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Abstract:

In the title compound, [Co(C 4 H 9 )(C 14 H 11 N 2 O 2 ) 2 (C 5 H 5 N)], the Co III atom is coordinated by a butyl group, a nitro-gen-bonded pyridine and two N,N′-bidentate diphenyl-glyoximate ligands in a distorted octa-hedral geometry. The crystal structure features two short O - H⋯O bridges between the two chelating anions, with O⋯O distances less than 2.5 Å.

Registro:

Documento: Artículo
Título:Butylbis(diphenylglyoximato)(pyridine-κN)-cobalt(III)
Autor:Kumar, S.; Thapa, S.
Filiación:DQIAQF, INQUIMAE, Universidad de Buenos Aires, Ciudad Universitaria, Pab. II, p. 3, EHA1428 Buenos Aires, Argentina
Faculty of Science and Technology, Purbanchal University, Biratnagar, Nepal
Palabras clave:data-to-parameter ratio = 15.7; mean σ(C-C) = 0.007 Å; R factor = 0.069; single-crystal X-ray study; T = 100 K; wR factor = 0.184
Año:2012
Volumen:68
Número:2
DOI: http://dx.doi.org/10.1107/S1600536812000153
Título revista:Acta Crystallographica Section E: Structure Reports Online
Título revista abreviado:Acta Crystallogr. Sect. E Struct. Rep. Online
ISSN:16005368
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_16005368_v68_n2_p_Kumar

Referencias:

  • Brandenburg, K., (1999) Diamond., , Crystal Impact GbR, Bonn, Germany
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  • (2001) SMART, SAINT and SADABS., , Bruker, Bruker AXS Inc., Madison, Wisconsin, USA
  • Kumar, S., Gupta, B.D., (2011) Inorg. Chem., 50, pp. 9207-9209
  • Mandal, D., Gupta, B.D., (2005) Organometallics, 24, pp. 1501-1510
  • Mandal, D., Gupta, B.D., (2007) Organometallics, 26, pp. 658-670
  • Randaccio, L., (1999) Comments Inorg. Chem., 21, pp. 327-376
  • Schrauzer, G.N., (1968) Acc. Chem. Res., 1, pp. 97-103
  • Sheldrick, G.M., (2008) Acta Cryst., A64, pp. 112-122
  • Zangrando, E., Trani, M., Stabon, E., Carfagna, C., Milani, B., Mestroni, G., (2003) Eur. J. Inorg. Chem., pp. 2683-2692

Citas:

---------- APA ----------
Kumar, S. & Thapa, S. (2012) . Butylbis(diphenylglyoximato)(pyridine-κN)-cobalt(III). Acta Crystallographica Section E: Structure Reports Online, 68(2).
http://dx.doi.org/10.1107/S1600536812000153
---------- CHICAGO ----------
Kumar, S., Thapa, S. "Butylbis(diphenylglyoximato)(pyridine-κN)-cobalt(III)" . Acta Crystallographica Section E: Structure Reports Online 68, no. 2 (2012).
http://dx.doi.org/10.1107/S1600536812000153
---------- MLA ----------
Kumar, S., Thapa, S. "Butylbis(diphenylglyoximato)(pyridine-κN)-cobalt(III)" . Acta Crystallographica Section E: Structure Reports Online, vol. 68, no. 2, 2012.
http://dx.doi.org/10.1107/S1600536812000153
---------- VANCOUVER ----------
Kumar, S., Thapa, S. Butylbis(diphenylglyoximato)(pyridine-κN)-cobalt(III). Acta Crystallogr. Sect. E Struct. Rep. Online. 2012;68(2).
http://dx.doi.org/10.1107/S1600536812000153