Artículo

González, J.D.; Kim, M.R.; Buonomo, E.L.; Bonelli, P.R.; Cukierman, A.L. "Pyrolysis of biomass from sustainable energy plantations: Effect of mineral matter reduction on kinetics and charcoal pore structure" (2008) Energy Sources, Part A: Recovery, Utilization and Environmental Effects. 30(9):809-817
Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

The effect of reducing mineral matter naturally present in sawdust from untreated poplar (Populus deltoide) wood and giant reed (Arundo donax) canes on pyrolysis kinetics was examined from comparative non-isothermal thermogravimetric measurements in the range 20-900C, using raw and previously demineralized samples. Estimated kinetic parameters reflected changes caused by demineralization, especially in the low temperature range (up to 450C), likely due to catalytic effects of the minerals. Pyrolysis of the demineralized biomasses also induced an enhanced development in pore structure of the resulting charcoal, favoring its potential use in adsorption applications and/or as an improved intermediate product for further conversion into activated carbons.

Registro:

Documento: Artículo
Título:Pyrolysis of biomass from sustainable energy plantations: Effect of mineral matter reduction on kinetics and charcoal pore structure
Autor:González, J.D.; Kim, M.R.; Buonomo, E.L.; Bonelli, P.R.; Cukierman, A.L.
Filiación:Programa de Investigacin y Desarrollo de Fuentes Alternativas de Materias Primas y Energía, Departamento de Industrias, Universidad de Buenos Aires, Buenos Aires, Argentina
Farmacotecnia II - Tecnología Especial, Departamento de Tecnología Farmacéutica, Universidad de Buenos Aires, Buenos Aires, Argentina
PINMATE, Depto. de Industrias, Ciudad Universitaria (C1428BGA), Buenos Aires, Argentina
Palabras clave:Biomass pyrolysis; Charcoal; Energy crops; Kinetics; Mineral matter; Adsorption; Charcoal; Pyrolysis; Thermogravimetric analysis; Catalytic effects; Energy crops; Mineral matters; Biomass
Año:2008
Volumen:30
Número:9
Página de inicio:809
Página de fin:817
DOI: http://dx.doi.org/10.1080/15567030600817878
Título revista:Energy Sources, Part A: Recovery, Utilization and Environmental Effects
Título revista abreviado:Energy Sources Recovery Util. Environ. Eff.
ISSN:15567036
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15567036_v30_n9_p809_Gonzalez

Referencias:

  • Basso, M.C., Cerrella, E.G., Buonomo, E.L., Bonelli, P.R., Cukierman, A.L., Thermochemical conversion of Arundo donax into useful solid products (2005) Energy Sources, 27, pp. 1429-1438
  • Basso, M.C., Cerrella, E.G., Cukierman, A.L., Activated carbons developed from a rapidly renewable biosource for removal of cadmium (II) and nickel (II) ions from dilute aqueous solutions (2002) Ind. Eng. Chem. Res, 41, pp. 180-189
  • Basso, M.C., Cukierman, A.L., Arundo donax-based activated carbons for aqueous-phase adsorption of volatile organic compounds (2005) Ind. Eng. Chem. Res, 44, pp. 2091-2100
  • Bonelli, P.R., Della Rocca, P.A., Cerrella, E.G., Cukierman, A.L., Effect of pyrolysis temperature on composition, surface properties and thermal degradation rates of Brazil nut shells (2001) Bioresource Technol, 76, pp. 15-22
  • Bonelli, P.R., Cerrella, E.G., Cukierman, A.L., Slow pyrolysis of nutshells: Characterization of derived chars and of process kinetics (2003) Energy Sources, 25, pp. 767-778
  • Das, P., Ganesh, A., Wangikar, P., Influence of pre-treatment for deashing of sugarcane bagasse on pyrolysis products (2004) Biomass Bioenergy, 27, pp. 445-457
  • Della Rocca, P.A., Cerrella, E.G., Bonelli, P.R., Cukierman, A.L., Pyrolysis of hardwood residues on kinetics and chars characterization (1999) Biomass Bioenergy, 16, pp. 79-88
  • Demirbas, A., Current technologies for the thermo-conversion of biomass into fuels and chemicals (2004) Energy Sources, 26, pp. 821-827
  • Di Blasi, C., Branca, C., D'Errico, G., Degradation characteristics of straw and washed straw (2000) Thermochim. Acta, 364, pp. 133-142
  • Di Blasi, C., Branca, C., Teislev, B., Development of a novel reactor for the oxidative degradation of straw (2004) Bioresour. Technol, 91, pp. 263-271
  • González, F., Ramiro, A., González-García, C.M., Gañán, J., Encinar, J.M., Sabio, E., Rubiales, J., Pyrolysis of almond shells. Energy applications of fractions (2005) Ind. Eng. Chem. Res, 44, pp. 3003-3012
  • Kersten, S.R.A., Wang, X., Prins, W., van Swaaij, W.P.M., Biomass pyrolysis in a fluidized bed reactor. Part 1: Literature review and model simulations (2005) Ind. Eng. Chem. Res, 44, pp. 8773-8785
  • Manyà, J.J., Velo, E., Puigjaner, L., Kinetics of biomass pyrolysis: A reformulated three-parallel-reactions model (2003) Ind. Eng. Chem. Res, 42, pp. 434-441
  • McIlveen-Wright, D.R., Williams, B.C., McMullan, J.T., A re-appraisal of wood-fired combustion (2001) Bioresour. Technol, 76, pp. 183-190
  • Raveendran, K., Ganesh, A., Khilar, K.C., Influence of mineral matter on biomass pyrolysis characteristics (1995) Fuel, 74, pp. 1812-1822
  • Ryu, C., Yang, Y.B., Khor, A., Yates, N.E., Sharifi, V.N., Swithenbank, J., Effect of fuel properties on biomass combustion: Part I. Experiments-fuel type, equivalence ratio and particle size (2006) Fuel, 85, pp. 1039-1046
  • Scott, D.S., Paterson, L., Piskorz, J., Radlein, D., Pretreatment of poplar wood for fast pyrolysis: Rate of cation removal (2000) J. Anal. Appl. Pyrol, 57, pp. 169-176
  • Taralas, G., Kontominas, M.G., Thermochemical treatment of solid and wastewater effluents originating from the olive oil food industry (2005) Energy Fuels, 19, pp. 1179-1185
  • Wei, X., Schnell, U., Hein, K.R.G., Behaviour of gaseous chlorine and alkali metals during biomass thermal utilization (2005) Fuel, 84, pp. 841-848
  • Yang, H., Yang, R., Chin, T., Tee Liang, D., Chen, H., Zheng, C., Thermogravimetric analysis - Fourier transform infrared analysis of palm oil waste pyrolysis (2004) Energy Fuels, 18, pp. 1814-1821
  • Zevenhoven-Onderwater, M., Backman, R., Skrifvars, B., Hupa, M., The ash chemistry in fluidized bed gasification of biomass fuels. Part I: Predicting the chemistry of melting ashes and ash-bed material interaction (2001) Fuel, 80, pp. 1489-1502

Citas:

---------- APA ----------
González, J.D., Kim, M.R., Buonomo, E.L., Bonelli, P.R. & Cukierman, A.L. (2008) . Pyrolysis of biomass from sustainable energy plantations: Effect of mineral matter reduction on kinetics and charcoal pore structure. Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 30(9), 809-817.
http://dx.doi.org/10.1080/15567030600817878
---------- CHICAGO ----------
González, J.D., Kim, M.R., Buonomo, E.L., Bonelli, P.R., Cukierman, A.L. "Pyrolysis of biomass from sustainable energy plantations: Effect of mineral matter reduction on kinetics and charcoal pore structure" . Energy Sources, Part A: Recovery, Utilization and Environmental Effects 30, no. 9 (2008) : 809-817.
http://dx.doi.org/10.1080/15567030600817878
---------- MLA ----------
González, J.D., Kim, M.R., Buonomo, E.L., Bonelli, P.R., Cukierman, A.L. "Pyrolysis of biomass from sustainable energy plantations: Effect of mineral matter reduction on kinetics and charcoal pore structure" . Energy Sources, Part A: Recovery, Utilization and Environmental Effects, vol. 30, no. 9, 2008, pp. 809-817.
http://dx.doi.org/10.1080/15567030600817878
---------- VANCOUVER ----------
González, J.D., Kim, M.R., Buonomo, E.L., Bonelli, P.R., Cukierman, A.L. Pyrolysis of biomass from sustainable energy plantations: Effect of mineral matter reduction on kinetics and charcoal pore structure. Energy Sources Recovery Util. Environ. Eff. 2008;30(9):809-817.
http://dx.doi.org/10.1080/15567030600817878