Abstract:
In this work an imaging method used for studying metallic system oxidation is presented. This implementation monitors changes in the molecular absorption of visible light with a redox probe, a ruthenium polypyridine complex. As the transmission microscopy method avoids irradiation of the sample with high intensity light in comparison to fluorescence techniques, images can be acquired using an inexpensive commercial digital camera, making this an excellent low-cost tool for oxidation mapping. Molar fractions of reduced and oxidized species of the probe are calculated using different channels of an RGB camera, green and red, respectively, allowing a ratiometric measurement for redox potential determination with a high temporal and spatial resolution. © The Royal Society of Chemistry.
Registro:
Documento: |
Artículo
|
Título: | A ratiometric method for the oxidation mapping of metallic systems |
Autor: | Gaviglio, C.; Carrone, G. |
Filiación: | Comisión Nacional de Energía Atómica, CAC-GIyANN, Departamento de Física de la Materia Condensada, Avenida General Paz 1499, San-Martín-Buenos-Aires, 1650, Argentina Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria Pabellón 2, Buenos Aires, AR1428EHA, Argentina
|
Palabras clave: | Light; Mapping; Metallography; Probes; Redox reactions; Ruthenium compounds; Fluorescence technique; Imaging method; Metallic systems; Molar fractions; Molecular absorption; Redox potentials; Temporal and spatial; Transmission microscopy; Oxidation |
Año: | 2018
|
Volumen: | 10
|
Número: | 17
|
Página de inicio: | 2007
|
Página de fin: | 2015
|
DOI: |
http://dx.doi.org/10.1039/c8ay00241j |
Título revista: | Analytical Methods
|
Título revista abreviado: | Anal. Methods
|
ISSN: | 17599660
|
Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_17599660_v10_n17_p2007_Gaviglio |
Referencias:
- Kirby, B.B., Takada, N., Latimer, A.J., Shin, J., Carney, T.J., Kelsh, R.N., Appel, B., (2006) Nat. Neurosci., 9 (12), p. 1506
- Ellenberq, J., Lippincott-Schwartz, J., Presley, J.F., (1999) Trends Cell Biol., 9 (2), p. 52
- Gendrin, C., Roggo, Y., Spiegel, C., Collect, C., (2008) Eur. J. Pharm. Biopharm., 68, p. 828
- Bedner, P., Niessen, H., Odermatt, B., Kretz, M., Willecke, K., Harz, H., (2006) J. Biol. Chem., 281 (10), p. 6673
- Bouffier, L., Doneux, T., Goudeau, B., Kuhn, A., (2014) Anal. Chem., 86, p. 3708
- Wu, C., Bull, B., Szymanski, C., Christensen, K., McNeill, J., (2008) ACS Nano, 2 (11), p. 2415
- Yuan, L., Lin, W., Zheng, K., He, L., Huang, W., (2013) Chem. Soc. Rev., 42, p. 622
- Xu, C., Williams, R.M., Zipfel, W., Webb, W.W., (1996) Bioimaging, 4, p. 198
- Frangioni, J.V., (2003) Curr. Opin. Chem. Biol., 7, p. 626
- Filevich, O., Carrone, G., Andino Pavlovsky, V., Etchenique, R., (2012) Anal. Chem., 84 (13), p. 5618
- Davis, R.M., Sowers, A.L., Degraff, W., Bernardo, M., Thetford, A., Krishna, M.C., Mitchell, J.B., (2011) Free Radical Biol. Med., 51 (3), p. 780
- Gutscher, M., Pauleau, A.L., Marty, L., Brach, T., Wabnitz, G.H., Samstag, Y., Meyer, A.J., Dick, T.P., (2008) Nat. Methods, 5, p. 553
- Eto, H., Hyodo, F., Kosem, N., Kobayashi, R., Yasukawa, K., Nakao, M., Nikiwa, M., Utsumi, H., (2015) Free Radical Biol. Med., 89, p. 1097
- Yang, Y., Scenini, F., Curioni, M., (2016) Electrochim. Acta, 198, p. 174
- Williams, G., McMurray, H.N., Haymana, D., Morgan, P.C., (2001) PhysChemComm, 6, p. 1
- Street, S.R., Mi, N., Cook, A.J.M.C., Mohammed-Ali, H.B., Guo, L., Rayment, T., Davenport, A.J., (2015) Faraday Discuss., 180, p. 251
- Passaretti Filho, J., Gomes Valente, M.A., Jr., De Lima Gomes, P.C.F., Fugivara, C.S., Cardoso, A.A., (2017) Anal. Methods, 9, p. 665
- Montemor, M.F., (2014) Surf. Coat. Technol., 258, p. 17
- Ates, M., (2016) J. Adhes. Sci. Technol., 30 (14), p. 1510
- Cicek, V., (2017) Corrosion Engineering and Cathodic Protection Handbook: With An Extensive Question and Answer Section, , John Wiley & Sons
