Artículo
Raffa, D.L.; Leung, K.T.; Battaglini, F. "Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization" (2006) Journal of Electroanalytical Chemistry. 587(1):60-66
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Abstract:
The electrochemical copolymerization of aniline and o-aminobenzylamine (ABA) leads to a polymer with aliphatic amino groups able to be derivatized. The synthesized material has a stoichiometry ABA:aniline ca. 1:1 when their ratio in the precursor solution range between 90:10 and 75:25. It presents similar conducting properties as polyaniline in acid medium. The conductance of the prepared polymer shows significant improvement compared to polyaniline in weak acidic to neutral media. The resulting product is able to be derivatized by mild reactions with molecules bearing a carboxylate or a carbonyl group. We show that approximately 20% of the added functional groups can be easily modified. © 2005 Elsevier B.V. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization |
| Autor: | Raffa, D.L.; Leung, K.T.; Battaglini, F. |
| Filiación: | INQUIMAE, Departamento de Química Inorgánica, Analítica y Química Física, Ciudad Universitaria, Pabellón 2, C1428EHA Buenos Aires, Argentina Department of Chemistry, University of Waterloo, 200 University Avenue W, Waterloo, Ont. N2L 3G1, Canada |
| Palabras clave: | 0-Aminobenzylamine; Aniline; Conductivity; Copolymerization; Derivatization; Polyaniline; Copolymerization; Derivatives; Electric conductance; Electrochemistry; Reaction kinetics; Solutions; Stoichiometry; Synthesis (chemical); Aniline; Derivatization; O-aminobenzylamine; Polyaniline; Amines |
| Año: | 2006 |
| Volumen: | 587 |
| Número: | 1 |
| Página de inicio: | 60 |
| Página de fin: | 66 |
| DOI: | http://dx.doi.org/10.1016/j.jelechem.2005.10.017 |
| Título revista: | Journal of Electroanalytical Chemistry |
| Título revista abreviado: | J Electroanal Chem |
| ISSN: | 15726657 |
| CODEN: | JECHE |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15726657_v587_n1_p60_Raffa |
Referencias:
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Citas:
---------- APA ----------
Raffa, D.L., Leung, K.T. & Battaglini, F. (2006) . Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization. Journal of Electroanalytical Chemistry, 587(1), 60-66.http://dx.doi.org/10.1016/j.jelechem.2005.10.017
---------- CHICAGO ----------
Raffa, D.L., Leung, K.T., Battaglini, F. "Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization" . Journal of Electroanalytical Chemistry 587, no. 1 (2006) : 60-66.http://dx.doi.org/10.1016/j.jelechem.2005.10.017
---------- MLA ----------
Raffa, D.L., Leung, K.T., Battaglini, F. "Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization" . Journal of Electroanalytical Chemistry, vol. 587, no. 1, 2006, pp. 60-66.http://dx.doi.org/10.1016/j.jelechem.2005.10.017
---------- VANCOUVER ----------
Raffa, D.L., Leung, K.T., Battaglini, F. Electrochemical copolymerization of aniline and ortho-aminobenzylamine. Studies on its conductivity and chemical derivatization. J Electroanal Chem. 2006;587(1):60-66.http://dx.doi.org/10.1016/j.jelechem.2005.10.017
