Artículo
Nudelman, N.S.; Doctorovich, F. "Kinetic study of the reaction of naphthyllithium with carbon monoxide in hexane-tetrahydrofuran solution" (1994) Journal of the Chemical Society, Perkin Transactions 2(6):1233-1238
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Abstract:
The rate of the reaction of naphthyllithium, 1, with CO in 80:20 hexane-tetrahydrofuran (THF) was studied at 25°C. The determined second order kinetic law was found to be first order with respect to 1 and to CO. The observed specific rate coefficient is 6.63 ± 0.35 dm3 mol-1 s-1. Radical scavengers were observed to inhibit the CO uptake: this result as well as the kinetic studies, are consistent with an electron transfer as the first and rate-determining step of the reaction. The rate of the reaction between 1 and THF was also determined and found to be 105 times slower than the reaction of 1 with CO.
Registro:
| Documento: | Artículo |
| Título: | Kinetic study of the reaction of naphthyllithium with carbon monoxide in hexane-tetrahydrofuran solution |
| Autor: | Nudelman, N.S.; Doctorovich, F. |
| Filiación: | Depto. Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina |
| Año: | 1994 |
| Número: | 6 |
| Página de inicio: | 1233 |
| Página de fin: | 1238 |
| Título revista: | Journal of the Chemical Society, Perkin Transactions 2 |
| ISSN: | 1472779X |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n6_p1233_Nudelman |
Citas:
---------- APA ----------
Nudelman, N.S. & Doctorovich, F. (1994) . Kinetic study of the reaction of naphthyllithium with carbon monoxide in hexane-tetrahydrofuran solution. Journal of the Chemical Society, Perkin Transactions 2(6), 1233-1238.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n6_p1233_Nudelman [ ]
---------- CHICAGO ----------
Nudelman, N.S., Doctorovich, F. "Kinetic study of the reaction of naphthyllithium with carbon monoxide in hexane-tetrahydrofuran solution" . Journal of the Chemical Society, Perkin Transactions 2, no. 6 (1994) : 1233-1238.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n6_p1233_Nudelman [ ]
---------- MLA ----------
Nudelman, N.S., Doctorovich, F. "Kinetic study of the reaction of naphthyllithium with carbon monoxide in hexane-tetrahydrofuran solution" . Journal of the Chemical Society, Perkin Transactions 2, no. 6, 1994, pp. 1233-1238.Recuperado de https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n6_p1233_Nudelman [ ]
---------- VANCOUVER ----------
Nudelman, N.S., Doctorovich, F. Kinetic study of the reaction of naphthyllithium with carbon monoxide in hexane-tetrahydrofuran solution. 1994(6):1233-1238.Available from: https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n6_p1233_Nudelman [ ]
