Artículo

Barreiro, N.L.; Méndez, J.R.; Slezak, V.B. "Thermal lens spectroscopy excited with two wavelengths " (2018) Anales de la Asociacion Fisica Argentina. 29(3):90-96
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Abstract:

There is a worldwide need for low cost devices with high sensitivity and selectivity for water monitoring and medical and biological analysis. Most commercial equipments suitable for this type of applications are of big dimensions and / or excessive costs. Other types of methods require sample pre-treatments or pre-concentrations making them time consuming. In this work we show the design of a compact low cost thermal lens system for water monitoring. The device is made up of two compact excitation lasers (pointers) of different wavelengths, 405 nm and 532 nm, modulated at low frequencies (4 and 7 Hz respectively), allowing differential measurements in real time. It also includes a red laser diode as probe which goes through the sample collinearly with the excitation beams. A small sample of the probe beam impinges on a 200μm core optic fiber and is guided to a photodiode. The detector signal is digitized by an Arduino microcontroller and sent to a PC to be analyzed. The signal processing is made in real time applying a Fast Fourier Transform to distinguish the signals that come from both excitation sources. A flow injection analysis system was implemented in order to speed up measurements. In this work we show how this system works using low toxicity dyes. © 2018, Centro de Investigaciones en Laseres y Aplicaciones. All rights reserved.

Registro:

Documento: Artículo
Título:Thermal lens spectroscopy excited with two wavelengths
Autor:Barreiro, N.L.; Méndez, J.R.; Slezak, V.B.
Filiación:Departamento de Investigaciones en Láseres y Aplicaciones DEILAP (CITEDEF-CONICET, Juan Bautista de La Salle 4397, Villa Martelli, Prov. Buenos Aires B1603ALO, Argentina
Alumno de la Carrera de Ciencias Físicas, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Palabras clave:Spectroscopy; Thermal lens; Water monitoring
Año:2018
Volumen:29
Número:3
Página de inicio:90
Página de fin:96
DOI: http://dx.doi.org/10.31527/analesafa.2018.29.3.90
Título revista:Anales de la Asociacion Fisica Argentina
Título revista abreviado:An. Asoc. Fis. Argent.
ISSN:18501168
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_18501168_v29_n3_p90_Barreiro

Referencias:

  • (1996) Water Quality Assessments-A Guide to Use of Biota, Sediments and Water in Environmental Monitoring-Second Edition, , Deborah Chapman ed., E&FN Spon, Gran Bretaña
  • Leopold, K., Foulkes, M., Worsfold, P., Methods for the determination and speciation of mercury in natural waters—a review (2010) Anal. Chim. Acta, 663, pp. 127-138
  • Ramesh, A., Rama Mohan, K., Seshaiah, K., Jeyakumar, N.D., Determination of trace elements by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after preconcentration on a support impregnated with piperidinedithiocarbamate (2001) Anal. Lett., 34 (2), pp. 219-229
  • Popp, M., Hann, S., Koellensperger, G., Environmental application of elemental speciation analysis based on liquid or gas chromatography hyphenated to inductively coupled plasma mass spectrometry—A review (2010) Anal. Chim. Acta, 668, pp. 114-129
  • Sandell, E.B., (1959) Chemical Analysis Vol III: Colorimetric Determination of Traces of Metal, , 3 rd edition, Clarke B. L., Elving P. J., Kolthoff L. M. (eds.); Interscience Publishers Inc, New York
  • Legeai, S., Vittori, O., A Cu/Nafion/Bi electrode for on-site monitoring of trace heavy metals in natural waters using anodic stripping voltammetry: An alternative to mercury-based electrodes (2006) Anal. Chim. Acta, 560, pp. 184-190
  • Bersier, P.M., Howell, J., Bruntlett, C., Tutorial review. Advanced electroanalytical techniques versus atomic absorption spectrometry, inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry in environmental analysis (1994) Analyst, 119, pp. 219-232
  • Franko, M., Thermal Lens Spectrometric Detection in Flow Injection Analysis and Separation Techniques (2008) Appl. Spectrosc. Rev., 43 (4), pp. 358-388
  • Bialkowski, S., (1996) Phototermal Spectroscopy Methods for Chemical Analysis, , John Wiley & Sons: Nueva York
  • Vyas, R., Gupta, R., Photothermal lensing spectroscopy in a flowing medium: Theory (1988) Appl. Opt., 27, pp. 4701-4711
  • Franko, M., Tran, C.D., Thermal lens spectroscopy (2010) Encyclopedia of Analytical Chemistry, , Meyers R. A. (ed.), Wiley-Interscience Publication
  • Franko, M., Tran, C.D., Development of a double-beam, dual-wavelength thermal-lens spectrometer for simultaneous measurement of absorption at two different wavelengths (1988) Anal. Chem., 60, pp. 1925-1928
  • Liu, M., Korte, D., Franko, M., Theoretical description of thermal lens spectrometry in micro space (2012) J. Appl. Phys., 111
  • Sheldon, S.J., Knight, L.V., Thorne, J.M., Laser-induced thermal lens effect: A new theoretical model (1982) Appl. Opt., 21, pp. 1663-1669
  • Shen, J., Lowe, R.D., Snook, R.D., A model for cw laser induced mode-mismatched dual-beam thermal lens spectrometry (1992) Chem. Phys., 165, pp. 385-396
  • Slezak, V., Signal processing in pulsed photoacoustic detection of traces by means of a fast Fourier transform-based method (2003) Rev.Sci.Instrum., 74, pp. 642-644
  • Maity, D., Govindaraju, T., Highly Selective Colorimetric Chemosensor for Co2+ (2011) Inorg. Chem., 50, pp. 11282-11284

Citas:

---------- APA ----------
Barreiro, N.L., Méndez, J.R. & Slezak, V.B. (2018) . Thermal lens spectroscopy excited with two wavelengths . Anales de la Asociacion Fisica Argentina, 29(3), 90-96.
http://dx.doi.org/10.31527/analesafa.2018.29.3.90
---------- CHICAGO ----------
Barreiro, N.L., Méndez, J.R., Slezak, V.B. "Thermal lens spectroscopy excited with two wavelengths " . Anales de la Asociacion Fisica Argentina 29, no. 3 (2018) : 90-96.
http://dx.doi.org/10.31527/analesafa.2018.29.3.90
---------- MLA ----------
Barreiro, N.L., Méndez, J.R., Slezak, V.B. "Thermal lens spectroscopy excited with two wavelengths " . Anales de la Asociacion Fisica Argentina, vol. 29, no. 3, 2018, pp. 90-96.
http://dx.doi.org/10.31527/analesafa.2018.29.3.90
---------- VANCOUVER ----------
Barreiro, N.L., Méndez, J.R., Slezak, V.B. Thermal lens spectroscopy excited with two wavelengths . An. Asoc. Fis. Argent. 2018;29(3):90-96.
http://dx.doi.org/10.31527/analesafa.2018.29.3.90