Artículo
Baggio, R.; Garland, M.T.; Perec, M. "Interaction of zinc and cadmium bis(benzothiazole-2-thiolates) with nitrogen bases" (1993) Journal of the Chemical Society, Dalton Transactions(22):3367-3372
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Abstract:
The reactions of polymeric [Zn(C7H4NS2)2] with pyridine (py), 2,2′-bipyridine (bipy) and 1,10-phenanthroline (phen) lead to the formation of mononuclear adducts which have been characterized by elemental analysis and infrared spectroscopy. The complexes [Zn(C7H4NS2)2(py)2] 1, [Zn(C7H4NS2)2(bipy)] 2 and [Cd(C7H4NS2)2(py)2] 3 were structurally characterized by X-ray crystallography. Adducts 1 and 2 have distorted-tetrahedral ZnN2S2 cores. The zinc ions are co-ordinated to the two exocyclic S atoms of the benzothiazole-2-thiolates and to two nitrogen atoms from the py or bipy base. The Zn-S and Zn-N bond distances are 2.324(1) and 2.063(4) Å in 1 and 2.310(13) and 2.096(4) Å in 2. The complex [Zn(C7H4NS2)2(phen)] was found to be isomorphous to 2. Adduct 3 shows a distorted-octahedral CdN4S2 unit formed by two bidentate S,N benzothiazole-2-thiolates and two cis pyridine nitrogen atoms. The two exocyclic S atoms are located at the axial positions. The mean Cd-S and Cd-N bonds of the bidentate ligands in 3 are 2.706(10) and 2.422(30) Å and the corresponding mean Cd-N(py) is 2.334(4) Å. The infrared spectra of the adducts in the range 650-200 cm-1 are discussed in the light of the known structures. The thermal degradation of complexes 1-3 affords ZnS or CdS.
Registro:
| Documento: | Artículo |
| Título: | Interaction of zinc and cadmium bis(benzothiazole-2-thiolates) with nitrogen bases |
| Autor: | Baggio, R.; Garland, M.T.; Perec, M. |
| Filiación: | División Fisica del Sólido, Departamento de Fisica, Comisión Nacional de Energia Atómica, Avda. del Libertador 8250, 1429 Buenos Aires, Argentina Departamento de Fisica, Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Avda. Blanco Encalada 2008, Santiago, Chile Departamento de Química Inorgánica, Analítica y Química Física, Universidad de Buenos Aires, Ciudad Universitaria, 1428 Buenos Aires, Argentina |
| Año: | 1993 |
| Número: | 22 |
| Página de inicio: | 3367 |
| Página de fin: | 3372 |
| DOI: | http://dx.doi.org/10.1039/DT9930003367 |
| Título revista: | Journal of the Chemical Society, Dalton Transactions |
| ISSN: | 14727773 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14727773_v_n22_p3367_Baggio |
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Citas:
---------- APA ----------
Baggio, R., Garland, M.T. & Perec, M. (1993) . Interaction of zinc and cadmium bis(benzothiazole-2-thiolates) with nitrogen bases. Journal of the Chemical Society, Dalton Transactions(22), 3367-3372.http://dx.doi.org/10.1039/DT9930003367
---------- CHICAGO ----------
Baggio, R., Garland, M.T., Perec, M. "Interaction of zinc and cadmium bis(benzothiazole-2-thiolates) with nitrogen bases" . Journal of the Chemical Society, Dalton Transactions, no. 22 (1993) : 3367-3372.http://dx.doi.org/10.1039/DT9930003367
---------- MLA ----------
Baggio, R., Garland, M.T., Perec, M. "Interaction of zinc and cadmium bis(benzothiazole-2-thiolates) with nitrogen bases" . Journal of the Chemical Society, Dalton Transactions, no. 22, 1993, pp. 3367-3372.http://dx.doi.org/10.1039/DT9930003367
---------- VANCOUVER ----------
Baggio, R., Garland, M.T., Perec, M. Interaction of zinc and cadmium bis(benzothiazole-2-thiolates) with nitrogen bases. 1993(22):3367-3372.http://dx.doi.org/10.1039/DT9930003367
