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Abstract:

The reactions of 2,4- and 2,6-dinitrochlorobenzene and 2,4-dinitroanisole with cyclohexylamine in benzene and in methanol have been examined. Computer analysis of the kinetic data shows the formation and fate of a solvolysis product in the reaction of 2,4-dinitrochlorobenzene in methanol. The results prove that an experimental failure to detect a solvolysis product is not evidence for a negligible solvolysis rate.

Registro:

Documento: Artículo
Título:Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution
Autor:Nudelman, N.S.; Garrido, D.
Filiación:Dep. de Química Orgánica, Facultad de Cs. Exactas y Naturales, Ciudad Universitaria, Buenos Aires, Argentina
Año:1976
Número:11
Página de inicio:1256
Página de fin:1260
DOI: http://dx.doi.org/10.1039/P29760001256
Título revista:Journal of the Chemical Society, Perkin Transactions 2
ISSN:1472779X
Registro:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1472779X_v_n11_p1256_Nudelman

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Citas:

---------- APA ----------
Nudelman, N.S. & Garrido, D. (1976) . Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution. Journal of the Chemical Society, Perkin Transactions 2(11), 1256-1260.
http://dx.doi.org/10.1039/P29760001256
---------- CHICAGO ----------
Nudelman, N.S., Garrido, D. "Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution" . Journal of the Chemical Society, Perkin Transactions 2, no. 11 (1976) : 1256-1260.
http://dx.doi.org/10.1039/P29760001256
---------- MLA ----------
Nudelman, N.S., Garrido, D. "Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution" . Journal of the Chemical Society, Perkin Transactions 2, no. 11, 1976, pp. 1256-1260.
http://dx.doi.org/10.1039/P29760001256
---------- VANCOUVER ----------
Nudelman, N.S., Garrido, D. Kinetic evidence for a methanolysis intermediate in aromatic nucleophilic substitution. 1976(11):1256-1260.
http://dx.doi.org/10.1039/P29760001256