Artículo

Torres, W.R.; Cantoni, L.; Tesio, A.Y.; Del Pozo, M.; Calvo, E.J. "EQCM study of oxygen cathodes in DMSO LiPF6 electrolyte" (2016) Journal of Electroanalytical Chemistry. 765:45-51
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Abstract:

The oxygen reduction reaction (ORR) in DMSO containing LiPF6 has been studied with the electrochemical quartz crystal microbalance (EQCM) during galvanostatic cathodic and anodic pulses, chronoamperometry and cyclic voltammetry experiments. We disclose here for the first time gravimetric evidence with the EQCM of the different mechanistic models that apply to the ORR in LiPF6/DMSO electrolyte: (i) Surface electrochemical/chemical deposition of Li2O2(s) and (ii) solution phase disproportion of LiO2(soln) yields large Li2O2 particles. The mass per electron detected with the EQCM depends on the respective current rates and thus on the mechanisms, i.e. 23 g/F for the formation of Li2O2 thin film at high current density and much larger values for low current density due to solvent co-deposition and further degradation. © 2015 Elsevier B.V. All rights reserved.

Registro:

Documento: Artículo
Título:EQCM study of oxygen cathodes in DMSO LiPF6 electrolyte
Autor:Torres, W.R.; Cantoni, L.; Tesio, A.Y.; Del Pozo, M.; Calvo, E.J.
Filiación:INQUIMAE, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellón 2, Buenos Aires, AR-1428, Argentina
Palabras clave:Battery; DMSO; EQCM; Lithium; Oxygen; Chronoamperometry; Cyclic voltammetry; Electrolytes; Electrolytic reduction; Lithium; Oxygen; Quartz crystal microbalances; Battery; DMSO; Electrochemical quartz crystal microbalance; EQCM; High current densities; Low current density; Mechanistic models; Oxygen reduction reaction; Deposition
Año:2016
Volumen:765
Página de inicio:45
Página de fin:51
DOI: http://dx.doi.org/10.1016/j.jelechem.2015.07.046
Título revista:Journal of Electroanalytical Chemistry
Título revista abreviado:J Electroanal Chem
ISSN:15726657
CODEN:JECHE
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15726657_v765_n_p45_Torres

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Citas:

---------- APA ----------
Torres, W.R., Cantoni, L., Tesio, A.Y., Del Pozo, M. & Calvo, E.J. (2016) . EQCM study of oxygen cathodes in DMSO LiPF6 electrolyte. Journal of Electroanalytical Chemistry, 765, 45-51.
http://dx.doi.org/10.1016/j.jelechem.2015.07.046
---------- CHICAGO ----------
Torres, W.R., Cantoni, L., Tesio, A.Y., Del Pozo, M., Calvo, E.J. "EQCM study of oxygen cathodes in DMSO LiPF6 electrolyte" . Journal of Electroanalytical Chemistry 765 (2016) : 45-51.
http://dx.doi.org/10.1016/j.jelechem.2015.07.046
---------- MLA ----------
Torres, W.R., Cantoni, L., Tesio, A.Y., Del Pozo, M., Calvo, E.J. "EQCM study of oxygen cathodes in DMSO LiPF6 electrolyte" . Journal of Electroanalytical Chemistry, vol. 765, 2016, pp. 45-51.
http://dx.doi.org/10.1016/j.jelechem.2015.07.046
---------- VANCOUVER ----------
Torres, W.R., Cantoni, L., Tesio, A.Y., Del Pozo, M., Calvo, E.J. EQCM study of oxygen cathodes in DMSO LiPF6 electrolyte. J Electroanal Chem. 2016;765:45-51.
http://dx.doi.org/10.1016/j.jelechem.2015.07.046