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Abstract:

We are reporting the first supramolecular dimeric units of basic carboxylates. The neutral [FeIII 2MIIO] motif for different 3d M metals is covalently bound through 2,2′-bipyrimidine. We have structurally characterized the hexanuclear clusters and the related trinuclear building blocks. Their magnetic properties have been fully analyzed and DFT calculations have been performed as a supplementary tool. All results evidence a weak antiferromagnetic interaction through the bpym bridge between isolated spin ground states (in some examples) arising from intra-Fe 2MO core exchange couplings. © The Royal Society of Chemistry 2010.

Registro:

Documento: Artículo
Título:Rational design of covalently bridged [FeIII 2M IIO] clusters
Autor:Alborés, P.; Rentschler, E.
Filiación:Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg - University of Mainz, Duesbergweg 10-14, D-55128 Mainz, Germany
Departamento de Química Inorgánica Analítica y Química Física, INQUIMAE (CONICET), Universidad de Buenos Aires, Pabellón 2, C1428EHA Buenos Aires, Argentina
Palabras clave:Antiferro-magnetic interactions; Building blockes; Covalently bound; DFT calculation; Dimeric units; Hexanuclear clusters; Rational design; Spin ground state; Antiferromagnetism; Carboxylation; Magnetic properties; Sulfur compounds
Año:2010
Volumen:39
Número:20
Página de inicio:5005
Página de fin:5019
DOI: http://dx.doi.org/10.1039/b925214b
Título revista:Dalton Transactions
Título revista abreviado:Dalton Trans.
ISSN:14779226
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v39_n20_p5005_Albores

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Citas:

---------- APA ----------
Alborés, P. & Rentschler, E. (2010) . Rational design of covalently bridged [FeIII 2M IIO] clusters. Dalton Transactions, 39(20), 5005-5019.
http://dx.doi.org/10.1039/b925214b
---------- CHICAGO ----------
Alborés, P., Rentschler, E. "Rational design of covalently bridged [FeIII 2M IIO] clusters" . Dalton Transactions 39, no. 20 (2010) : 5005-5019.
http://dx.doi.org/10.1039/b925214b
---------- MLA ----------
Alborés, P., Rentschler, E. "Rational design of covalently bridged [FeIII 2M IIO] clusters" . Dalton Transactions, vol. 39, no. 20, 2010, pp. 5005-5019.
http://dx.doi.org/10.1039/b925214b
---------- VANCOUVER ----------
Alborés, P., Rentschler, E. Rational design of covalently bridged [FeIII 2M IIO] clusters. Dalton Trans. 2010;39(20):5005-5019.
http://dx.doi.org/10.1039/b925214b