Artículo
Abstract:
The title compound {[Cu2Ho2(C4H5O2)10(H2O)4]·3H2O} n , is a one-dimensional 3d/4f organic-inorganic hybrid complex, the HoIII member of the isotypic lanthanoid series with Ln = GdIII, Er III and YIII. The structure shows an alternation of Cu2 and Ho2 dinuclear units bridged by the ligands and hydrogen bonds only. The chains are composed of Cu2 classical dinuclear 1:1:2 fourfold bridges [Cu⋯Cu = 2.6417 (9) Å] and of Ho2 units bridged by two 2:1:2 carboxyl-ate units. This results in distorted square-based pyramidal CuO5 units and irregular HoO9 units. The alternating Cu2 and Ho2 units are bridged into linear arrays along the a axis by a set of one 2:1:2 carboxyl-ate O atom and two hydrogen bonds with Cu⋯Ho separations of 4.4883 (10) and 4.5086 (10) Å. The distance between adjacent chains, as calculated by the closest and furthest distances between two chains, covers the range 10-14 Å. The H atoms of the water mol-ecules could not be located, but the O⋯O separations for these species suggest the presence of O - H⋯O hydrogen bonds.
Registro:
| Documento: | Artículo |
| Título: | catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate] |
| Autor: | Baggio, R.; Perec, M.; Garland, M.T. |
| Filiación: | Departamento de Química Inorgánica, Analítica y Química Física, INQUIMAE, Ciudad Universitaria, Pabellón II, 1428 Buenos Aires, Argentina Departamento de Física, Facultad de Ciencias Físicas y Matemáticas and CIMAT, Universidad de Chile, Santiago de Chile, Chile Departamento de Física, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina |
| Palabras clave: | Tetra |
| Año: | 2008 |
| Volumen: | 64 |
| Número: | 11 |
| Página de inicio: | m1463 |
| Página de fin: | m1464 |
| DOI: | http://dx.doi.org/10.1107/S1600536808034296 |
| Título revista: | Acta Crystallographica Section E: Structure Reports Online |
| Título revista abreviado: | Acta Crystallogr. Sect. E Struct. Rep. Online |
| ISSN: | 16005368 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_16005368_v64_n11_pm1463_Baggio |
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Citas:
---------- APA ----------
Baggio, R., Perec, M. & Garland, M.T. (2008) . catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]. Acta Crystallographica Section E: Structure Reports Online, 64(11), m1463-m1464.http://dx.doi.org/10.1107/S1600536808034296
---------- CHICAGO ----------
Baggio, R., Perec, M., Garland, M.T. "catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]" . Acta Crystallographica Section E: Structure Reports Online 64, no. 11 (2008) : m1463-m1464.http://dx.doi.org/10.1107/S1600536808034296
---------- MLA ----------
Baggio, R., Perec, M., Garland, M.T. "catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]" . Acta Crystallographica Section E: Structure Reports Online, vol. 64, no. 11, 2008, pp. m1463-m1464.http://dx.doi.org/10.1107/S1600536808034296
---------- VANCOUVER ----------
Baggio, R., Perec, M., Garland, M.T. catena-Poly[[[tetra-kis(μ-2-butenoato)dicopper(II)] -μ- 2-butenoato-[diaqua-(2-butenoato)holmium(III)]-di - 2-butenoato-[diaqua-(-μ- 2-butenoato)holmium(III)]-μ-2-butenoato] trihydrate]. Acta Crystallogr. Sect. E Struct. Rep. Online. 2008;64(11):m1463-m1464.http://dx.doi.org/10.1107/S1600536808034296
