Abstract:
In the title compound, [Co(C 4 H 9 )(C 14 H 11 N 2 O 2 ) 2 (C 5 H 5 N)], the Co III atom is coordinated by a butyl group, a nitro-gen-bonded pyridine and two N,N′-bidentate diphenyl-glyoximate ligands in a distorted octa-hedral geometry. The crystal structure features two short O - H⋯O bridges between the two chelating anions, with O⋯O distances less than 2.5 Å.
Registro:
Documento: |
Artículo
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Título: | Butylbis(diphenylglyoximato)(pyridine-κN)-cobalt(III) |
Autor: | Kumar, S.; Thapa, S. |
Filiación: | DQIAQF, INQUIMAE, Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, p. 3, EHA1428 Buenos Aires, Argentina Faculty of Science and Technology, Purbanchal University, Biratnagar, Nepal
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Palabras clave: | data-to-parameter ratio = 15.7; mean σ(C-C) = 0.007 Å; R factor = 0.069; single-crystal X-ray study; T = 100 K; wR factor = 0.184 |
Año: | 2012
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Volumen: | 68
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Número: | 2
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DOI: |
http://dx.doi.org/10.1107/S1600536812000153 |
Título revista: | Acta Crystallographica Section E: Structure Reports Online
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Título revista abreviado: | Acta Crystallogr. Sect. E Struct. Rep. Online
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ISSN: | 16005368
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_16005368_v68_n2_p_Kumar |
Referencias:
- Brandenburg, K., (1999) Diamond., , Crystal Impact GbR, Bonn, Germany
- Brown, K.L., (2006) Dalton Trans., pp. 1123-1133
- (2001) SMART, SAINT and SADABS., , Bruker, Bruker AXS Inc., Madison, Wisconsin, USA
- Kumar, S., Gupta, B.D., (2011) Inorg. Chem., 50, pp. 9207-9209
- Mandal, D., Gupta, B.D., (2005) Organometallics, 24, pp. 1501-1510
- Mandal, D., Gupta, B.D., (2007) Organometallics, 26, pp. 658-670
- Randaccio, L., (1999) Comments Inorg. Chem., 21, pp. 327-376
- Schrauzer, G.N., (1968) Acc. Chem. Res., 1, pp. 97-103
- Sheldrick, G.M., (2008) Acta Cryst., A64, pp. 112-122
- Zangrando, E., Trani, M., Stabon, E., Carfagna, C., Milani, B., Mestroni, G., (2003) Eur. J. Inorg. Chem., pp. 2683-2692
Citas:
---------- APA ----------
Kumar, S. & Thapa, S.
(2012)
. Butylbis(diphenylglyoximato)(pyridine-κN)-cobalt(III). Acta Crystallographica Section E: Structure Reports Online, 68(2).
http://dx.doi.org/10.1107/S1600536812000153---------- CHICAGO ----------
Kumar, S., Thapa, S.
"Butylbis(diphenylglyoximato)(pyridine-κN)-cobalt(III)"
. Acta Crystallographica Section E: Structure Reports Online 68, no. 2
(2012).
http://dx.doi.org/10.1107/S1600536812000153---------- MLA ----------
Kumar, S., Thapa, S.
"Butylbis(diphenylglyoximato)(pyridine-κN)-cobalt(III)"
. Acta Crystallographica Section E: Structure Reports Online, vol. 68, no. 2, 2012.
http://dx.doi.org/10.1107/S1600536812000153---------- VANCOUVER ----------
Kumar, S., Thapa, S. Butylbis(diphenylglyoximato)(pyridine-κN)-cobalt(III). Acta Crystallogr. Sect. E Struct. Rep. Online. 2012;68(2).
http://dx.doi.org/10.1107/S1600536812000153