- Uhlig, H.H., (2011) Uhlig's Corrosion Handbook, 51. , John Wiley & Sons
- Makhlouf, A.S.H., (2014) Handbook of Smart Coatings for Materials Protection, , no. 64, Elsevier
- Marcus, P., Mansfeld, F., (2006) Analytical Methods in Corrosion Science and Engineering, , CRC Press, NY
- Amirudin, A., Thieny, D., (1995) Prog. Org. Coat., 26, p. 1
- Huang, V.M., Wu, S.L., Orazem, M.E., Pébère, N., Tribollet, B., Vivier, V., (2011) Electrochim. Acta, 56 (23), p. 8048
- Bastos, A.C., Quevedo, M.C., Karavai, O.V., Ferreira, M.G.S., (2017) J. Electrochem. Soc., 164 (14), p. 973
- Rohwerder, M., Turcu, F., (2007) Electrochim. Acta, 53, p. 290
- Tallman, D.E., Jensen, M.B., Applications of Scanning Electrochemical Microscopy in Corrosion Research (2012) Scanning Electrochemical Microscopy, pp. 451-488. , ed. A. J. Bard and M. V. Mirkin, CRC Press
- Payne, N.A., Stephens, L.I., Mauzeroll, J., (2017) Corrosion, 73 (7), p. 759
- Lever, A.B.P., (1990) Inorg. Chem., 29 (6), p. 1271
- Dodsworth, E.S., Lever, A.B.P., (1986) Chem. Phys. Lett., 124 (2), p. 152
- Kalyanasundaram, K., (1982) Coord. Chem. Rev., 46, p. 159
- Sullivan, B.P., Salmon, D.J., Meyer, T.J., (1978) Inorg. Chem., 17 (12), p. 3334
- Pinnick, D.V., Durham, B., (1984) Inorg. Chem., 23 (10), p. 1440
- Bahreman, A., Cuello-Garibo, J.A., Bonnet, S., (2014) Dalton Trans., 43 (11), p. 4494
- Zayat, L., Filevich, O., Baraldo, L.M., Etchenique, R., (2015) Struct. Bonding, 165, p. 47
- White, J.K., Schmehl, R.H., Turro, C., (2017) Inorg. Chim. Acta, 454, p. 7
- Carrone, G., Etchenique, R., (2015) Anal. Chem., 87 (8), p. 4363
- Cuello-Garibo, J.A., Meijer, M.S., Bonnet, S., (2017) Chem. Commun., 53, p. 6768
- Carrone, G., Pellegrino, J., Doctorovich, F., (2017) Chem. Commun., 53, p. 5314
- Lameijer, L.N., Ernst, D., Hopkins, S.L., Meijer, M.S., Askes, S.H., Le Dévédec, S.E., Bonnet, S., (2017) Angew. Chem., Int. Ed., 56 (38), p. 11549
- Respondek, T., Sharma, R., Herroon, M.K., Garner, R.N., Knoll, J.D., Cueny, E., Kodanko, J.J., (2014) ChemMedChem, 9 (6), p. 1306
- Huisman, M., White, J.K., Lewalski, V.G., Podgorski, I., Turro, C., Kodanko, J.J., (2016) Chem. Commun., 52 (85), p. 12590
- Kalyanasundaram, K., Zakeeruddin, S.M., Nazeeruddin, M.K., (1994) Coord. Chem. Rev., 132, p. 259
- Nazeeruddin, M.K., Zakeeruddin, S.M., Kalyanasundaram, K., (1993) J. Phys. Chem., 97 (38), p. 9607
- Schneider, C.A., Rasband, W.S., Eliceiri, K.W., (2012) Nat. Methods, 9 (7), p. 671
- Bard, A.J., Faulkner, L.R., (2000) Electrochemical Methods: Fundamentals and Applications, , John Wiley and Sons, USA, 2nd edn
- Ikeuchi, H., Naganuma, K., Ichikawa, M., Ozawa, H., Ino, T., Sato, M., Yonezawa, H., Hashimoto, T., (2007) J. Solution Chem., 36 (10), p. 1243
- Matsuda, H., Ayabe, Y., (1955) Bull. Chem. Soc. Jpn., 28 (6), p. 422
- Matsuda, H., Ayabe, Y., (1955) Ber. Bunsenges. Phys. Chem., 59 (6), p. 494
- Nicholson, R.S., (1965) Anal. Chem., 37 (11), p. 1351
- Taylor, R.J., Humffray, A.A., (1973) J. Electroanal. Chem., 42, p. 347
Citas:
---------- APA ----------
Gaviglio, C. & Carrone, G.
(2018)
. A ratiometric method for the oxidation mapping of metallic systems. Analytical Methods, 10(17), 2007-2015.
http://dx.doi.org/10.1039/c8ay00241j---------- CHICAGO ----------
Gaviglio, C., Carrone, G.
"A ratiometric method for the oxidation mapping of metallic systems"
. Analytical Methods 10, no. 17
(2018) : 2007-2015.
http://dx.doi.org/10.1039/c8ay00241j---------- MLA ----------
Gaviglio, C., Carrone, G.
"A ratiometric method for the oxidation mapping of metallic systems"
. Analytical Methods, vol. 10, no. 17, 2018, pp. 2007-2015.
http://dx.doi.org/10.1039/c8ay00241j---------- VANCOUVER ----------
Gaviglio, C., Carrone, G. A ratiometric method for the oxidation mapping of metallic systems. Anal. Methods. 2018;10(17):2007-2015.
http://dx.doi.org/10.1039/c8ay00241j