Artículo
Baggio, R.; Frigerio, A.; Halac, E.B.; Vega, D.; Perec, M. "Anionic halide and isothiocyanate adducts of zinc and cadmium dithiocarbamates" (1992) Journal of the Chemical Society, Dalton Transactions(4):549-554
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Abstract:
The mixed-ligand complexes [NEt4][Zn(S2CNMe2)2X] (X = Cl, Br, or NCS) and [NR4][Cd(S2CNEt2)2X] (R = Et, X = Cl, Br, or NCS; R = Bun, X = I) have been prepared by reaction of zinc and cadmium bis(dithiocarbamate) with the tetraalkylammonium salt of the halide or thiocyanate in acetone at room temperature. The single-crystal X-ray structures of [NEt4][Zn(S2CNMe2)2(NCS)] 1 and [NEt4][Cd(S2CNEt2)2(NCS)] 2 were determined: 1, monoclinic, space group P21/n, a = 9.447(1), b = 16.661(2), c = 15.807(1) Å, β = 97.10(1)° and Z = 4; 2, orthorhombic, space group P212121, a = 16.213(1), b = 17.501(2), c = 10.243(1) Å and Z = 4. The central Zn and Cd atoms show distorted trigonal-bipyramidal co-ordination geometry with the thiocyanate N atom occupying an equatorial position and the dithiocarbamate ligands spanning one axial and one equatorial position each. The infrared and Raman spectra (2100-50 cm-1) of the complexes are discussed. The metal-sulfur stretching frequencies are assigned in the ranges 226-205 (Zn-S) and 203-145 cm-1 (Cd-S), respectively.
Registro:
| Documento: | Artículo |
| Título: | Anionic halide and isothiocyanate adducts of zinc and cadmium dithiocarbamates |
| Autor: | Baggio, R.; Frigerio, A.; Halac, E.B.; Vega, D.; Perec, M. |
| Filiación: | Division Fisica del Solido, Departamento de Fisica, Comision Nacional de Energia Atomica, Avda. del Libertador 8250 1429, Buenos Aires, Argentina Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon II 1428, Buenos Aires, Argentina |
| Año: | 1992 |
| Número: | 4 |
| Página de inicio: | 549 |
| Página de fin: | 554 |
| DOI: | http://dx.doi.org/10.1039/DT9920000549 |
| Título revista: | Journal of the Chemical Society, Dalton Transactions |
| ISSN: | 14727773 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14727773_v_n4_p549_Baggio |
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Citas:
---------- APA ----------
Baggio, R., Frigerio, A., Halac, E.B., Vega, D. & Perec, M. (1992) . Anionic halide and isothiocyanate adducts of zinc and cadmium dithiocarbamates. Journal of the Chemical Society, Dalton Transactions(4), 549-554.http://dx.doi.org/10.1039/DT9920000549
---------- CHICAGO ----------
Baggio, R., Frigerio, A., Halac, E.B., Vega, D., Perec, M. "Anionic halide and isothiocyanate adducts of zinc and cadmium dithiocarbamates" . Journal of the Chemical Society, Dalton Transactions, no. 4 (1992) : 549-554.http://dx.doi.org/10.1039/DT9920000549
---------- MLA ----------
Baggio, R., Frigerio, A., Halac, E.B., Vega, D., Perec, M. "Anionic halide and isothiocyanate adducts of zinc and cadmium dithiocarbamates" . Journal of the Chemical Society, Dalton Transactions, no. 4, 1992, pp. 549-554.http://dx.doi.org/10.1039/DT9920000549
---------- VANCOUVER ----------
Baggio, R., Frigerio, A., Halac, E.B., Vega, D., Perec, M. Anionic halide and isothiocyanate adducts of zinc and cadmium dithiocarbamates. 1992(4):549-554.http://dx.doi.org/10.1039/DT9920000549
