Abstract:
Silver nanoparticle assemblies are embedded within mesoporous oxide thin films by an in situ mild reduction leading to nanoparticle-mesoporous oxide thin-film composites (NP@MOTF). A quantitative method based on X-ray reflectivity is developed and validated with energy dispersive spectroscopy in order to assess pore filling. The use of dilute formaldehyde solutions leads to control over the formation of silver nanoparticles within mesoporous titania films. Inclusion of silver nanoparticles in mesoporous silica requires more drastic conditions. This difference in reactivity can be exploited to selectively synthesize nanoparticles in a predetermined layer of a multilayered mesoporous stack leading to complex 1D-ordered multilayers with precise spatial location of nanometric objects. The metal oxide nanocomposites synthesized have potential applications in catalysis, optical devices, surface-enhanced Raman scattering, and metal enhancement fluorescence. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
Registro:
Documento: |
Artículo
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Título: | Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects |
Autor: | Fuertes, M.C.; Marchena, M.; Marchi, M.C.; Wolosiuk, A.; Soler-Illia, G.J.A.A. |
Filiación: | Gerencia de Química, CNEA, Centro Atómico Constituyentes, Av. Gral Paz 1499, San Martín, B1650KNA, Argentina DQIAyQF, FCEN, Universidad de Buenos Aires Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Centro Interdisciplinario de Nanociencia y Nanotecnología, Av. Rivadavia 1917, C1033AAJ, Buenos Aires, Argentina
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Palabras clave: | Electroless deposition; Mesoporous materials; Multilayers; Nanostructures; Silver nanoparticles; Carbon fiber reinforced plastics; Film preparation; Mesoporous materials; Metallic compounds; Multilayer films; Multilayers; Nanoparticles; Nanostructures; Optical instruments; Oxide films; Raman scattering; Silica; Thin films; Titanium dioxide; Titanium oxides; Complex 1; Controlled depositions; Drastic conditions; Electroless deposition; Energy dispersive; Formaldehyde solutions; In-situ; Mesoporous oxides; Mesoporous silicas; Mesoporous titania; Metal oxides; Multi-layer thin films; Multi-layered; Nanometric; Pore fillings; Potential applications; Quantitative methods; Silver nanoparticles; Spatial locations; Thin-film; X-ray reflectivities; Silver; metal; metal nanoparticle; nanoparticle; oxide; silicon dioxide; silver; titanium; titanium dioxide; article; chemistry; methodology; nanotechnology; optics; Raman spectrometry; spectrofluorometry; surface property; transmission electron microscopy; X ray; Metal Nanoparticles; Metals; Microscopy, Electron, Transmission; Nanoparticles; Nanotechnology; Optics and Photonics; Oxides; Silicon Dioxide; Silver; Spectrometry, Fluorescence; Spectrum Analysis, Raman; Surface Properties; Titanium; X-Rays |
Año: | 2009
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Volumen: | 5
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Número: | 2
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Página de inicio: | 272
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Página de fin: | 280
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DOI: |
http://dx.doi.org/10.1002/smll.200800894 |
Título revista: | Small
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Título revista abreviado: | Small
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ISSN: | 16136810
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CAS: | oxide, 16833-27-5; silicon dioxide, 10279-57-9, 14464-46-1, 14808-60-7, 15468-32-3, 60676-86-0, 7631-86-9; silver, 7440-22-4; titanium, 7440-32-6; titanium dioxide, 1317-70-0, 1317-80-2, 13463-67-7, 51745-87-0; Metals; Oxides; Silicon Dioxide, 7631-86-9; Silver, 7440-22-4; Titanium, 7440-32-6; titanium dioxide, 13463-67-7
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_16136810_v5_n2_p272_Fuertes |
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Citas:
---------- APA ----------
Fuertes, M.C., Marchena, M., Marchi, M.C., Wolosiuk, A. & Soler-Illia, G.J.A.A.
(2009)
. Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects. Small, 5(2), 272-280.
http://dx.doi.org/10.1002/smll.200800894---------- CHICAGO ----------
Fuertes, M.C., Marchena, M., Marchi, M.C., Wolosiuk, A., Soler-Illia, G.J.A.A.
"Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects"
. Small 5, no. 2
(2009) : 272-280.
http://dx.doi.org/10.1002/smll.200800894---------- MLA ----------
Fuertes, M.C., Marchena, M., Marchi, M.C., Wolosiuk, A., Soler-Illia, G.J.A.A.
"Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects"
. Small, vol. 5, no. 2, 2009, pp. 272-280.
http://dx.doi.org/10.1002/smll.200800894---------- VANCOUVER ----------
Fuertes, M.C., Marchena, M., Marchi, M.C., Wolosiuk, A., Soler-Illia, G.J.A.A. Controlled deposition of silver nanoparticles in mesoporous single- Or multilayer thin films: From tuned pore filling to selective spatial location of nanometric objects. Small. 2009;5(2):272-280.
http://dx.doi.org/10.1002/smll.200800894