Artículo

Jimeno, A.; Goyanes, S.; Eceiza, A.; Kortaberria, G.; Mondragon, I.; Corcuera, M.A. "Effects of amine molecular structure on carbon nanotubes functionalization" (2009) Journal of Nanoscience and Nanotechnology. 9(10):6222-6227
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Abstract:

Three amines with different molecular structure, triethylenetetramine (TETA) and two polyetheramines (Jeffamine D-230 and Jeffamine T-403) were employed to functionalize multi-walled carbon nanotubes (MWCNT) previously oxidized by acid treatment. The functionalized MWCNT were characterized by Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, UV-vis spectroscopy and the surface modification was investigated by field emission scanning electron microscopy (FE-SEM). Thermogravimetric analysis (TGA) was employed to quantify the amount of amine groups anchored to MWCNTs. The results have shown that the efficiency of amine functionalization is in the order TETA > D-230 > T-403, thus showing that amine chemical structure and molecular weight are important parameters on functionalization of carbon nanotubes. Copyright © 2009 American Scientific Publishers.

Registro:

Documento: Artículo
Título:Effects of amine molecular structure on carbon nanotubes functionalization
Autor:Jimeno, A.; Goyanes, S.; Eceiza, A.; Kortaberria, G.; Mondragon, I.; Corcuera, M.A.
Filiación:Materials + Technologies Group, Dpto. Ingeniería Química y M. Ambiente, Escuela Politécnica, Universidad País Vasco/Euskal Herriko Unibertsitatea, Pza. Europa 1, 20018 Donostia-San Sebastáin, Spain
LP and MC, Dep. de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pab. 1, Ciudad Universitaria, 1428, Buenos Aires, Argentina
Palabras clave:Amine; Functionalization; Multiwalled carbon nanotubes; Acid treatments; Amine functionalization; Amine groups; Chemical structure; Field emission scanning electron microscopy; Functionalization; Functionalizations; Functionalized-MWCNT; Jeffamines; Surface modification; Triethylenetetramine; UV-vis spectroscopy; Amines; Anodic oxidation; Carbon nanotubes; Emission spectroscopy; Field emission; Field emission microscopes; Fourier transform infrared spectroscopy; Molecular structure; Organic compounds; Raman spectroscopy; Scanning electron microscopy; Spectroscopic analysis; Sulfur compounds; Thermogravimetric analysis; Ultraviolet spectroscopy; Multiwalled carbon nanotubes (MWCN)
Año:2009
Volumen:9
Número:10
Página de inicio:6222
Página de fin:6227
DOI: http://dx.doi.org/10.1166/jnn.2009.1562
Título revista:Journal of Nanoscience and Nanotechnology
Título revista abreviado:J. Nanosci. Nanotechnol.
ISSN:15334880
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15334880_v9_n10_p6222_Jimeno

Referencias:

  • Kim, J.M., Choi, W.B., Lee, N.S., Jung, J.E., (2000) Diamond Rel. Mater., 9, p. 1184
  • Cheng, H.M., Yang, Q.H., Liu, C., (2001) Carbon, 39, p. 1447
  • Asedegbega-Nieto, E., Guerrero-Ruiz, A., Rodríguez-Ramos, I., (2006) Carbon, 44, p. 804
  • Wang, Y., Iqbal, Z., Malhotra, S.V., (2005) Chem. Phys. Lett., 402, p. 96
  • He, P., Gao, Y., Lian, J., Wang, L., Qian, D., Zhao, J., Wang, W., Shi, D., (2006) Composites A, 37, p. 1270
  • Sham, M.L., Kim, J.K., Lee, N.S., (2006) Carbon, 44, p. 768
  • Hill, D.E., Lin, Y., Rao, A.M., Allard, L.F., Sun, Y.P., (2002) Macromolecules, 35, p. 9466
  • Shi, D., Lian, J., He, P., Wang, L.M., Xiao, F., Yang, L., (2003) Appl. Phys. Lett., 83, p. 5301
  • Lin, Y., Zhou, B., Fernando, K.A.S., Liu, P., Allard, L.F., Sun, Y.P., (2003) Macromolecules, 36, p. 7199
  • Gojny, F.H., Nastalczyk, J., Roslaniec, Z., Schulte, K., (2003) Chem. Phys. Lett., 370, p. 820
  • Chen, M., Yu, H.W., Cheng, J.H., Koo, H.S., (2007) Diamond Rel. Mater., 16, p. 1110
  • Zhang, G., Shuhui, S., Dequan, Y., Dodelet, J.P., Sacher, E., (2008) Carbon, 46, p. 196
  • Goyanes, S., Rubiolo, G.H., Salazar, A., Jimeno, A., Corcuera, M.A., Mondragon, I., (2007) Diamond Rel. Mater., 16, p. 412
  • Rasheed, A., Howe, J.Y., Dadmun, M.D., Britt, P.F., (2007) Carbon, 45, p. 1072
  • Yudasaka, M., Zhang, M., Jabs, C., Iijima, S., (2000) Appl. Phys. A, 71, p. 449
  • Pierard, N., Fonseca, A., Konya, Z., Willems, I., Van Tendeloo, G., Nagy, J.B., (2001) Chem. Phys. Lett., 335, p. 1
  • Tao, Z., Geng, H., Yu, K., Yang, Z., Wang, Y., (2004) Mater. Lett., 58, p. 3410
  • Chen, L., Pang, X.J., Zhang, Q.T., Yu, Z.L., (2006) Mater. Lett., 60, p. 241
  • Dieckmann, G.R., Dalton, A.B., Johnson, P.A., Razal, J., Chen, J., Giordano, G.M., Muñoz, E., Draper, R.K., (2003) J. Am. Chem. Soc., 125, p. 1770
  • Ramesh, B.P., Blau, W.J., Tyagi, P.K., Misra, D.S., Ali, N., Gracio, J., Cabral, G., Titus, E., (2006) Thin Solid Films, 494, p. 128
  • Wang, G., Dong, Y., Liu, L., Zhao, C., (2007) J. Appl. Polym. Sci., 105, p. 1385
  • Yang, Z., Chen, X., Chen, C., Li, W., Zhang, H., Xu, L., Yi, B., (2007) Polym. Compos, 28, p. 36
  • Malaspina, T., Filed, E.E., Rivelino, R., (2007) J. Phys. Chem. B., 111, p. 11935
  • Shen, J., Huang, W., Wu, L., Hu, Y., Ye, M., (2007) Mater. Sci. Eng. A, 464, p. 151
  • Liu, M., Yang, Y., Zhu, T., Liu, Z., (2005) Carbon, 43, p. 1470
  • Chen, W., Auad, M.L., Williams, R.J.J., Nutt, S.R., (2006) Eur. Polym. J., 42, p. 2765
  • Gojny, F.H., Schulte, K., (2004) Comp. Sci. Tech., 64, p. 2203
  • Li, J., Grennberg, H., (2006) Chem. Eur. J., 12, p. 3969
  • Saito, R., Jorio, A., Filho, A.G.S., Grueneis, A., Pimenta, M.A., Dresselhaus, G., Dresselhaus, M.S., (2002) Physica B., 323, p. 100
  • Paiva, M.C., Zhou, B., Fernando, K.A.S., Lin, Y., Lopes, P.E., Pennington, W.T., Kennedy, J.M., Sun, Y.P., (2005) Comp. Interf, 12, p. 757
  • Dresselhaus, M.S., Dresselhaus, G., Saito, R., Jorio, A., (2005) Phys. Rep, 409, p. 47
  • Bandow, S., Takizawa, M., Hirahara, K., Yudasaka, M., Iijima, S., (2001) Chem. Phys. Lett., 337, p. 48
  • Osswald, S., Havel, M., Gogotsi, Y., (2007) J. Raman Spectr., 38, p. 728
  • Huang, W., Fernando, S., Allard, L.F., Sun, Y.P., (2003) Nano Lett., 3, p. 565
  • Graupner, R., (2007) J. Raman Spectr., 38, p. 673
  • Vix-guterl, C., Couzi, M., Dentzer, J., Trinquecoste, M., Delhaes, P., (2004) J. Phys. Chem. B., 108, p. 19361
  • Li, X., Wong, S.Y., Tjiu, W.C., Lyons, B.P., Oh, S.A., He, C.B., (2008) Carbon, 46, p. 829

Citas:

---------- APA ----------
Jimeno, A., Goyanes, S., Eceiza, A., Kortaberria, G., Mondragon, I. & Corcuera, M.A. (2009) . Effects of amine molecular structure on carbon nanotubes functionalization. Journal of Nanoscience and Nanotechnology, 9(10), 6222-6227.
http://dx.doi.org/10.1166/jnn.2009.1562
---------- CHICAGO ----------
Jimeno, A., Goyanes, S., Eceiza, A., Kortaberria, G., Mondragon, I., Corcuera, M.A. "Effects of amine molecular structure on carbon nanotubes functionalization" . Journal of Nanoscience and Nanotechnology 9, no. 10 (2009) : 6222-6227.
http://dx.doi.org/10.1166/jnn.2009.1562
---------- MLA ----------
Jimeno, A., Goyanes, S., Eceiza, A., Kortaberria, G., Mondragon, I., Corcuera, M.A. "Effects of amine molecular structure on carbon nanotubes functionalization" . Journal of Nanoscience and Nanotechnology, vol. 9, no. 10, 2009, pp. 6222-6227.
http://dx.doi.org/10.1166/jnn.2009.1562
---------- VANCOUVER ----------
Jimeno, A., Goyanes, S., Eceiza, A., Kortaberria, G., Mondragon, I., Corcuera, M.A. Effects of amine molecular structure on carbon nanotubes functionalization. J. Nanosci. Nanotechnol. 2009;9(10):6222-6227.
http://dx.doi.org/10.1166/jnn.2009.1562