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Abstract:

Zr-Si mixed mesoporous oxides were obtained in a wide range of proportions, from 0 to 30% and from 70 to 100% of Si, using Si(OEt)4 and ZrCl4 as precursors and Pluronic F127 as a template. The oxide mesostructure was characterized by transmission electron microscopy and 2D-small angle X-ray scattering. Fourier transform infrared spectroscopy measurements suggested a local homogeneous interdispersion of both cations. Further selective studies using X-ray Absorption Near Edge Structure (XANES) spectroscopy for separately Zr and Si local environments, allowed for demonstrating that the Zr coordination varies from close to 7 to 6, when its concentration in the mixed oxide is reduced. In addition, it was possible to determine that in mixed oxides with low Zr concentrations, Zr can fit into the spaces occupied by Si in SiO2 pure oxide. An equivalent XANES result was obtained for Si, which is also compatible with the information obtained by FTIR. Furthermore, the Zr-O distance varied from close to 2.2 Å to 1.7 Å when the Zr concentration decreased. Finally, our study also demonstrates the usefulness of XANES to selectively assess the local structure (coordination, symmetry and chemical state) of specific atoms in nanostructured systems. © 2016 The Royal Society of Chemistry.

Registro:

Documento: Artículo
Título:Understanding the Zr and Si interdispersion in Zr1-xSixO2 mesoporous thin films by using FTIR and XANES spectroscopy
Autor:Andrini, L.; Angelomé, P.C.; Soler-Illia, G.J.A.A.; Requejo, F.G.
Filiación:Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas, INIFTA, CONICET, La Plata, 1900, Argentina
Gerencia Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Av. General Paz 1499, San Martín, Buenos Aires, B1650KNA, Argentina
Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina
Instituto de Nanosistemas, Universidad Nacional de General San Martín, Av. 25 de Mayo y Francia, San Martín Buenos Aires, 1650, Argentina
Departamento de Física, Facultad de Ciencias Exactas, Universidad Nacional de la Plata, La Plata, Argentina
Palabras clave:Fourier transform infrared spectroscopy; High resolution transmission electron microscopy; Silicon; Transmission electron microscopy; X ray absorption; X ray absorption near edge structure spectroscopy; X ray scattering; Chemical state; Local environments; Local structure; Mesoporous oxides; Mesoporous thin films; Mesostructures; Nanostructured systems; Pluronic F-127; Crystal atomic structure
Año:2016
Volumen:45
Número:24
Página de inicio:9977
Página de fin:9987
DOI: http://dx.doi.org/10.1039/c6dt00203j
Título revista:Dalton Transactions
Título revista abreviado:Dalton Trans.
ISSN:14779226
CODEN:DTARA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v45_n24_p9977_Andrini

Referencias:

