Navegar

Colección

Datos Estadísticas

Artículo

Estamos trabajando para incorporar este artículo al repositorio
Consulte el artículo en la página del editor
Consulte la política de Acceso Abierto del editor

Abstract:

The newly obtained complexes [NiII8LnIII6(Piv)16(teaH)6(OCH3)2(CO3)2(H2O)2] Ln = Gd, Dy, show a remarkable μ5-carbonate bridged octanuclear planar {Ni4Ln4} core further capped with embedded {Ni3Ln} cubane motifs to afford a rod shaped nano-sized molecule of about 1.2 × 2.8 nm. Unusual MCE behaviour has been found due to multiple low lying excited states arising from competing ferromagnetic and anti-ferromagnetic Ni-Ni and Ni-Ln exchange interactions. © 2016 The Royal Society of Chemistry.

Registro:

Documento: Artículo
Título:{Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour
Autor:Guarda, E.; Bader, K.; Van Slageren, J.; Alborés, P.
Filiación:Departamento de Química Inorgánica, Analítica y Química Física/INQUIMAE (CONICET), Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, C1428EHA, Argentina
Institut für Physikalische Chemie, Universität Stuttgart, Pfaffenwaldring 55, Stuttgart, D-70569, Germany
Palabras clave:Ferromagnetic materials; Ferromagnetism; Coordination clusters; Ferromagnetic and anti-ferromagnetic; Heteronuclear; Low-lying excited state; Nano sized; Rod-shaped; Nickel
Año:2016
Volumen:45
Número:20
Página de inicio:8566
Página de fin:8572
DOI: http://dx.doi.org/10.1039/c6dt00859c
Título revista:Dalton Transactions
Título revista abreviado:Dalton Trans.
ISSN:14779226
CODEN:DTARA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v45_n20_p8566_Guarda

Referencias:

  • Hooper, T.N., Inglis, R., Palacios, M.A., Nichol, G.S., Pitak, M.B., Coles, S.J., Lorusso, G., Brechin, E.K., (2014) Chem. Commun., 50, p. 3498
  • Kong, X.J., Ren, Y.P., Long, L.S., Zheng, Z., Huang, R.B., Zheng, L.S., (2007) J. Am. Chem. Soc., 129, p. 7016
  • Kong, X.J., Ren, Y.P., Chen, W.X., Long, L.S., Zheng, Z., Huang, R.B., Zheng, L.S., (2008) Angew. Chem., Int. Ed., 47, p. 2398
  • Dermitzaki, D., Lorusso, G., Raptopoulou, C.P., Psycharis, V., Escuer, A., Evangelisti, M., Perlepes, S.P., Stamatatos, T.C., (2013) Inorg. Chem., 52, p. 10235
  • Du, S., Bi, Y., Yi, Y., Liao, W., (2012) Sci. Sin.: Chim., 42, p. 1356
  • Xiong, K., Wang, X., Jiang, F., Gai, Y., Xu, W., Su, K., Li, X., Hong, M., (2012) Chem. Commun., 48, p. 7456
  • Liu, K., Shi, W., Cheng, P., (2015) Coord. Chem. Rev., 289-290, p. 74
  • Liu, J.-L., Chen, Y.-C., Guo, F.-S., Tong, M.-L., (2014) Coord. Chem. Rev., 281, p. 26
  • Ako, A.M., Waldmann, O., Mereacre, V., Klower, F., Hewitt, I.J., Anson, C.E., Gudel, H.U., Powell, A.K., (2007) Inorg. Chem., 46, p. 756
  • Peng, J.B., Zhang, Q.C., Kong, X.J., Zheng, Y.Z., Ren, Y.P., Long, L.S., Huang, R.B., Zheng, Z., (2012) J. Am. Chem. Soc., 134, p. 3314
  • Sakamoto, S., Fujinami, T., Nishi, K., Matsumoto, N., Mochida, N., Ishida, T., Sunatsuki, Y., Re, N., (2013) Inorg. Chem., 52, p. 7218
  • Sakamoto, S., Yamauchi, S., Hagiwara, H., Matsumoto, N., Sunatsuki, Y., Re, N., (2012) Inorg. Chem. Commun., 26, p. 20
  • Akerboom, S., Hazenberg, E.T., Schrader, I., Verbeek, S.F., Mutikainen, I., Fu, W.T., Bouwman, E., (2014) Eur. J. Inorg. Chem., 2014, p. 4896
  • Velasco, V., Aguilà, D., Barrios, L.A., Borilovic, I., Roubeau, O., Ribas-Ariño, J., Fumanal, M., Aromí, G., (2015) Chem. Sci., 6, p. 123
  • Alvarez, S., Alemany, P., Casanova, D., Cirera, J., Llunell, M., Avnir, D., (2005) Coord. Chem. Rev., 249, p. 1693
  • Abraham, A., Bleaney, B., (1970) Electron Paramagnetic Resonance of Transition Ions, , Oxford University Press
  • Chilton, N.F., Anderson, R.P., Turner, L.D., Soncini, A., Murray, K.S., (2013) J. Comput. Chem., 34, p. 1164
  • Pait, M., Bauzá, A., Frontera, A., Colacio, E., Ray, D., (2015) Inorg. Chem., 54, p. 4709
  • Fondo, M., Ocampo, N., García-Deibe, A.M., Vicente, R., Corbella, M., Bermejo, M.R., Sanmartín, J., (2006) Inorg. Chem., 45, p. 255
  • Wikstrom, J.P., Filatov, A.S., Mikhalyova, E.A., Shatruk, M., Foxman, B.M., Rybak-Akimova, E.V., (2010) Dalton Trans., 39, p. 2504
  • Rosado Piquer, L., Sañudo, E.C., (2015) Dalton Trans., 44, p. 8771
  • Chaboussant, G., Basler, R., Gudel, H.U., Ochsenbein, S., Parkin, A., Parsons, S., Rajaraman, G., Winpenny, R.E.P., (2004) Dalton Trans., pp. 2758-2766
  • (2006) SCALE3 ABSPACK: Empirical Absorption Correction, CrysAlis-Software Package, , Oxford Diffraction Ltd., Oxford
  • Altomare, A., Burla, M.C., Camalli, M., Cascarano, G.L., Giacovazzo, C., Guagliardi, A., Moliterni, A.G.G., Spagna, R., (1999) J. Appl. Crystallogr., 32, p. 115
  • Sheldrick, G.M., (2015) Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 71, p. 3
  • Farrugia, L.J., (2012) J. Appl. Crystallogr., 45, p. 849
  • Spek, A.L., (2015) Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 71, p. 9

Citas:

---------- APA ----------
Guarda, E., Bader, K., Van Slageren, J. & Alborés, P. (2016) . {Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour. Dalton Transactions, 45(20), 8566-8572.
http://dx.doi.org/10.1039/c6dt00859c
---------- CHICAGO ----------
Guarda, E., Bader, K., Van Slageren, J., Alborés, P. "{Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour" . Dalton Transactions 45, no. 20 (2016) : 8566-8572.
http://dx.doi.org/10.1039/c6dt00859c
---------- MLA ----------
Guarda, E., Bader, K., Van Slageren, J., Alborés, P. "{Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour" . Dalton Transactions, vol. 45, no. 20, 2016, pp. 8566-8572.
http://dx.doi.org/10.1039/c6dt00859c
---------- VANCOUVER ----------
Guarda, E., Bader, K., Van Slageren, J., Alborés, P. {Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour. Dalton Trans. 2016;45(20):8566-8572.
http://dx.doi.org/10.1039/c6dt00859c