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Abstract:

Archaeological samples are complex in composition since they generally comprise a mixture of materials submitted to deterioration factors largely dependent on the environmental conditions. Therefore, the integration of analytical tools such as TXRF, FT-IR and GC-MS can maximize the amount of information provided by the sample. Recently, two black rock art samples of camelid figures at Alero Hornillos 2, an archaeological site located near the town of Susques (Jujuy Province, Argentina), were investigated. TXRF, selected for inorganic information, showed the presence of manganese and iron among other elements, consistent with an iron and manganese oxide as the black pigment. Aiming at the detection of any residual organic compounds, the samples were extracted with a chloroform-methanol mixture and the extracts were analyzed by FT-IR, showing the presence of bands attributable to lipids. Analysis by GC-MS of the carboxylic acid methyl esters prepared from the sample extracts, indicated that the main organic constituents were saturated (C16:0 and C18:0) fatty acids in relative abundance characteristic of degraded animal fat. The presence of minor C15:0 and C17:0 fatty acids and branched-chain iso-C16:0 pointed to a ruminant animal source. © 2008 Springer-Verlag.

Registro:

Documento: Artículo
Título:Combining TXRF, FT-IR and GC-MS information for identification of inorganic and organic components in black pigments of rock art from Alero Hornillos 2 (Jujuy, Argentina)
Autor:Vázquez, C.; Maier, M.S.; Parera, S.D.; Yacobaccio, H.; Solá, P.
Filiación:Chemistry Department, Comisión Nacional de Energía Atómica, Av. Gral Paz 1499, (B1650KNA), Buenos Aires, Argentina
Facultad de Ingeniería, Universidad de Buenos Aires, Av. Paseo Colón 1650 (C1063ACV), Buenos Aires, Argentina
UMYMFOR, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellón 2, (C1428EGA), Buenos Aires, Argentina
Instituto de Arqueología, Universidad de Buenos Aires, 25 de Mayo 221 - 3o Piso (C1002ABE), Buenos Aires, Argentina
Palabras clave:FT-IR; GC-MS; Inorganic and organic components; Prehistoric rock art; TXRF; Carboxylic acids; Fourier transform infrared spectroscopy; Gas chromatography; Inorganic compounds; Mass spectrometry; Organic compounds; Pigments; Chloroform-methanol mixture; Deterioration factors; Prehistoric rock art; Rocks; Animalia; Artiodactyla; Bovidae; Camelidae
Año:2008
Volumen:391
Número:4
Página de inicio:1381
Página de fin:1387
DOI: http://dx.doi.org/10.1007/s00216-008-2038-4
Título revista:Analytical and Bioanalytical Chemistry
Título revista abreviado:Anal. Bioanal. Chem.
ISSN:16182642
CODEN:ABCNB
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_16182642_v391_n4_p1381_Vazquez

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Citas:

---------- APA ----------
Vázquez, C., Maier, M.S., Parera, S.D., Yacobaccio, H. & Solá, P. (2008) . Combining TXRF, FT-IR and GC-MS information for identification of inorganic and organic components in black pigments of rock art from Alero Hornillos 2 (Jujuy, Argentina). Analytical and Bioanalytical Chemistry, 391(4), 1381-1387.
http://dx.doi.org/10.1007/s00216-008-2038-4
---------- CHICAGO ----------
Vázquez, C., Maier, M.S., Parera, S.D., Yacobaccio, H., Solá, P. "Combining TXRF, FT-IR and GC-MS information for identification of inorganic and organic components in black pigments of rock art from Alero Hornillos 2 (Jujuy, Argentina)" . Analytical and Bioanalytical Chemistry 391, no. 4 (2008) : 1381-1387.
http://dx.doi.org/10.1007/s00216-008-2038-4
---------- MLA ----------
Vázquez, C., Maier, M.S., Parera, S.D., Yacobaccio, H., Solá, P. "Combining TXRF, FT-IR and GC-MS information for identification of inorganic and organic components in black pigments of rock art from Alero Hornillos 2 (Jujuy, Argentina)" . Analytical and Bioanalytical Chemistry, vol. 391, no. 4, 2008, pp. 1381-1387.
http://dx.doi.org/10.1007/s00216-008-2038-4
---------- VANCOUVER ----------
Vázquez, C., Maier, M.S., Parera, S.D., Yacobaccio, H., Solá, P. Combining TXRF, FT-IR and GC-MS information for identification of inorganic and organic components in black pigments of rock art from Alero Hornillos 2 (Jujuy, Argentina). Anal. Bioanal. Chem. 2008;391(4):1381-1387.
http://dx.doi.org/10.1007/s00216-008-2038-4