org/10.1021/jp211049u---------- CHICAGO ----------
Tognalli, N.G., Fainstein, A., Calvo, E.J., Abdelsalam, M., Bartlett, P.N.
"Incident wavelength resolved resonant SERS on au sphere segment void (SSV) arrays"
. Journal of Physical Chemistry C 116, no. 5
(2012) : 3414-3420.
http://dx.doi.org/10.1021/jp211049u---------- MLA ----------
Tognalli, N.G., Fainstein, A., Calvo, E.J., Abdelsalam, M., Bartlett, P.N.
"Incident wavelength resolved resonant SERS on au sphere segment void (SSV) arrays"
. Journal of Physical Chemistry C, vol. 116, no. 5, 2012, pp. 3414-3420.
http://dx.doi.org/10.1021/jp211049u---------- VANCOUVER ----------
Tognalli, N.G., Fainstein, A., Calvo, E.J., Abdelsalam, M., Bartlett, P.N. Incident wavelength resolved resonant SERS on au sphere segment void (SSV) arrays. J. Phys. Chem. C. 2012;116(5):3414-3420.
http://dx.doi.org/10.1021/jp211049u