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Abstract:

The composition of river water, sediments, and pore waters (down to 30 cm below the bed) of Las Catonas Stream was studied to analyze the distribution of trace elements in a peri-urban site. The Las Catonas Stream is one of the main tributaries of Reconquista River, a highly polluted water course in the Buenos Aires Province, Argentina. The semi-consolidated Quaternary sediments of the Luján Formation are the main source of sediments for Las Catonas Stream. The coarse-grained fraction in the sediments is mainly composed of tosca (calcretes), intraclasts, bone fragments, glass shards, quartz, and aggregates of fine-grained sediments together with considerably amounts of vegetal remains. The clay minerals are illite, illite–smectite, smectite, and kaolinite. For the clay-sized fraction, the external surface area values are mostly between 70 and 110 m2g−1, although the fraction at 15 cm below the bottom of the river shows a lower surface area of 12 m2g−1. The N2 adsorption–desorption isotherms at 77 K for this sample display a behavior indicative of non-porous or macroporous material, whereas the samples above and below present a typical behavior of mesoporous materials with pores between parallel plates (slit-shaped). As, Cr, Cu, and Cd concentrations increase down to 15 cm depth in the sediments, where the highest trace element and total organic carbon (TOC) concentrations were found, and then decrease toward the bottom of the core. Except for As, the levels of the other heavy metals show higher concentration in surficial waters than in pore waters. Distribution coefficients between the sediments, pore water, and surficial water phases indicate that As is released from the sediments to the pore and surficial waters. Cu content strongly correlates with TOC (mainly from vegetal remains), suggesting that this element is mainly bound to the organic phase. © 2018, Springer-Verlag GmbH Germany, part of Springer Nature.

Registro:

Documento: Artículo
Título:Mobility of trace elements between the river water, the sediments, and the pore water of Las Catonas Stream, Buenos Aires Province, Argentina
Autor:Cantera, C.G.; Scasso, R.A.; Tufo, A.; Villalba, L.B.; dos Santos Afonso, M.
Filiación:Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires (IGEBA), CONICET-Universidad de Buenos Aires, Ciudad Universitaria Pabellón II 1er Piso, Int. Guiraldes 2160, Ciudad Autónoma de Buenos Aires, C1428EHA, Argentina
Departamento de Ciencias Geológicas, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria Pabellón II 1er Piso, Int. Guiraldes 2160, Ciudad Autónoma de Buenos Aires, C1428EHA, Argentina
Instituto de Investigación e Ingeniería Ambiental (3iA), Universidad Nacional de San Martín, Campus Miguelete, 25 de Mayo y Francia, San Martín, Buenos Aires 1650, Argentina
Coordinación de Activos y Residuos Químicos, Departamento de Medicamentos y Contaminantes, Área Absorción Atómica, SENASA, Talcahuano 1660, Martínez, Buenos Aires B1640CZT, Argentina
Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Instituto de Química Física de los Materiales, Medio Ambiente y Energía (INQUIMAE), CONICET-Universidad de Buenos Aires, Ciudad Universitaria Pabellón II 3er Piso, Int. Guiraldes 2160, Ciudad Autónoma de Buenos Aires, C1428EHA, Argentina
Palabras clave:Clay minerals; Geochemistry; Heavy metals; Partitioning coefficient; Clay minerals; Geochemistry; Heavy metals; Kaolinite; Mesoporous materials; Organic carbon; River pollution; Surficial sediments; Trace elements; Urban growth; Water; Clay-sized fractions; Desorption isotherms; Distribution coefficient; Fine-grained sediment; Macroporous materials; Partitioning coefficients; Quaternary sediments; Total Organic Carbon; Rivers; clay mineral; concentration (composition); fine grained sediment; heavy metal; mobility; partition coefficient; periurban area; porewater; river water; sediment pollution; surface water; total organic carbon; trace element; tributary; water pollution; Argentina; Buenos Aires [Argentina]; Reconquista River
Año:2018
Volumen:77
Número:14
DOI: http://dx.doi.org/10.1007/s12665-018-7699-5
Título revista:Environmental Earth Sciences
Título revista abreviado:Environ. Earth Sci.
ISSN:18666280
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_18666280_v77_n14_p_Cantera

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Citas:

---------- APA ----------
Cantera, C.G., Scasso, R.A., Tufo, A., Villalba, L.B. & dos Santos Afonso, M. (2018) . Mobility of trace elements between the river water, the sediments, and the pore water of Las Catonas Stream, Buenos Aires Province, Argentina. Environmental Earth Sciences, 77(14).
http://dx.doi.org/10.1007/s12665-018-7699-5
---------- CHICAGO ----------
Cantera, C.G., Scasso, R.A., Tufo, A., Villalba, L.B., dos Santos Afonso, M. "Mobility of trace elements between the river water, the sediments, and the pore water of Las Catonas Stream, Buenos Aires Province, Argentina" . Environmental Earth Sciences 77, no. 14 (2018).
http://dx.doi.org/10.1007/s12665-018-7699-5
---------- MLA ----------
Cantera, C.G., Scasso, R.A., Tufo, A., Villalba, L.B., dos Santos Afonso, M. "Mobility of trace elements between the river water, the sediments, and the pore water of Las Catonas Stream, Buenos Aires Province, Argentina" . Environmental Earth Sciences, vol. 77, no. 14, 2018.
http://dx.doi.org/10.1007/s12665-018-7699-5
---------- VANCOUVER ----------
Cantera, C.G., Scasso, R.A., Tufo, A., Villalba, L.B., dos Santos Afonso, M. Mobility of trace elements between the river water, the sediments, and the pore water of Las Catonas Stream, Buenos Aires Province, Argentina. Environ. Earth Sci. 2018;77(14).
http://dx.doi.org/10.1007/s12665-018-7699-5