  • Soler-Illia, G.J.A.A., Sanchez, C., Lebeau, B., Patarin, J., (2002) Chem. Rev., 102, p. 4093
  • Chem. Soc. Rev., 42, p. 3649. , edited by B. Lebeau, A. Galarneau and M. Linden
  • Kresge, C.T., Leonowicz, M.E., Roth, W.J., Vartuli, J.C., Beck, J.S., (1992) Nature, 359, p. 710
  • Brinker, C.J., Lu, Y., Sellinger, A., Fan, H., (1999) Adv. Mater., 11, p. 579
  • Grosso, D., Cagnol, F., Soler-Illia, G.J.A.A., Crepaldi, E.L., Amenitsch, H., Brunet-Bruneau, A., Bourgeois, A., Sanchez, C., (2004) Adv. Funct. Mater., 14, p. 309
  • Sánchez, C., Boissière, C., Grosso, D., Laberty, C., Nicole, L., (2008) Chem. Mater., 20, p. 682
  • Sawa, A., Nakanishi, K., Hanada, T., (2008) Thin Solid Films, 516, p. 4665
  • Del Monte, F., Larsen, W., Mackenzie, J.D., (2000) J. Am. Ceram. Soc., 83, p. 628
  • Miller, J.B., Ko, E.I., (1996) J. Catal., 159, p. 58
  • Wang, Z., Jiang, Y., Hunger, M., Baiker, A., Huang, J., (2014) ChemCatChem, 6, p. 2970
  • Yano, Y., Noguchi, T., (2008); Yano, Y., Noguchi, T., (2008); Gonella, F., Mattei, G., Mazzoldi, P., Battaglin, G., (1999) Chem. Mater., 11, p. 814
  • Shalliker, R.A., Kayillo, S., (2009) Encyclopedia of Chromatography, p. 2444. , Taylor & Francis, 3rd edn
  • Soler-Illia, G.J.A.A., Crepaldi, E.L., Grosso, D., Sanchez, C., (2004) J. Mater. Chem., 14, p. 1879
  • Lomoschitz, M., Peterlik, H., Friedbacher, G., Schubert, U., (2009) J. Mater. Chem., 19, p. 75
  • Wu, Z.-G., Zhao, Y.-X., Liu, D.-S., (2004) Microporous Mesoporous Mater., 68, p. 127
  • Bore, M.T., Marzke, R.F., Ward, T.L., Datye, A.K., (2005) J. Mater. Chem., 15, p. 5022
  • Ortiz De Zárate, D., Gómez-Moratalla, A., Guillem, C., Beltrán, A., Latorre, J., Beltrán, D., Amorós, P., (2006) Eur. J. Inorg. Chem., 2006, p. 2572
  • Kriesel, J.W., Sander, M.S., Tilley, T.D., (2001) Adv. Mater., 13, p. 331
  • Yang, P., Zhao, D., Margolese, D.I., Chmelka, B.F., Stucky, G.D., (1998) Nature, 396, p. 152
  • Yang, P., Zhao, D., Margolese, D.I., Chmelka, B.F., Stucky, G.D., (1999) Chem. Mater., 11, p. 2813
  • Gontier, S., Tuel, A., (1996) Appl. Catal., A, 143, p. 125
  • Wang, X.X., Lefebvre, F., Patarin, J., Basset, J.-M., (2001) Microporous Mesoporous Mater., 42, p. 269
  • Wong, M.S., Huang, H.C., Ying, J.Y., (2002) Chem. Mater., 14, p. 1961
  • Mountjoy, G., Pickup, D.M., Anderson, R., Wallidge, G.W., Holland, M.A., Newport, R.J., Smith, M.E., (2000) Phys. Chem. Chem. Phys., 2, p. 2455
  • Okabayashi, J., Toyoda, S., Kumigashira, H., Oshima, M., Usuda, K., Niwa, M., Liu, G.L., (2005) J. Vac. Sci. Technol., A, 23, p. 1554
  • Evans, A.M., Williamson, J.P.H., Glasser, F.P., (1980) J. Mater. Sci., 15, p. 2325
  • Kingery, W.D., (1960) Introduction to Ceramics, , John Wiley & Sons, New York
  • Fabris, S., Paxton, A.T., Finnis, M.W., (2000) Phys. Rev. B: Condens. Matter, 61, p. 6617
  • Galoisy, L., Pélegrin, E., Arrio, M.A., Ildefonse, P., Calas, G., Ghaleb, D., Fillet, C., Pacaud, F., (1999) J. Am. Ceram. Soc., 82, p. 2219
  • Cormier, L., Dargaud, O., Calas, G., Jousseaume, C., Papin, S., Trcera, N., Cognignia, A., (2015) Mater. Chem. Phys., 152, p. 41
  • Ceresoli, D., Vanderbilt, D., (2006) Phys. Rev. B: Condens. Matter, 74, p. 125108
  • Luo, X., Zhou, W., Ushakov, S.V., Navrotsky, A., Demkov, A.A., (2009) Phys. Rev. B: Condens. Matter, 80, p. 134119
  • López, E.F., Escribano, V.S., Panizza, M., Carnasciali, M.M., Busca, G., (2001) J. Mater. Chem., 11, p. 1891
  • Blanchard, P.E.R., Liu, S., Kennedy, B.J., Ling, C.D., Zhang, Z., Avdeev, M., Cowie, B.C.C., Jangd, L.-Y., (2013) Dalton Trans., 42, p. 14875
  • Koningsberger, D.C., Prins, R., (1987) X-Ray Absorption: Principles, Applications, Techniques of EXAFS, SEXAFS and XANES, , ed., John Wiley & Sons
  • Rehr, J.J., Ankudinov, A.L., (2005) Coord. Chem. Rev., 249, p. 131
  • De Groot, F., Kotani, A., (2008) Core Level Spectroscopy of Solids, , CRC Press
  • Crepaldi, E.L., Soler-Illia, G.J.A.A., Grosso, D., Albouy, P.-A., Sanchez, C., (2001) Chem. Commun., p. 1582
  • Crepaldi, E.L., Soler-Illia, G.J.A.A., Grosso, D., Ribot, F., Cagnol, F., Sanchez, C., (2003) J. Am. Chem. Soc., 125, p. 9770
