Artículo
Baggio, R.; Garland, M.T.; Moreno, Y.; Peña, O.; Perec, M.; Spodine, E. "Synthesis, structure and magnetic properties of the 2,2′-oxydiacetato-bridged Cu(II)-Ln(III) complexes [{Cu3Ln2(oda)6(H2O) 6}·12H2O]n (Ln = Y, Gd, Eu, Nd, Pr)" (2000) Journal of the Chemical Society, Dalton Transactions(13):2061-2066
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Abstract:
Heterometallic compounds comprising copper(II) and rare-earth cations with carboxylate groups of the 2,2′-oxydiacetato as the connecting ligands, have been investigated. Five isostructural polymers [{Cu3Ln2(oda)6-(H2O) 6}·12H2O]n (Ln = Y (1), Gd (2), Eu (3), Nd (4) and Pr (5)) have been obtained and their structures determined by X-ray diffraction methods. The Ln(III) cations in 1 to 5 are coordinated by six carboxy and three ether oxygen atoms in the tricapped trigonal prism arrangement and the Cu(II) cations are bonded to four carboxy oxygens and two apical aqua ligands in a distorted octahedral geometry. The magnetic behaviors of these complexes show very weak antiferromaenetic interaction in the solid. © The Royal Society of Chemistry 2000.
Registro:
| Documento: | Artículo |
| Título: | Synthesis, structure and magnetic properties of the 2,2′-oxydiacetato-bridged Cu(II)-Ln(III) complexes [{Cu3Ln2(oda)6(H2O) 6}·12H2O]n (Ln = Y, Gd, Eu, Nd, Pr) |
| Autor: | Baggio, R.; Garland, M.T.; Moreno, Y.; Peña, O.; Perec, M.; Spodine, E. |
| Filiación: | Departamento de Fisica, Comision National de Energia Atomica, Avda del Libertador 8250, 1429 Buenos Aires, Argentina Departamento de Fisica, Facultad de Ciencias Fisicas y Matematicas, Universidad de Chile, Avda Blanco Encalada 2008, Casilla 487-3, Santiago, Chile U.M.R. 6511, L.C.S.I.M. CNRS, Universite Rennes I, 35042 Rennes, France Departamento de Quimica Inorganica Analitica y Quimica Fisica, Facultad de Ciencias Exactas y Naturales, Pabellon II, 1428 Buenos Aires, Argentina Facultad de Ciencias Quimicas y Farmaceuticas, Universidad de Chile, Casilla 233, Santiago, Chile |
| Año: | 2000 |
| Número: | 13 |
| Página de inicio: | 2061 |
| Página de fin: | 2066 |
| DOI: | http://dx.doi.org/10.1039/a909544f |
| Título revista: | Journal of the Chemical Society, Dalton Transactions |
| Título revista abreviado: | J. Chem. Soc. Dalton Trans. |
| ISSN: | 1470479X |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_1470479X_v_n13_p2061_Baggio |
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Citas:
---------- APA ----------
Baggio, R., Garland, M.T., Moreno, Y., Peña, O., Perec, M. & Spodine, E. (2000) . Synthesis, structure and magnetic properties of the 2,2′-oxydiacetato-bridged Cu(II)-Ln(III) complexes [{Cu3Ln2(oda)6(H2O) 6}·12H2O]n (Ln = Y, Gd, Eu, Nd, Pr). Journal of the Chemical Society, Dalton Transactions(13), 2061-2066.http://dx.doi.org/10.1039/a909544f
---------- CHICAGO ----------
Baggio, R., Garland, M.T., Moreno, Y., Peña, O., Perec, M., Spodine, E. "Synthesis, structure and magnetic properties of the 2,2′-oxydiacetato-bridged Cu(II)-Ln(III) complexes [{Cu3Ln2(oda)6(H2O) 6}·12H2O]n (Ln = Y, Gd, Eu, Nd, Pr)" . Journal of the Chemical Society, Dalton Transactions, no. 13 (2000) : 2061-2066.http://dx.doi.org/10.1039/a909544f
---------- MLA ----------
Baggio, R., Garland, M.T., Moreno, Y., Peña, O., Perec, M., Spodine, E. "Synthesis, structure and magnetic properties of the 2,2′-oxydiacetato-bridged Cu(II)-Ln(III) complexes [{Cu3Ln2(oda)6(H2O) 6}·12H2O]n (Ln = Y, Gd, Eu, Nd, Pr)" . Journal of the Chemical Society, Dalton Transactions, no. 13, 2000, pp. 2061-2066.http://dx.doi.org/10.1039/a909544f
---------- VANCOUVER ----------
Baggio, R., Garland, M.T., Moreno, Y., Peña, O., Perec, M., Spodine, E. Synthesis, structure and magnetic properties of the 2,2′-oxydiacetato-bridged Cu(II)-Ln(III) complexes [{Cu3Ln2(oda)6(H2O) 6}·12H2O]n (Ln = Y, Gd, Eu, Nd, Pr). J. Chem. Soc. Dalton Trans. 2000(13):2061-2066.http://dx.doi.org/10.1039/a909544f
