Abstract:
Iron is an essential micronutrient for higher plants. Although abundant in most soils, Fe3+ is not available for plant uptake, because of its poor solubility. Ferrous sulfate is a fertilizer used for crops but, Fe2+ is readily oxidized to the plant-unavailable ferric form. It is therefore important to provide Fe2+ to plants, minimizing the loss of this nutrient by oxidation in Fe3+. This paper reports the development of a composite material consisting of a matrix (PLARAM), obtained by the chemical modification of poly(lactic acid), capable of retaining ferrous carbonate (siderite) within PLARAM (PLARAMFe). From the matrix, Fe2+ is released into the soil, enhancing its bioavailability. PLARAM and PLARAMFe films were obtained and their water wettability was studied. One side of the films was more hydrophilic than the other, turning this material attractive as a protective film when it is necessary to avoid loss of humidity. © 2017, Springer Science+Business Media, LLC.
Registro:
Documento: |
Artículo
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Título: | Absorption of Siderite Within a Chemically Modified Poly(lactic acid) Based Composite Material for Agricultural Applications |
Autor: | Garcia, N.L.; Fascio, M.; Errea, M.I.; Dufresne, A.; Goyanes, S.; D’Accorso, N. |
Filiación: | CONICET- Universidad de Buenos Aires, Centro de Investigaciones en Hidratos de Carbono (CIHIDECAR), Buenos Aires, Argentina Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina Instituto Tecnológico de Buenos Aires, Avenida Eduardo Madero 399, C1106ACD, Ciudad Autónoma de Buenos Aires, Argentina Université Grenoble Alpes, CNRS, Grenoble INP, LGP2, Grenoble, 38000, France Departamento de Física, FCEyN, UBA and IFIBA, Conicet, Pabellón 1, Ciudad Universitaria, Buenos Aires, 1428, Argentina
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Palabras clave: | Bilayer; Biodegradable; l-Rhamnose; Nano biocomposite; Poly(lactic acid); Siderite; Biochemistry; Chemical modification; Composite materials; Iron; Lactic acid; Nutrients; Bi-layer; Biodegradable; L-rhamnose; Nano bio composites; Poly lactic acid; Siderite; Iron ores; adsorption; biodegradation; iron; nanocomposite; nutrient; organic compound; siderite; sugar; Embryophyta |
Año: | 2018
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Volumen: | 26
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Número: | 5
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Página de inicio: | 2173
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Página de fin: | 2181
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DOI: |
http://dx.doi.org/10.1007/s10924-017-1119-x |
Título revista: | Journal of Polymers and the Environment
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Título revista abreviado: | J. Polym. Environ.
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ISSN: | 15662543
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CODEN: | JPENF
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Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15662543_v26_n5_p2173_Garcia |
Referencias:
- Castro-Aguirre, E., Iñiguez-Franco, F., Samsudin, H., Fang, X., Auras, R., Poly(lactic acid)—mass production, processing, industrial applications, and end of life (2016) Adv Drug Deliv Rev, 107, pp. 333-366. , COI: 1:CAS:528:DC%2BC28XlsF2ms7w%3D
- Jamshidian, M., Tehrany, E.A., Imran, M., Jacquot, M., Desobry, S., Poly-lactic acid: production, applications, nanocomposites, and release studies (2010) Compr Rev Food Sci F, 9 (5), pp. 552-571. , COI: 1:CAS:528:DC%2BC3cXhsVCjtLzL
- Sin, L.T., Rahmat, A.R., Rahman WAWA, W.A.W.A., 1—overview of poly(lactic acid) (2013) Polylactic acid, pp. 1-70. , William Andrew Publishing, Oxford
- Sinha Ray, S., Okamoto, M., Polymer/layered silicate nanocomposites: a review from preparation to processing (2003) Progr Polym Sci, 28 (11), pp. 1539-1641