  • Angelomé, P.C., Andrini, L., Fuertes, M.C., Requejo, F.G., Soler-Illia, G.J.A.A., (2010) C. R. Chim., 13, p. 256
  • http://www.lnls.br; Abbate, M., Vicentin, F.C., Compagnon-Cailhol, V., Rocha, M.C., Tolentino, H., (1999) J. Synchrotron Radiat., 6, p. 964
  • http://www.lnls.br; Outka, D.A., Stöhr, J., (1988) J. Chem. Phys., 88, p. 3539
  • Ressler, T., (1998) J. Synchrotron Radiat., 5, p. 118
  • http://www.winxas.de; Innocenzi, P., (2003) J. Non-Cryst. Solids, 316, p. 309
  • Andrianainarivelo, M., Corriu, R., Leclercq, D., Mutin, P.H., Vioux, A., (1996) J. Mater. Chem., 6, p. 1665
  • Zhan, Z., Zeng, H.C., (1999) J. Non-Cryst. Solids, 243, p. 26
  • Miller, J.M., Lakshmi, L.J., (1998) J. Phys. Chem. B, 102, p. 6465
  • Teo, S.H., Zeng, H.C., (2001) J. Phys. Chem. B, 105, p. 9093
  • Kelly, S.D., Hesterberg, D., Ravel, B., Analysis of soils and minerals using X-ray Absorption Spectroscopy (2008) Methods of Soil Analysis, 5, pp. 387-463. , ed. A. L. Ulery and L. R. Dress, SSSA Book Series
  • Ikeno, H., Krause, M., Höche, T., Patzig, C., Hu, Y., Gawronski, A., Tanaka, I., Rüssel, C., (2013) J. Phys.: Condens. Matter, 25, p. 165505
  • Li, P., Chen, I.-W., Penner-Hahn, J.E., (1993) Phys. Rev. B: Condens. Matter, 48, p. 10063
  • Li, P., Chen, I.-W., Penner-Hahn, J.E., (1993) Phys. Rev. B: Condens. Matter, 48, p. 10074
  • Li, P., Chen, I.-W., Penner-Hahn, J.E., (1993) Phys. Rev. B: Condens. Matter, 48, p. 10082
  • Figgs, B.N., Hitchman, M.A., (2000) Ligand Field Theory and Its Applications, , Wiley-VCH, N.Y
  • Crocombette, J.P., Jollet, F., (1994) J. Phys.: Condens. Matter, 6, p. 8341
  • De Groot, F.M.F., Hu, Z.W., Lopez, M.F., Kaindl, G., Guillot, F., Tronc, M., (1994) J. Chem. Phys., 101, p. 6570
  • De Groot, F.M.F., (1995) Physica B, 208-209, p. 15
  • Patzig, C., Höche, T., Hu, Y., Ikeno, H., Krause, M., Dittmer, M., Gawronski, A., Henderson, G.S., (2014) J. Non-Cryst. Solids, 384, p. 47
  • Morinaga, M., Adachi, H., Tsukada, M., (1983) J. Phys. Chem. Solids, 44, p. 301
  • French, R.H., Glass, S.J., Ohuchi, F.S., (1994) Phys. Rev. B: Condens. Matter, 49, p. 5133
  • Ballhausen, J.C., (1962) Introduction to Ligand Field Theory, , McGraw-Hill, New York
  • Figgis, B.N., (1986) Introduction to Ligand Field, , Malabar, Florida
  • Alberts Cotton, F., (1990) Chemical Applications of Group Theory, , Wiley-Interscience, New York, 3rd edn
  • Burns, R., (1995) Mineralogical Applications of Crystal Field Theory, , Cambridge University Press, New York
  • Et Al., , For example, Ikeno 52 demonstrated that four compounds of tetravalent Zr the coordination numbers and symmetries around the Zr ions are different
  • Pelegrin, E., (2000) Centre d'Études de la Vallée du Rhône Site de Marcoul, RAPPORT CEA-R-5929, , Doctoral Thesis, Commissariat à l'EnergieAtomique, France
  • Rehr, J.J., De Mustre, L.J., Zabinsky, S.I., Albers, R.C., (1999) J. Am. Chem. Soc., 113, p. 5135
  • Mozzi, R.L., Warren, B.E., (1969) J. Appl. Crystallogr., 2, p. 164
  • Dargaud, O., Cormier, L., Menguy, N., Galoisy, L., Calas, G., Papin, S., Querel, G., Olivi, L., (2010) J. Non-Cryst. Solids, 356, p. 2928
  • Mountjoy, G., Anderson, R., Newport, R.J., Smith, M.E., (2000) J. Phys.: Condens. Matter, 12, p. 3505
  • Pickup, D.M., Mountjoy, G., Wallidge, G.W., Newport, R.J., Smith, M.E., (1999) Phys. Chem. Chem. Phys., 1, p. 2527
  • Gaultois, M.W., Greedan, J.E., Grosvenor, A.P., (2010) J. Electron Spectrosc. Relat. Phenom., 184, p. 192
  • Blanchard, P.E.R., Liu, S., Kennedy, B.J., Ling, C.D., Zhang, Z., Avdeev, M., Cowie, B.C.C., Jangd, L.-Y., (2013) Dalton Trans., 42, p. 14875
  • Cormier, L., Dargaud, O., Calas, G., Jousseaume, C., Papin, S., Trcera, N., Cognigni, A., (2015) Mater. Chem. Phys., 152, p. 41
  • Thole, B.T., Van Der Laan, G., (1988) Phys. Rev. B: Condens. Matter, 38, p. 1943
  • Thole, B.T., Van Der Laan, G., (1988) Phys. Rev. B: Condens. Matter, 38, p. 3158
  • Li, D., Bancroft, G.M., Fleet, M.E., Feng, X.H., (1995) Phys. Chem. Miner., 22, p. 15

