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Cadranel, A.; Pieslinger, G.E.; Tongying, P.; Kuno, M.K.; Baraldo, L.M.; Hodak, J.H. "Spectroscopic signatures of ligand field states in {RuII(imine)} complexes" (2016) Dalton Transactions. 45(13):5464-5475
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Abstract:

Ligand field (LF) states have been present in discussions on the photophysics and photochemistry of ruthenium-iminic chromophores for decades, although there is very little documented direct evidence of them. We studied the picosecond transient absorption (TA) spectroscopy of four {RuII(imine)} complexes that respond to the formula trans-[Ru(L)4(X)2], where L is either pyridine (py) or 4-methoxypyridine (MeOpy) and X is either cyanide or thiocyanate. Dicyano compounds behave as most ruthenium polypyridines and their LF states remain silent. In contrast, in the dithiocyanate complexes we found clear spectroscopic evidence of the participation of LF states in the MLCT decay pathway. These states are of donor and acceptor character simultaneously and this is manifested in the presence of MLCT and LMCT transient absorption bands of similar energy. Spectroelectrochemical techniques supported the interpretation of the absorption features of MLCT states, and DFT methods helped to assign their spectroscopic signatures and provided strong evidence on the nature of LF states. © 2016 The Royal Society of Chemistry.

Registro:

Documento: Artículo
Título:Spectroscopic signatures of ligand field states in {RuII(imine)} complexes
Autor:Cadranel, A.; Pieslinger, G.E.; Tongying, P.; Kuno, M.K.; Baraldo, L.M.; Hodak, J.H.
Filiación:Departamento de Química Analítica, Inorgánica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, C1428EHA, Argentina
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46656, United States
Palabras clave:Chromophores; Ligands; Nitrogen compounds; Ruthenium; Spectroelectrochemistry; Absorption features; Donor and acceptor; Ligand field; Polypyridines; Spectroelectrochemical technique; Spectroscopic evidence; Spectroscopic signatures; Transient absorption; Absorption spectroscopy
Año:2016
Volumen:45
Número:13
Página de inicio:5464
Página de fin:5475
DOI: http://dx.doi.org/10.1039/c5dt04332h
Título revista:Dalton Transactions
Título revista abreviado:Dalton Trans.
ISSN:14779226
CODEN:DTARA
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v45_n13_p5464_Cadranel

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Citas:

---------- APA ----------
Cadranel, A., Pieslinger, G.E., Tongying, P., Kuno, M.K., Baraldo, L.M. & Hodak, J.H. (2016) . Spectroscopic signatures of ligand field states in {RuII(imine)} complexes. Dalton Transactions, 45(13), 5464-5475.
http://dx.doi.org/10.1039/c5dt04332h
---------- CHICAGO ----------
Cadranel, A., Pieslinger, G.E., Tongying, P., Kuno, M.K., Baraldo, L.M., Hodak, J.H. "Spectroscopic signatures of ligand field states in {RuII(imine)} complexes" . Dalton Transactions 45, no. 13 (2016) : 5464-5475.
http://dx.doi.org/10.1039/c5dt04332h
---------- MLA ----------
Cadranel, A., Pieslinger, G.E., Tongying, P., Kuno, M.K., Baraldo, L.M., Hodak, J.H. "Spectroscopic signatures of ligand field states in {RuII(imine)} complexes" . Dalton Transactions, vol. 45, no. 13, 2016, pp. 5464-5475.
http://dx.doi.org/10.1039/c5dt04332h
---------- VANCOUVER ----------
Cadranel, A., Pieslinger, G.E., Tongying, P., Kuno, M.K., Baraldo, L.M., Hodak, J.H. Spectroscopic signatures of ligand field states in {RuII(imine)} complexes. Dalton Trans. 2016;45(13):5464-5475.
http://dx.doi.org/10.1039/c5dt04332h