Artículo

Lopez, S.G.; Crovetto, L.; Alvarez-Pez, J.M.; Talavera, E.M.; San Román, E. "Fluorescence enhancement of a fluorescein derivative upon adsorption on cellulose" (2014) Photochemical and Photobiological Sciences. 13(9):1311-1320
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Abstract:

9-[1-(2-Methyl-4-methoxyphenyl)]-6-hydroxy-3H-xanthen-3-one (2-Me-4-OMe TG) is a fluorescein derivative dye whose photophysical properties show a remarkable pH dependence. In aqueous solution the fluorescence quantum yield (Φf) of its anionic species is nearly a hundred times higher than that of its neutral species. Such a large difference in Φf makes 2-Me-4-OMe TG useful as an "on-off" pH indicator. Here we report that adsorption on the surface of microcrystalline cellulose exerts a profound effect upon the photophysical properties of 2-Me-4-OMe TG. On the solid only the dye neutral species is observed and its Φf is 0.31 ± 0.10, which is approximately thirty times higher than the value found for the neutral species in aqueous solution (Φf = 0.01). 2-Me-4-OMe TG and Dabcyl (DB) were co-adsorbed on the surface of microcrystalline cellulose to study the transfer of excitation energy from the former to the latter. In the absence of the dye, the formation of DB aggregates is observed at concentrations greater than 0.34 μmol per gram of cellulose, while in the presence of 2-Me-4-OMe TG the formation of DB aggregates is thoroughly inhibited. The quenching of fluorescence of 2-Me-4-OMe TG by DB reaches efficiencies as high as 90% for the most concentrated samples. © the Partner Organisations 2014.

Registro:

Documento: Artículo
Título:Fluorescence enhancement of a fluorescein derivative upon adsorption on cellulose
Autor:Lopez, S.G.; Crovetto, L.; Alvarez-Pez, J.M.; Talavera, E.M.; San Román, E.
Filiación:Departamento de Fisicoquímica, Universidad de Granada, Campus de Cartuja, E-18071-Granada, Spain
INQUIMAE, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina
Palabras clave:6-hydroxy-3-xanthen-3-one; cellulose; fluorescein; microcrystalline cellulose; water; xanthene derivative; adsorption; chemistry; hydrogen bond; pH; quantum theory; spectrofluorometry; synthesis; Adsorption; Cellulose; Fluorescein; Hydrogen Bonding; Hydrogen-Ion Concentration; Quantum Theory; Spectrometry, Fluorescence; Water; Xanthenes
Año:2014
Volumen:13
Número:9
Página de inicio:1311
Página de fin:1320
DOI: http://dx.doi.org/10.1039/c4pp00150h
Título revista:Photochemical and Photobiological Sciences
Título revista abreviado:Photochem. Photobiol. Sci.
ISSN:1474905X
CODEN:PPSHC
CAS:cellulose, 61991-22-8, 68073-05-2, 9004-34-6; fluorescein, 2321-07-5, 91316-42-6; microcrystalline cellulose, 39394-43-9, 51395-75-6; water, 7732-18-5; 6-hydroxy-3-xanthen-3-one; Cellulose; Fluorescein; microcrystalline cellulose; Water; Xanthenes
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1474905X_v13_n9_p1311_Lopez

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Citas:

---------- APA ----------
Lopez, S.G., Crovetto, L., Alvarez-Pez, J.M., Talavera, E.M. & San Román, E. (2014) . Fluorescence enhancement of a fluorescein derivative upon adsorption on cellulose. Photochemical and Photobiological Sciences, 13(9), 1311-1320.
http://dx.doi.org/10.1039/c4pp00150h
---------- CHICAGO ----------
Lopez, S.G., Crovetto, L., Alvarez-Pez, J.M., Talavera, E.M., San Román, E. "Fluorescence enhancement of a fluorescein derivative upon adsorption on cellulose" . Photochemical and Photobiological Sciences 13, no. 9 (2014) : 1311-1320.
http://dx.doi.org/10.1039/c4pp00150h
---------- MLA ----------
Lopez, S.G., Crovetto, L., Alvarez-Pez, J.M., Talavera, E.M., San Román, E. "Fluorescence enhancement of a fluorescein derivative upon adsorption on cellulose" . Photochemical and Photobiological Sciences, vol. 13, no. 9, 2014, pp. 1311-1320.
http://dx.doi.org/10.1039/c4pp00150h
---------- VANCOUVER ----------
Lopez, S.G., Crovetto, L., Alvarez-Pez, J.M., Talavera, E.M., San Román, E. Fluorescence enhancement of a fluorescein derivative upon adsorption on cellulose. Photochem. Photobiol. Sci. 2014;13(9):1311-1320.
http://dx.doi.org/10.1039/c4pp00150h