Artículo
Schor, L.; Seldes, A.M.; Gros, E.G. "Zinc(II)-promoted stereospecific rearrangement of 17-hydroxy-20-oxopregnane derivatives" (1990) Journal of the Chemical Society, Perkin Transactions 1(1):163-166
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Abstract:
A new and highly efficient method for D-homo-rearrangements in the steroid field is described. The transformation is induced by the action of zinc(II) on different 17-hydroxy-20-oxopregnanes. With 17α-hydroxy-20-oxopregnanes the reaction afforded 17aα-hydroxy-17aβ-methyl-D-homo-derivatives while under the same conditions 17β-hydroxy-20-oxopregnanes gave the corresponding 17a-epimeric-D-homo-steroids. In both cases the rearrangement was stereospecif giving the corresponding products in almost quantitative yields. © 1990, The Royal Society of Chemistry. All rights reserved.
Registro:
| Documento: | Artículo |
| Título: | Zinc(II)-promoted stereospecific rearrangement of 17-hydroxy-20-oxopregnane derivatives |
| Autor: | Schor, L.; Seldes, A.M.; Gros, E.G. |
| Filiación: | Departamento de Química Orgánica, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón 2, Buenos Aires, 1428, Argentina |
| Año: | 1990 |
| Número: | 1 |
| Página de inicio: | 163 |
| Página de fin: | 166 |
| DOI: | http://dx.doi.org/10.1039/P19900000163 |
| Título revista: | Journal of the Chemical Society, Perkin Transactions 1 |
| Título revista abreviado: | J. Chem. Soc. Perkin Trans. 1 |
| ISSN: | 14704358 |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14704358_v_n1_p163_Schor |
Referencias:
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Citas:
---------- APA ----------
Schor, L., Seldes, A.M. & Gros, E.G. (1990) . Zinc(II)-promoted stereospecific rearrangement of 17-hydroxy-20-oxopregnane derivatives. Journal of the Chemical Society, Perkin Transactions 1(1), 163-166.http://dx.doi.org/10.1039/P19900000163
---------- CHICAGO ----------
Schor, L., Seldes, A.M., Gros, E.G. "Zinc(II)-promoted stereospecific rearrangement of 17-hydroxy-20-oxopregnane derivatives" . Journal of the Chemical Society, Perkin Transactions 1, no. 1 (1990) : 163-166.http://dx.doi.org/10.1039/P19900000163
---------- MLA ----------
Schor, L., Seldes, A.M., Gros, E.G. "Zinc(II)-promoted stereospecific rearrangement of 17-hydroxy-20-oxopregnane derivatives" . Journal of the Chemical Society, Perkin Transactions 1, no. 1, 1990, pp. 163-166.http://dx.doi.org/10.1039/P19900000163
---------- VANCOUVER ----------
Schor, L., Seldes, A.M., Gros, E.G. Zinc(II)-promoted stereospecific rearrangement of 17-hydroxy-20-oxopregnane derivatives. J. Chem. Soc. Perkin Trans. 1. 1990(1):163-166.http://dx.doi.org/10.1039/P19900000163
