Artículo
Schor, L.; Gros, E.G.; Seldes, A.M. "ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde" (1992) Journal of the Chemical Society, Perkin Transactions 1(4):453-454
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Abstract:
The synthesis of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde and a highly efficient method for its D-homorearrangement is described. The transformation produced by the action of Zn IIafforded 17α-hydroxy-3β-methoxy-D-homoandrost-5-en-17a-one in a fast, stereospecific, and high-yield reaction. © Royal Society of Chemistry.
Registro:
| Documento: | Artículo |
| Título: | ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde |
| Autor: | Schor, L.; Gros, E.G.; Seldes, A.M. |
| Filiación: | Departamento de Química Orgánica, Universidad de Buenos Aires, Pabellón 2, Buenos Aires, 1428, Argentina |
| Año: | 1992 |
| Número: | 4 |
| Página de inicio: | 453 |
| Página de fin: | 454 |
| DOI: | http://dx.doi.org/10.1039/P19920000453 |
| Título revista: | Journal of the Chemical Society, Perkin Transactions 1 |
| Título revista abreviado: | J. Chem. Soc. Perkin Trans. 1 |
| ISSN: | 14704358 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14704358_v_n4_p453_Schor |
Referencias:
- Wendler, N.L., (1964) Molecular Rearrangements, 2, pp. 1099-1101, 1114-1121. , P. de Mayo, Interscience, New York
- Kirk, Q.N., Hartshorn, M.P., (1968) Steroid Reaction Mechanisms, pp. 294-301. , Elsevier, Amsterdam
- Kirk, D.N., McHugh, C.R., (1978) J. Chem. Soc., Perkin Trans. 1, p. 173. , references therein
- Schor, L., Seldes, A.M., Gros, E.G., (1990) J. Chem. Soc., Perkin Trans. 1, p. 163
- Reid, J.G., Debiak-Krook, T., (1990) Tetrahedron Lett., 31, p. 3669
- Hansen, M.M., Bartlett, P.A., Heathcock, C.H., (1987) Organometallics, 6, p. 2069
Citas:
---------- APA ----------
Schor, L., Gros, E.G. & Seldes, A.M. (1992) . ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde. Journal of the Chemical Society, Perkin Transactions 1(4), 453-454.http://dx.doi.org/10.1039/P19920000453
---------- CHICAGO ----------
Schor, L., Gros, E.G., Seldes, A.M. "ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde" . Journal of the Chemical Society, Perkin Transactions 1, no. 4 (1992) : 453-454.http://dx.doi.org/10.1039/P19920000453
---------- MLA ----------
Schor, L., Gros, E.G., Seldes, A.M. "ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde" . Journal of the Chemical Society, Perkin Transactions 1, no. 4, 1992, pp. 453-454.http://dx.doi.org/10.1039/P19920000453
---------- VANCOUVER ----------
Schor, L., Gros, E.G., Seldes, A.M. ZnII-promoted D-homorearrangement of 17α-hydroxy-3β-methoxyandrost-5-ene-17β-carbaldehyde. J. Chem. Soc. Perkin Trans. 1. 1992(4):453-454.http://dx.doi.org/10.1039/P19920000453