Citas:

---------- APA ----------
Andrini, L., Angelomé, P.C., Soler-Illia, G.J.A.A. & Requejo, F.G. (2016) . Understanding the Zr and Si interdispersion in Zr1-xSixO2 mesoporous thin films by using FTIR and XANES spectroscopy. Dalton Transactions, 45(24), 9977-9987.
http://dx.doi.org/10.1039/c6dt00203j
---------- CHICAGO ----------
Andrini, L., Angelomé, P.C., Soler-Illia, G.J.A.A., Requejo, F.G. "Understanding the Zr and Si interdispersion in Zr1-xSixO2 mesoporous thin films by using FTIR and XANES spectroscopy" . Dalton Transactions 45, no. 24 (2016) : 9977-9987.
http://dx.doi.org/10.1039/c6dt00203j
---------- MLA ----------
Andrini, L., Angelomé, P.C., Soler-Illia, G.J.A.A., Requejo, F.G. "Understanding the Zr and Si interdispersion in Zr1-xSixO2 mesoporous thin films by using FTIR and XANES spectroscopy" . Dalton Transactions, vol. 45, no. 24, 2016, pp. 9977-9987.
http://dx.doi.org/10.1039/c6dt00203j
---------- VANCOUVER ----------
Andrini, L., Angelomé, P.C., Soler-Illia, G.J.A.A., Requejo, F.G. Understanding the Zr and Si interdispersion in Zr1-xSixO2 mesoporous thin films by using FTIR and XANES spectroscopy. Dalton Trans. 2016;45(24):9977-9987.
http://dx.doi.org/10.1039/c6dt00203j