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Abstract:

Monophasic hexagonal precursors, obeying to the formula Ce1-xLnx(OH)CO3, are introduced herein as versatile precursors for the preparation of Ln(III-IV)-substituted nanocrystalline ceria. To this aim, three hexagonal Ce1-xLnx(OH)CO3 families increasingly substituted with Ln(III) = Sm(III), Gd(III), or Pr(III), were prepared with high (quantitative) precipitation yields. Once Ce1-xLnx(OH)CO3 precursors are submitted to moderate thermal treatment (5 h, 723 K, air atmosphere), the oxidation of Ce(III) centers triggers a single step massive decomposition (dehydroxylation/decarbonation), developing monophasic Ce1-xLnxO2-δ solid solutions with Ln(IV-III) substitutions up to 30%. These binary oxides exhibit large surface areas, up to 130 m2 g-1, even larger than those obtained by means of costly procedures. © 2017 American Chemical Society.

Registro:

Documento: Artículo
Título:Hexagonal Ce1-xLnx(OH)CO3 as Highly Efficient Precursors of Nanocrystalline Ln(III-IV)-Substituted Ceria
Autor:Sorbello, C.; Jobbágy, M.
Filiación:INQUIMAE, DQIAQF, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, Ciudad Universitaria, Buenos Aires, C1428EHA, Argentina
Palabras clave:Nanocrystals; Air atmosphere; Binary oxides; Dehydroxylations; Hexagonal precursors; Large surface area; Nanocrystallines; Single-step; Cerium compounds
Año:2017
Volumen:17
Número:11
Página de inicio:5660
Página de fin:5666
DOI: http://dx.doi.org/10.1021/acs.cgd.7b00491
Título revista:Crystal Growth and Design
Título revista abreviado:Cryst. Growth Des.
ISSN:15287483
CODEN:CGDEF
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15287483_v17_n11_p5660_Sorbello

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Citas:

---------- APA ----------
Sorbello, C. & Jobbágy, M. (2017) . Hexagonal Ce1-xLnx(OH)CO3 as Highly Efficient Precursors of Nanocrystalline Ln(III-IV)-Substituted Ceria. Crystal Growth and Design, 17(11), 5660-5666.
http://dx.doi.org/10.1021/acs.cgd.7b00491
---------- CHICAGO ----------
Sorbello, C., Jobbágy, M. "Hexagonal Ce1-xLnx(OH)CO3 as Highly Efficient Precursors of Nanocrystalline Ln(III-IV)-Substituted Ceria" . Crystal Growth and Design 17, no. 11 (2017) : 5660-5666.
http://dx.doi.org/10.1021/acs.cgd.7b00491
---------- MLA ----------
Sorbello, C., Jobbágy, M. "Hexagonal Ce1-xLnx(OH)CO3 as Highly Efficient Precursors of Nanocrystalline Ln(III-IV)-Substituted Ceria" . Crystal Growth and Design, vol. 17, no. 11, 2017, pp. 5660-5666.
http://dx.doi.org/10.1021/acs.cgd.7b00491
---------- VANCOUVER ----------
Sorbello, C., Jobbágy, M. Hexagonal Ce1-xLnx(OH)CO3 as Highly Efficient Precursors of Nanocrystalline Ln(III-IV)-Substituted Ceria. Cryst. Growth Des. 2017;17(11):5660-5666.
http://dx.doi.org/10.1021/acs.cgd.7b00491