Artículo
Ruiz, G.N.; Amann-Winkel, K.; Bove, L.E.; Corti, H.R.; Loerting, T. "Calorimetric study of water's two glass transitions in the presence of LiCl" (2018) Physical Chemistry Chemical Physics. 20(9):6401-6408
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Abstract:
A DSC study of dilute glassy LiCl aqueous solutions in the water-dominated regime provides direct evidence of a glass-to-liquid transition in expanded high density amorphous (eHDA)-type solutions. Similarly, low density amorphous ice (LDA) exhibits a glass transition prior to crystallization to ice Ic. Both glass transition temperatures are independent of the salt concentration, whereas the magnitude of the heat capacity increase differs. By contrast to pure water, the glass transition endpoint for LDA can be accessed in LiCl aqueous solutions above 0.01 mole fraction. Furthermore, we also reveal the endpoint for HDA's glass transition, solving the question on the width of both glass transitions. This suggests that both equilibrated HDL and LDL can be accessed in dilute LiCl solutions, supporting the liquid-liquid transition scenario to understand water's anomalies. © 2017 the Owner Societies.
Registro:
| Documento: | Artículo |
| Título: | Calorimetric study of water's two glass transitions in the presence of LiCl |
| Autor: | Ruiz, G.N.; Amann-Winkel, K.; Bove, L.E.; Corti, H.R.; Loerting, T. |
| Filiación: | Institute of Physical Chemistry, University of Innsbruck, Innrain 52c, Innsbruck, 6020, Austria Departament de Física e Enginyeria Nuclear, Universitat Politècnica de Catalunya, Barcelona, 08028, Spain Department of Physics, AlbaNova University Center, Stockolm, 10691, Sweden Institut de Mineralogie et de Physique des Milieux Condenses, CNRS, Universitè P.et M. Curie, 4 place de Jussieu, Paris, 75005, France Institute of Condensed Matter Physics, Ecole Polytechnique Fédérale de Lausanne, Lausanne, Switzerland Departamento de Física de la Materia Condensada, Comisión Nacional de Energía Atómica, San Martín Buenos Aires, Argentina Instituto de Química Física de Los Materiales, Medio Ambiente y Energía, Universidad de Buenos Aires, Ciudad Autónoma de Buenos Aires, Argentina |
| Año: | 2018 |
| Volumen: | 20 |
| Número: | 9 |
| Página de inicio: | 6401 |
| Página de fin: | 6408 |
| DOI: | http://dx.doi.org/10.1039/c7cp08677f |
| Título revista: | Physical Chemistry Chemical Physics |
| Título revista abreviado: | Phys. Chem. Chem. Phys. |
| ISSN: | 14639076 |
| CODEN: | PPCPF |
| Registro: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14639076_v20_n9_p6401_Ruiz |
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Citas:
---------- APA ----------
Ruiz, G.N., Amann-Winkel, K., Bove, L.E., Corti, H.R. & Loerting, T. (2018) . Calorimetric study of water's two glass transitions in the presence of LiCl. Physical Chemistry Chemical Physics, 20(9), 6401-6408.http://dx.doi.org/10.1039/c7cp08677f
---------- CHICAGO ----------
Ruiz, G.N., Amann-Winkel, K., Bove, L.E., Corti, H.R., Loerting, T. "Calorimetric study of water's two glass transitions in the presence of LiCl" . Physical Chemistry Chemical Physics 20, no. 9 (2018) : 6401-6408.http://dx.doi.org/10.1039/c7cp08677f
---------- MLA ----------
Ruiz, G.N., Amann-Winkel, K., Bove, L.E., Corti, H.R., Loerting, T. "Calorimetric study of water's two glass transitions in the presence of LiCl" . Physical Chemistry Chemical Physics, vol. 20, no. 9, 2018, pp. 6401-6408.http://dx.doi.org/10.1039/c7cp08677f
---------- VANCOUVER ----------
Ruiz, G.N., Amann-Winkel, K., Bove, L.E., Corti, H.R., Loerting, T. Calorimetric study of water's two glass transitions in the presence of LiCl. Phys. Chem. Chem. Phys. 2018;20(9):6401-6408.http://dx.doi.org/10.1039/c7cp08677f