- Pluta, M., Galeski, A., Alexandre, M., Paul, M.A., Dubois, P., Polylactide/montmorillonite nanocomposites and microcomposites prepared by melt blending: structure and some physical properties (2002) J Appl Polym Sci, 86 (6), pp. 1497-1506. , COI: 1:CAS:528:DC%2BD38XntFWqsrg%3D
- Sabliov, C., Chen, H., Yada, R., (2015) Nanotechnology and functional foods: effective delivery of bioactive ingredients, , Wiley, Chichester
- Helfferich, F.G., (1962) Ion exchange, , McGraw-Hill, New York
- Del Campilllo Garcia, M.C., Sanchez Alcala, I., (2010) Method for preventing and correcting iron chlorosis in plants, , Patent WO2010076353
- Garcia, N., Lamanna, M., D’Accorso, N., Dufresne, A., Aranguren, M., Goyanes, S., Biodegradable materials from grafting of modified PLA onto starch nanocrystals (2012) Polym Degrad Stab, 97, pp. 2021-2026. , COI: 1:CAS:528:DC%2BC38XlsFWgtr8%3D
- Liu, X., Wang, H., Su, C., Zhang, P., Bai, J., ) Controlled fabrication and characterization of microspherical FeCO3 and α-Fe2O3 (2010) J Colloid Interface Sci, 351 (2), pp. 427-432. , COI: 1:CAS:528:DC%2BC3cXht1SnsbrP
- Qu, X.-F.Y., Qi-Zhi, Z., Gen-Tao, Synthesis of siderite microspheres and their transformation to magnetite microspheres (2011) Eur J Mineral, 11 (23), pp. 759-770
- Guan, J., Yan, G., Wang, W., Liu, J., External field-assisted solution synthesis and selectively catalytic properties of amorphous iron nanoplatelets (2012) J Mater Chem, 22 (9), pp. 3909-3915. , COI: 1:CAS:528:DC%2BC38XhvFamtrk%3D
- Kopinke, F.D., Remmler, M., Mackenzie, K., Möder, M., Wachsen, O., Thermal decomposition of biodegradable polyesters—II. Poly(lactic acid) (1996) Polym Degrad Stab, 53 (3), pp. 329-342. , COI: 1:CAS:528:DyaK28XmtFCmtLg%3D
- Piemonte, V., Gironi, F., Kinetics of hydrolytic degradation of PLA (2013) J Polym Environ, 21 (2), pp. 313-318. , COI: 1:CAS:528:DC%2BC3sXlslyms7k%3D
- García, N.L., Ribba, L., Dufresne, A., Aranguren, M.I., Goyanes, S., Physico-mechanical properties of biodegradable starch nanocomposites (2009) Macromol Mater Eng, 294 (3), pp. 169-177
- Lamanna, M., Morales, N.J., García, N.L., Goyanes, S., Development and characterization of starch nanoparticles by gamma radiation: potential application as starch matrix filler (2013) Carbohydr Polym, 97 (1), pp. 90-97. , COI: 1:CAS:528:DC%2BC3sXpsV2isbw%3D
- Zilli, D., Chiliotte, C., Escobar, M.M., Bekeris, V., Rubiolo, G.R., Cukierman, A.L., Goyanes, S., Magnetic properties of multi-walled carbon nanotube–epoxy composites (2005) Polym, 46 (16), pp. 6090-6095. , COI: 1:CAS:528:DC%2BD2MXlvV2lsr4%3D
- Flannery, R.L., Busscher, W.J., Use of a synthetic polymer in potting soils to improve water holding capacity (1982) Commun Soil Sci Plant Anal, 13 (2), pp. 103-111. , COI: 1:CAS:528:DyaL38XhvVSjt7k%3D
Citas:
---------- APA ----------
Garcia, N.L., Fascio, M., Errea, M.I., Dufresne, A., Goyanes, S. & D’Accorso, N.
(2018)
. Absorption of Siderite Within a Chemically Modified Poly(lactic acid) Based Composite Material for Agricultural Applications. Journal of Polymers and the Environment, 26(5), 2173-2181.
http://dx.doi.org/10.1007/s10924-017-1119-x---------- CHICAGO ----------
Garcia, N.L., Fascio, M., Errea, M.I., Dufresne, A., Goyanes, S., D’Accorso, N.
"Absorption of Siderite Within a Chemically Modified Poly(lactic acid) Based Composite Material for Agricultural Applications"
. Journal of Polymers and the Environment 26, no. 5
(2018) : 2173-2181.
http://dx.doi.org/10.1007/s10924-017-1119-x---------- MLA ----------
Garcia, N.L., Fascio, M., Errea, M.I., Dufresne, A., Goyanes, S., D’Accorso, N.
"Absorption of Siderite Within a Chemically Modified Poly(lactic acid) Based Composite Material for Agricultural Applications"
. Journal of Polymers and the Environment, vol. 26, no. 5, 2018, pp. 2173-2181.
http://dx.doi.org/10.1007/s10924-017-1119-x---------- VANCOUVER ----------
Garcia, N.L., Fascio, M., Errea, M.I., Dufresne, A., Goyanes, S., D’Accorso, N. Absorption of Siderite Within a Chemically Modified Poly(lactic acid) Based Composite Material for Agricultural Applications. J. Polym. Environ. 2018;26(5):2173-2181.
http://dx.doi.org/10.1007/s10924-017-1119-x