Artículo

Hojamberdiev, M.; Kadirova, Z.C.; Makinose, Y.; Zhu, G.; Matsushita, N.; Rodríguez, J.; Bilmes, S.A.; Hasegawa, M.; Okada, K. "Influence of BiOI content on the photocatalytic activity of Bi 2 WO 6 /BiOI/allophane composites and molecular modeling studies of acetaldehyde adsorption" (2017) Journal of the Taiwan Institute of Chemical Engineers. 81:258-264
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Abstract:

As a major indoor volatile organic compound, acetaldehyde is considered to be toxic when applied externally for prolonged periods; it is an irritant and a probable carcinogen. In this work, Bi 2 WO 6 /BiOI/allophane (BW/BI/A) composites with different molar ratios of Bi 2 WO 6 :BiOI were prepared by either mechanical mixing or a hydrothermal synthesis. The adsorption capacity and photocatalytic activity of the prepared composites were evaluated for the adsorption and photodegradation of gaseous acetaldehyde in the dark and under visible light irradiation, respectively. SEM revealed that with increasing BiOI content, the overall morphology of the BW/BI/A composite was altered because BiOI nanoparticles gradually occupied the surfaces of the nanosheets, which formed flower-like structures, and eventually covered the surfaces of the Bi 2 WO 6 particles. Adsorption affinities and preferential adsorption sites of acetaldehyde molecules on the Bi 2 WO 6 , BiOI, and allophane components of the BW/BI/A composite were also predicted using molecular dynamics simulations. The BW/0.5BI/A composite exhibited high adsorption capacity, excellent photocatalytic performance and good stability owing to its large specific surface area, greater number of easily accessible active sites, facilitated diffusion of reactants, multiple scattering of incident light, and formed p–n heterojunction, which suggest that it can be used in environmental remediation in the future. © 2017 Taiwan Institute of Chemical Engineers

Registro:

Documento: Artículo
Título:Influence of BiOI content on the photocatalytic activity of Bi 2 WO 6 /BiOI/allophane composites and molecular modeling studies of acetaldehyde adsorption
Autor:Hojamberdiev, M.; Kadirova, Z.C.; Makinose, Y.; Zhu, G.; Matsushita, N.; Rodríguez, J.; Bilmes, S.A.; Hasegawa, M.; Okada, K.
Filiación:Department of Materials Physics, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8603, Japan
Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama, Kanagawa 226-8503, Japan
Department of Silicate Materials and Rare Earth and Noble Metals, Tashkent Institute of Chemical Technology, Navoi Street 32, Tashkent, 100011, Uzbekistan
Interdisciplinary Graduate School of Science and Engineering, Shimane University, 1060, Matsue, Shimane 690-8504, Japan
School of Physics and Information Technology, Shaanxi Normal University, Xi'an, Shaanxi 710062, China
Facultad de Ciencias, Universidad Nacional de Ingeniería, P.O. Box 31-139, Av. Tupac Amaru 210, Lima, Peru
Instituto de Química Física de los Materiales, Medio Ambiente y Energía (INQUIMAE), Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, Ciudad Universitaria, Buenos Aires, C1428EHA, Argentina
Palabras clave:Acetaldehyde; Allophane; Bi 2 WO 6; BiOI; Molecular dynamics; Photocatalytic activity; Acetaldehyde; Adsorption; Aluminosilicates; Complexation; Heterojunctions; Hydrothermal synthesis; Indoor air pollution; Light; Molecular dynamics; Photocatalysis; Photodegradation; Volatile organic compounds; Allophane; Bi2WO6; BiOI; Large specific surface areas; Molecular dynamics simulations; Molecular modeling studies; Photocatalytic activities; Photocatalytic performance; Bismuth compounds
Año:2017
Volumen:81
Página de inicio:258
Página de fin:264
DOI: http://dx.doi.org/10.1016/j.jtice.2017.10.008
Título revista:Journal of the Taiwan Institute of Chemical Engineers
Título revista abreviado:J. Taiwan Inst. Chem. Eng.
ISSN:18761070
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_18761070_v81_n_p258_Hojamberdiev

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Citas:

---------- APA ----------
Hojamberdiev, M., Kadirova, Z.C., Makinose, Y., Zhu, G., Matsushita, N., Rodríguez, J., Bilmes, S.A.,..., Okada, K. (2017) . Influence of BiOI content on the photocatalytic activity of Bi 2 WO 6 /BiOI/allophane composites and molecular modeling studies of acetaldehyde adsorption. Journal of the Taiwan Institute of Chemical Engineers, 81, 258-264.
http://dx.doi.org/10.1016/j.jtice.2017.10.008
---------- CHICAGO ----------
Hojamberdiev, M., Kadirova, Z.C., Makinose, Y., Zhu, G., Matsushita, N., Rodríguez, J., et al. "Influence of BiOI content on the photocatalytic activity of Bi 2 WO 6 /BiOI/allophane composites and molecular modeling studies of acetaldehyde adsorption" . Journal of the Taiwan Institute of Chemical Engineers 81 (2017) : 258-264.
http://dx.doi.org/10.1016/j.jtice.2017.10.008
---------- MLA ----------
Hojamberdiev, M., Kadirova, Z.C., Makinose, Y., Zhu, G., Matsushita, N., Rodríguez, J., et al. "Influence of BiOI content on the photocatalytic activity of Bi 2 WO 6 /BiOI/allophane composites and molecular modeling studies of acetaldehyde adsorption" . Journal of the Taiwan Institute of Chemical Engineers, vol. 81, 2017, pp. 258-264.
http://dx.doi.org/10.1016/j.jtice.2017.10.008
---------- VANCOUVER ----------
Hojamberdiev, M., Kadirova, Z.C., Makinose, Y., Zhu, G., Matsushita, N., Rodríguez, J., et al. Influence of BiOI content on the photocatalytic activity of Bi 2 WO 6 /BiOI/allophane composites and molecular modeling studies of acetaldehyde adsorption. J. Taiwan Inst. Chem. Eng. 2017;81:258-264.
http://dx.doi.org/10.1016/j.jtice.2017.10.008