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Gutiérrez, M.M.; Alluisetti, G.B.; Olabe, J.A.; Amorebieta, V.T. "Catalytic disproportionation of N-alkylhydroxylamines bound to pentacyanoferrates" (2009) Journal of the Chemical Society. Dalton Transactions(7):1187-1194
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Abstract:

The substituted hydroxylamines, CH3N(H)OH (N-methylhydroxylamine) and (CH3)2NOH (N,N-dimethylhydroxylamine), disproportionate catalytically to the corresponding alkylamines and oxidation products, only in the presence of [Fe(CN)5H2O]3−. Substitution kinetic measurements suggest an initial coordination step to Fe(ii). Two parallel N- and O-coordination modes are considered with the subsequent formation of Fe(iii), free aminyl (RNCH3) and nitroxide (RN(CH3)O) radicals (R = H, CH3). With CH3N(H)OH, bound nitrosomethane, CH3NO, has been characterized by UV-visible and IR spectroscopies. The mechanism is discussed on the basis of common and differential features with respect to the disproportionation of hydroxylamine catalyzed by the same Fe-fragment. © 2008 The Royal Society of Chemistry.

Registro:

Documento: Artículo
Título:Catalytic disproportionation of N-alkylhydroxylamines bound to pentacyanoferrates
Autor:Gutiérrez, M.M.; Alluisetti, G.B.; Olabe, J.A.; Amorebieta, V.T.
Filiación:Department of Chemistry, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Mar del Plata, Funes y Roca, Mar del Plata, B7602AYL, Argentina
Department of Inorganic, Analytical and Physical Chemistry and INQUIMAE, CONICET, Facultad de Ciencias Exactas y Naturales and Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, C1428EHA, Argentina
Año:2009
Número:7
Página de inicio:1187
Página de fin:1194
DOI: http://dx.doi.org/10.1039/b812173g
Título revista:Journal of the Chemical Society. Dalton Transactions
Título revista abreviado:J Chem Soc Dalton Trans
ISSN:14779226
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v_n7_p1187_Gutierrez

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Citas:

---------- APA ----------
Gutiérrez, M.M., Alluisetti, G.B., Olabe, J.A. & Amorebieta, V.T. (2009) . Catalytic disproportionation of N-alkylhydroxylamines bound to pentacyanoferrates. Journal of the Chemical Society. Dalton Transactions(7), 1187-1194.
http://dx.doi.org/10.1039/b812173g
---------- CHICAGO ----------
Gutiérrez, M.M., Alluisetti, G.B., Olabe, J.A., Amorebieta, V.T. "Catalytic disproportionation of N-alkylhydroxylamines bound to pentacyanoferrates" . Journal of the Chemical Society. Dalton Transactions, no. 7 (2009) : 1187-1194.
http://dx.doi.org/10.1039/b812173g
---------- MLA ----------
Gutiérrez, M.M., Alluisetti, G.B., Olabe, J.A., Amorebieta, V.T. "Catalytic disproportionation of N-alkylhydroxylamines bound to pentacyanoferrates" . Journal of the Chemical Society. Dalton Transactions, no. 7, 2009, pp. 1187-1194.
http://dx.doi.org/10.1039/b812173g
---------- VANCOUVER ----------
Gutiérrez, M.M., Alluisetti, G.B., Olabe, J.A., Amorebieta, V.T. Catalytic disproportionation of N-alkylhydroxylamines bound to pentacyanoferrates. J Chem Soc Dalton Trans. 2009(7):1187-1194.
http://dx.doi.org/10.1039/b812173g