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Abstract:

In this work an imaging method used for studying metallic system oxidation is presented. This implementation monitors changes in the molecular absorption of visible light with a redox probe, a ruthenium polypyridine complex. As the transmission microscopy method avoids irradiation of the sample with high intensity light in comparison to fluorescence techniques, images can be acquired using an inexpensive commercial digital camera, making this an excellent low-cost tool for oxidation mapping. Molar fractions of reduced and oxidized species of the probe are calculated using different channels of an RGB camera, green and red, respectively, allowing a ratiometric measurement for redox potential determination with a high temporal and spatial resolution. © The Royal Society of Chemistry.

Registro:

Documento: Artículo
Título:A ratiometric method for the oxidation mapping of metallic systems
Autor:Gaviglio, C.; Carrone, G.
Filiación:Comisión Nacional de Energía Atómica, CAC-GIyANN, Departamento de Física de la Materia Condensada, Avenida General Paz 1499, San-Martín-Buenos-Aires, 1650, Argentina
Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria Pabellón 2, Buenos Aires, AR1428EHA, Argentina
Palabras clave:Light; Mapping; Metallography; Probes; Redox reactions; Ruthenium compounds; Fluorescence technique; Imaging method; Metallic systems; Molar fractions; Molecular absorption; Redox potentials; Temporal and spatial; Transmission microscopy; Oxidation
Año:2018
Volumen:10
Número:17
Página de inicio:2007
Página de fin:2015
DOI: http://dx.doi.org/10.1039/c8ay00241j
Título revista:Analytical Methods
Título revista abreviado:Anal. Methods
ISSN:17599660
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_17599660_v10_n17_p2007_Gaviglio

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Citas:

---------- APA ----------
Gaviglio, C. & Carrone, G. (2018) . A ratiometric method for the oxidation mapping of metallic systems. Analytical Methods, 10(17), 2007-2015.
http://dx.doi.org/10.1039/c8ay00241j
---------- CHICAGO ----------
Gaviglio, C., Carrone, G. "A ratiometric method for the oxidation mapping of metallic systems" . Analytical Methods 10, no. 17 (2018) : 2007-2015.
http://dx.doi.org/10.1039/c8ay00241j
---------- MLA ----------
Gaviglio, C., Carrone, G. "A ratiometric method for the oxidation mapping of metallic systems" . Analytical Methods, vol. 10, no. 17, 2018, pp. 2007-2015.
http://dx.doi.org/10.1039/c8ay00241j
---------- VANCOUVER ----------
Gaviglio, C., Carrone, G. A ratiometric method for the oxidation mapping of metallic systems. Anal. Methods. 2018;10(17):2007-2015.
http://dx.doi.org/10.1039/c8ay00241j