Navegar

Colección

Datos Estadísticas

Artículo

Messina, L.G.; Bonelli, P.R.; Cukierman, A.L. "Effect of mineral matter removal on pyrolysis of wood sawdust from an invasive species" (2016) Energy Sources, Part A: Recovery, Utilization and Environmental Effects. 38(4):542-548
Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

Kinetics of the pyrolysis of wood sawdust from the invasive species Parkinsonia aculeata, untreated and demineralized by a mild acid treatment, is comparatively investigated in order to examine the effect of the removal of minerals naturally present in the biomass. Non-isothermal thermogravimetric analysis from room temperature up to 500°C is applied for this purpose. Demineralization shifts the process onset and the maximum degradation rate to higher temperatures, and leads to enhance the activation energy from 56 to 60 kJ mol-1, pointing to a catalytic role of alkaline and alkaline earth metals in the biomass. Likewise, the three kinds of pyrolysis products (gas, bio-char, and bio-oil) are obtained from experiments performed in a bench-scale installation at 500°C. Yields and physicochemical characteristics of the pyrolysis products are determined. The pronounced reduction in the content of metals in the sawdust leads to increase bio-oil yield in around 10%, the specific surface area of the bio-char, from ≈ 2 to ≈ 74 m2 g-1, and the higher heating value of all the pyrolysis products. © 2016 Taylor & Francis.

Registro:

Documento: Artículo
Título:Effect of mineral matter removal on pyrolysis of wood sawdust from an invasive species
Autor:Messina, L.G.; Bonelli, P.R.; Cukierman, A.L.
Filiación:Prog. de Invest. y Desarrollo de Fuentes Alternativas de Materias Primas y Ener. - Depto. de Industrias, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón de Industrias, 2620, Ciudad Universitaria, Buenos Aires, C1428BGA, Argentina
Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Buenos Aires, Argentina
Cátedra de Tecnología Farmacéutica II, Departamento de Tecnología Farmacéutica, Facultad de Farmacia y Bioquímica, Universidad de Buenos Aires, Buenos Aires, Argentina
Palabras clave:Bio-energy; bio-fuels; bioresources; invasive wood biomass; pyrolysis; Activation energy; Biofuels; Biomass; Calorific value; Degradation; Thermogravimetric analysis; Wood fuels; Bio energy; Bioresources; Higher heating value; Invasive species; Parkinsonia aculeata; Physicochemical characteristics; Pyrolysis products; Wood biomass; Pyrolysis
Año:2016
Volumen:38
Número:4
Página de inicio:542
Página de fin:548
DOI: http://dx.doi.org/10.1080/15567036.2013.799616
Título revista:Energy Sources, Part A: Recovery, Utilization and Environmental Effects
Título revista abreviado:Energy Sources Recovery Util. Environ. Eff.
ISSN:15567036
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15567036_v38_n4_p542_Messina

Referencias:

  • Basso, M.C., Cukierman, A.L., Wastewater treatment by chemically activated carbons from giant reed: Effect of the activation atmosphere on properties and adsorptive behavior (2006) Sep. Sci. Technol, 41, pp. 149-156
  • Bonelli, P.R., Nunell, G., Fernández, M.E., Buonomo, E.L., Cukierman, A.L., The potential applications of the bio-char derived from the pyrolysis of an agro-industrial waste Effects of temperature and acid-pretreatment (2012) Energy Sources Part A, 34, pp. 746-755
  • Bridgwater, A.V., Review of fast pyrolysis of biomass and product upgrading (2012) Biomass Bioenergy, 38, pp. 68-94
  • Chew, J.J., Doshi, V., Recent advances in biomass pretreatment-Torrefaction fundamentals and technology (2011) Renewable Sustainable Energy Rev, 15, pp. 4212-4222
  • De Lange, W.J., Stafford, W.H.L., Forsyth, G.G., Le Maitre, D.C., Incorporating stakeholder preferences in the selection of technologies for using invasive alien plants as a bio-energy feedstock: Applying the analytical hierarchy process (2012) J. Environ. Manage, 99, pp. 76-83
  • Di Blasi, C., Galgano, A., Branca, C., Influences of the chemical state of alkaline compounds and the nature of alkali metal on wood pyrolysis (2009) Ind. Eng. Chem. Res, 48, pp. 3359-3369
  • Eom, I.-Y., Kim, J.-Y., Kim, T.-S., Lee, S.-M., Choi, D., Choi, I.-G., Choi, J.-W., Effect of essential inorganic metals on primary thermal degradation of lignocellulosic biomass (2012) Bioresour. Technol, 104, pp. 687-694
  • Fahmi, R., Bridgwater, A.V., Donnison, I., Yates, N., Jones, J.M., The effect of lignin and inorganic species in biomass pyrolysis oil yields, quality and stability (2008) Fuel, 87, pp. 1230-1240
  • González, J.D., Kim, M.R., Buonomo, E.L., Bonelli, P.R., Cukierman, A.L., Pyrolysis of biomass from sustainable energy plantations: Effect of mineral matter reduction on kinetics and charcoal pore structure (2008) Energy Sources Part A, 30, pp. 809-817
  • Nunell, G.V., Fernández, M.E., Bonelli, P.R., Cukierman, A.L., Conversion of biomass from an invasive species into activated carbons for removal of nitrate from wastewater (2012) Biomass Bioenergy, 44, pp. 87-95
  • Qu, T., Guo, W., Shen, L., Xiao, J., Zhao, K., Experimental study of biomass pyrolysis based on three major components: Hemicellulose, cellulose and lignin (2011) Ind. Eng. Chem. Res, 50, pp. 10424-10433
  • Raveendran, K., Ganesh, A., Khilar, K.C., Influence of mineral matter on biomass pyrolysis characteristics (1995) Fuel, 74, pp. 1812-1822
  • Saidur, R., Abdelaziz, E.A., Demirbas, A., Hossain, M.S., Mekhilef, S., A review on biomass as a fuel for boilers (2011) Renewable Sustainable Energy Rev, 15, pp. 2262-2289
  • Shi, L., Yu, S., Wang, F.-C., Wang, J., Pyrolytic characteristics of rice straw and its constituents catalyzed by internal alkali and alkali earth metals (2012) Fuel, 96, pp. 586-594

Citas:

---------- APA ----------
Messina, L.G., Bonelli, P.R. & Cukierman, A.L. (2016) . Effect of mineral matter removal on pyrolysis of wood sawdust from an invasive species. Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 38(4), 542-548.
http://dx.doi.org/10.1080/15567036.2013.799616
---------- CHICAGO ----------
Messina, L.G., Bonelli, P.R., Cukierman, A.L. "Effect of mineral matter removal on pyrolysis of wood sawdust from an invasive species" . Energy Sources, Part A: Recovery, Utilization and Environmental Effects 38, no. 4 (2016) : 542-548.
http://dx.doi.org/10.1080/15567036.2013.799616
---------- MLA ----------
Messina, L.G., Bonelli, P.R., Cukierman, A.L. "Effect of mineral matter removal on pyrolysis of wood sawdust from an invasive species" . Energy Sources, Part A: Recovery, Utilization and Environmental Effects, vol. 38, no. 4, 2016, pp. 542-548.
http://dx.doi.org/10.1080/15567036.2013.799616
---------- VANCOUVER ----------
Messina, L.G., Bonelli, P.R., Cukierman, A.L. Effect of mineral matter removal on pyrolysis of wood sawdust from an invasive species. Energy Sources Recovery Util. Environ. Eff. 2016;38(4):542-548.
http://dx.doi.org/10.1080/15567036.2013.799616